Diseño y preparación de catalizadores soportados en materiales carbonosos estructurados

ilustraciones, fotografías, gráficas, tablas

Autores:: Rodríguez Riaño, Nicolás

Tipo de recurso:: Doctoral thesis

Fecha de publicación:: 2021

Institución:: Universidad Nacional de Colombia

Repositorio:: Universidad Nacional de Colombia

Idioma:: spa

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dc.title.spa.fl_str_mv	Diseño y preparación de catalizadores soportados en materiales carbonosos estructurados
dc.title.translated.eng.fl_str_mv	Design and preparation of catalysts supported on structured carbonaceous materials
title	Diseño y preparación de catalizadores soportados en materiales carbonosos estructurados
spellingShingle	Diseño y preparación de catalizadores soportados en materiales carbonosos estructurados 540 - Química y ciencias afines::541 - Química física Catalysts Chemistry, Technical Gels Catalizadores Tecnología química Geles WGSR Monolith Carbon xerogel Starch Acetic acid ketonization Monolito Xerogel de carbono Almidón Cetonización de ácido acético
title_short	Diseño y preparación de catalizadores soportados en materiales carbonosos estructurados
title_full	Diseño y preparación de catalizadores soportados en materiales carbonosos estructurados
title_fullStr	Diseño y preparación de catalizadores soportados en materiales carbonosos estructurados
title_full_unstemmed	Diseño y preparación de catalizadores soportados en materiales carbonosos estructurados
title_sort	Diseño y preparación de catalizadores soportados en materiales carbonosos estructurados
dc.creator.fl_str_mv	Rodríguez Riaño, Nicolás
dc.contributor.advisor.spa.fl_str_mv	Agamez Pertuz, Yazmin Yaneth Odriozola Gordon, Jose Antonio Centeno Gallego, Miguel Angel
dc.contributor.author.spa.fl_str_mv	Rodríguez Riaño, Nicolás
dc.contributor.researchgroup.spa.fl_str_mv	Laboratorio de Investigación en Combustibles y Energía
dc.subject.ddc.spa.fl_str_mv	540 - Química y ciencias afines::541 - Química física
topic	540 - Química y ciencias afines::541 - Química física Catalysts Chemistry, Technical Gels Catalizadores Tecnología química Geles WGSR Monolith Carbon xerogel Starch Acetic acid ketonization Monolito Xerogel de carbono Almidón Cetonización de ácido acético
dc.subject.lemb.eng.fl_str_mv	Catalysts Chemistry, Technical Gels
dc.subject.lemb.spa.fl_str_mv	Catalizadores Tecnología química Geles
dc.subject.proposal.eng.fl_str_mv	WGSR Monolith Carbon xerogel Starch Acetic acid ketonization
dc.subject.proposal.spa.fl_str_mv	Monolito Xerogel de carbono Almidón Cetonización de ácido acético
description	ilustraciones, fotografías, gráficas, tablas
publishDate	2021
dc.date.accessioned.none.fl_str_mv	2021-10-27T17:11:45Z
dc.date.available.none.fl_str_mv	2021-10-27T17:11:45Z
dc.date.issued.none.fl_str_mv	2021-04-15
dc.type.spa.fl_str_mv	Trabajo de grado - Doctorado
dc.type.driver.spa.fl_str_mv	info:eu-repo/semantics/doctoralThesis
dc.type.version.spa.fl_str_mv	info:eu-repo/semantics/acceptedVersion
dc.type.coar.spa.fl_str_mv	http://purl.org/coar/resource_type/c_db06
dc.type.content.spa.fl_str_mv	Text
dc.type.redcol.spa.fl_str_mv	http://purl.org/redcol/resource_type/TD
format	http://purl.org/coar/resource_type/c_db06
status_str	acceptedVersion
dc.identifier.uri.none.fl_str_mv	https://repositorio.unal.edu.co/handle/unal/80626
dc.identifier.instname.spa.fl_str_mv	Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv	Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv	https://repositorio.unal.edu.co/
url	https://repositorio.unal.edu.co/handle/unal/80626 https://repositorio.unal.edu.co/
identifier_str_mv	Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv	spa
language	spa
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dc.format.extent.spa.fl_str_mv	xxii, 197 páginas
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dc.publisher.spa.fl_str_mv	Universidad Nacional de Colombia
dc.publisher.program.spa.fl_str_mv	Bogotá - Ciencias - Doctorado en Ciencias - Química
dc.publisher.department.spa.fl_str_mv	Departamento de Química
dc.publisher.faculty.spa.fl_str_mv	Facultad de Ciencias
dc.publisher.place.spa.fl_str_mv	Bogotá, Colombia
dc.publisher.branch.spa.fl_str_mv	Universidad Nacional de Colombia - Sede Bogotá
institution	Universidad Nacional de Colombia
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spelling	Atribución-NoComercial 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Agamez Pertuz, Yazmin Yanethefd909b83bf98bc0b7dada7542028289Odriozola Gordon, Jose Antonioe15ddad5c34add71882cb39dc0507684Centeno Gallego, Miguel Angele473bf2b953d4c932f8fc34fc4a950ae600Rodríguez Riaño, Nicolásd1b4d228be808e6d6342a2f071847051Laboratorio de Investigación en Combustibles y Energía2021-10-27T17:11:45Z2021-10-27T17:11:45Z2021-04-15https://repositorio.unal.edu.co/handle/unal/80626Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, fotografías, gráficas, tablasLa presente tesis desarrolla una nueva metodología de preparación de monolitos de carbono a partir de diversos materiales carbonosos abarcando desde carbones minerales hasta materiales diseñados con características específicas preparados a nivel laboratorio, empleando una solución de resorcinol - formaldehído con adición de almidón soluble como medio de suspensión de las materias primas carbonosas y asistiendo la formación de las múltiples geometrías logradas con moldes diseñados y elaborados mediante impresión 3D. En la exploración de materias primas que constituyeran los monolitos se prepararon y caracterizaron un coque derivado de un carbón mineral colombiano, diferentes carbones activados obtenidos a partir de un residuo agrícola denominado cuesco generado por la obtención de biodiesel a partir de aceite de palma africana, aerogeles de carbono y xerogeles de carbono en los que se incluyó de manera sistemática la adición de aglomerantes como glicerina y almidón como aditivos, los cuales mantuvieron la estructura microporosa que suele colapsar en el secado convectivo. Una vez estudiadas las posibles materias primas se presenta un sondeo para determinar los diferentes efectos de la variación de algunos parámetros en la novedosa metodología para la preparación de monolitos. Con el xerogel de carbono obtenido y estudiado en la exploración de materias primas que se empleó como medio de suspensión en la metodología de preparación de monolitos, se prepararon catalizadores para la reacción de desplazamiento de vapor de agua (WGSR) y se prepara un catalizador en polvo y uno estructurado para la cetonización de ácido acético, esto con le fin de aplicar el conocimiento desarrollado en este trabajo en como posibles soportes catalíticos de reacciones de interés medio ambiental. (Texto tomado de la fuente).This thesis develops a new methodology for the preparation of carbon monoliths from various carbonaceous materials, ranging from mineral coals to materials designed with specific characteristics prepared at the laboratory level, using a resorcinol-formaldehyde solution with the addition of soluble starch as a suspension medium of carbonaceous raw materials and assisting the formation of the multiple geometries achieved with molds designed and manufactured by 3D printing. In the exploration of raw materials that constituted the monoliths, a coke derived from a Colombian mineral coal was prepared and characterized, different activated carbons obtained from an agricultural residue called shell generated by obtaining biodiesel from African palm oil, aerogels of carbon and carbon xerogels in which the addition of binders such as glycerin and starch as additives was systematically included, which maintained the microporous structure that usually collapses in convective drying. Once the possible raw materials have been studied, a survey is presented to determine the different effects of the variation of some parameters in the novel methodology for the preparation of monoliths. With the carbon xerogel obtained and studied in the exploration of raw materials that was used as a suspension medium in the monolith preparation methodology, catalysts were prepared for the water gas shift reaction (WGSR) and a catalyst is prepared in powder and a structured one for acetic acid ketonization, this in order to apply the knowledge developed in this work as possible catalytic supports for reactions of environmental interest.Convocatoria 617 Doctorados NacionalesTesis de doctorado en cotutela con la Universidad de SevillaDoctoradoDoctor en Ciencias - QuímicaDesarrollo de tesis doctoralMateriales y Energíaxxii, 197 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ciencias - Doctorado en Ciencias - QuímicaDepartamento de QuímicaFacultad de CienciasBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá540 - Química y ciencias afines::541 - Química físicaCatalystsChemistry, TechnicalGelsCatalizadoresTecnología químicaGelesWGSRMonolithCarbon xerogelStarchAcetic acid ketonizationMonolitoXerogel de carbonoAlmidónCetonización de ácido acéticoDiseño y preparación de catalizadores soportados en materiales carbonosos estructuradosDesign and preparation of catalysts supported on structured carbonaceous materialsTrabajo de grado - Doctoradoinfo:eu-repo/semantics/doctoralThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_db06Texthttp://purl.org/redcol/resource_type/TD[1] H. 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Xu, Impacts of niobia loading on active sites and surface acidity in NbOx/CeO2–ZrO2 NH3–SCR catalysts, Applied Catalysis B: Environmental, 179 (2015) 380-394.ColcienciasInvestigadoresPúblico generalLICENSElicense.txtlicense.txttext/plain; charset=utf-84074https://repositorio.unal.edu.co/bitstream/unal/80626/1/license.txt8153f7789df02f0a4c9e079953658ab2MD51ORIGINAL1018429978.2021.pdf1018429978.2021.pdfTesis de Doctorado en Ciencias - Químicaapplication/pdf4109550https://repositorio.unal.edu.co/bitstream/unal/80626/2/1018429978.2021.pdf424d29c477b94ddaf307f6858d3d68dfMD52THUMBNAIL1018429978.2021.pdf.jpg1018429978.2021.pdf.jpgGenerated Thumbnailimage/jpeg5111https://repositorio.unal.edu.co/bitstream/unal/80626/3/1018429978.2021.pdf.jpg31fa3be617c8f9d06f9c20e2e6f91317MD53unal/80626oai:repositorio.unal.edu.co:unal/806262024-08-01 23:09:40.718Repositorio Institucional Universidad Nacional de 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EVESURBIFBPUiBMQSBTRUNSRVRBUsONQSBHRU5FUkFMLiAqTEEgVEVTSVMgQSBQVUJMSUNBUiBERUJFIFNFUiBMQSBWRVJTScOTTiBGSU5BTCBBUFJPQkFEQS4gCgpBbCBoYWNlciBjbGljIGVuIGVsIHNpZ3VpZW50ZSBib3TDs24sIHVzdGVkIGluZGljYSBxdWUgZXN0w6EgZGUgYWN1ZXJkbyBjb24gZXN0b3MgdMOpcm1pbm9zLiBTaSB0aWVuZSBhbGd1bmEgZHVkYSBzb2JyZSBsYSBsaWNlbmNpYSwgcG9yIGZhdm9yLCBjb250YWN0ZSBjb24gZWwgYWRtaW5pc3RyYWRvciBkZWwgc2lzdGVtYS4KClVOSVZFUlNJREFEIE5BQ0lPTkFMIERFIENPTE9NQklBIC0gw5psdGltYSBtb2RpZmljYWNpw7NuIDE5LzEwLzIwMjEK

Diseño y preparación de catalizadores soportados en materiales carbonosos estructurados

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