Obtention and characterization of lithium superionic conductors using the glass-ceramic method
This paper proposes the glass-ceramics method for obtaining lithium ion (Li+) solid electrolytes. This technique provides high chemical and microstructural homogeneity as well as low porosity. Glass samples were subjected to either single or double heat treatments, between 700 °C and 1000 °C, in ord...
- Autores:
-
Narváez-Semanate, Jose Luis
Martins Rodrigues, Ana Cândida
Muñoz Meneses, Rodrigo Arbey
Muñoz-Hoyos, José Rodrigo
Villamarín, Julián
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2018
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/68531
- Acceso en línea:
- https://repositorio.unal.edu.co/handle/unal/68531
http://bdigital.unal.edu.co/69564/
- Palabra clave:
- 62 Ingeniería y operaciones afines / Engineering
vitrocerámicas
baterías de ion litio
espectroscopía de impedancia
conductores superiónicos
sistema Li2O·Al2O3·TiO2·P2O5
glass-ceramics
lithium ion batteries
impedance spectroscopy
superionic conductors
Li2O·Al2O3·TiO2·P2O5 system
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Obtention and characterization of lithium superionic conductors using the glass-ceramic method |
| title |
Obtention and characterization of lithium superionic conductors using the glass-ceramic method |
| spellingShingle |
Obtention and characterization of lithium superionic conductors using the glass-ceramic method 62 Ingeniería y operaciones afines / Engineering vitrocerámicas baterías de ion litio espectroscopía de impedancia conductores superiónicos sistema Li2O·Al2O3·TiO2·P2O5 glass-ceramics lithium ion batteries impedance spectroscopy superionic conductors Li2O·Al2O3·TiO2·P2O5 system |
| title_short |
Obtention and characterization of lithium superionic conductors using the glass-ceramic method |
| title_full |
Obtention and characterization of lithium superionic conductors using the glass-ceramic method |
| title_fullStr |
Obtention and characterization of lithium superionic conductors using the glass-ceramic method |
| title_full_unstemmed |
Obtention and characterization of lithium superionic conductors using the glass-ceramic method |
| title_sort |
Obtention and characterization of lithium superionic conductors using the glass-ceramic method |
| dc.creator.fl_str_mv |
Narváez-Semanate, Jose Luis Martins Rodrigues, Ana Cândida Muñoz Meneses, Rodrigo Arbey Muñoz-Hoyos, José Rodrigo Villamarín, Julián |
| dc.contributor.author.spa.fl_str_mv |
Narváez-Semanate, Jose Luis Martins Rodrigues, Ana Cândida Muñoz Meneses, Rodrigo Arbey Muñoz-Hoyos, José Rodrigo Villamarín, Julián |
| dc.subject.ddc.spa.fl_str_mv |
62 Ingeniería y operaciones afines / Engineering |
| topic |
62 Ingeniería y operaciones afines / Engineering vitrocerámicas baterías de ion litio espectroscopía de impedancia conductores superiónicos sistema Li2O·Al2O3·TiO2·P2O5 glass-ceramics lithium ion batteries impedance spectroscopy superionic conductors Li2O·Al2O3·TiO2·P2O5 system |
| dc.subject.proposal.spa.fl_str_mv |
vitrocerámicas baterías de ion litio espectroscopía de impedancia conductores superiónicos sistema Li2O·Al2O3·TiO2·P2O5 glass-ceramics lithium ion batteries impedance spectroscopy superionic conductors Li2O·Al2O3·TiO2·P2O5 system |
| description |
This paper proposes the glass-ceramics method for obtaining lithium ion (Li+) solid electrolytes. This technique provides high chemical and microstructural homogeneity as well as low porosity. Glass samples were subjected to either single or double heat treatments, between 700 °C and 1000 °C, in order to obtain the glass-ceramics. Differential Scanning Calorimetry – DSC – results evidenced the possibility of fabricating these ceramics from glass in the system Li2O·Al2O3·TiO2·P2O5. Samples observed by Scanning Electron Microscopy – SEM – showed a finely grained microstructure which was homogeneously distributed and non-porous. X-ray Diffraction – XRD – patterns showed the formation of the high conducting phase LiTi2(PO4)3. A high ionic conductivity, in the order of 10-3 S/cm at 1000 °C, was measured by Impedance Spectroscopy – IS. It suggests that the synthesis method used in this research is useful for fabricating lithium ion glass-ceramics and opens up a new alternative for manufacturing different electrical ceramics. |
| publishDate |
2018 |
| dc.date.issued.spa.fl_str_mv |
2018-04-01 |
| dc.date.accessioned.spa.fl_str_mv |
2019-07-03T07:02:52Z |
| dc.date.available.spa.fl_str_mv |
2019-07-03T07:02:52Z |
| dc.type.spa.fl_str_mv |
Artículo de revista |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_6501 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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Text |
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http://purl.org/redcol/resource_type/ART |
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http://purl.org/coar/resource_type/c_6501 |
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publishedVersion |
| dc.identifier.issn.spa.fl_str_mv |
ISSN: 2346-2183 |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/68531 |
| dc.identifier.eprints.spa.fl_str_mv |
http://bdigital.unal.edu.co/69564/ |
| identifier_str_mv |
ISSN: 2346-2183 |
| url |
https://repositorio.unal.edu.co/handle/unal/68531 http://bdigital.unal.edu.co/69564/ |
| dc.language.iso.spa.fl_str_mv |
spa |
| language |
spa |
| dc.relation.spa.fl_str_mv |
https://revistas.unal.edu.co/index.php/dyna/article/view/70273 |
| dc.relation.ispartof.spa.fl_str_mv |
Universidad Nacional de Colombia Revistas electrónicas UN Dyna Dyna |
| dc.relation.references.spa.fl_str_mv |
Narváez-Semanate, Jose Luis and Martins Rodrigues, Ana Cândida and Muñoz Meneses, Rodrigo Arbey and Muñoz-Hoyos, José Rodrigo and Villamarín, Julián (2018) Obtention and characterization of lithium superionic conductors using the glass-ceramic method. DYNA, 85 (205). pp. 148-156. ISSN 2346-2183 |
| dc.rights.spa.fl_str_mv |
Derechos reservados - Universidad Nacional de Colombia |
| dc.rights.coar.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
| dc.rights.license.spa.fl_str_mv |
Atribución-NoComercial 4.0 Internacional |
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http://creativecommons.org/licenses/by-nc/4.0/ |
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info:eu-repo/semantics/openAccess |
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Atribución-NoComercial 4.0 Internacional Derechos reservados - Universidad Nacional de Colombia http://creativecommons.org/licenses/by-nc/4.0/ http://purl.org/coar/access_right/c_abf2 |
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openAccess |
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application/pdf |
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Universidad Nacional de Colombia - Sede Medellín - Facultad de Minas |
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Universidad Nacional de Colombia |
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Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Narváez-Semanate, Jose Luis575b7ed7-83ad-43ea-b9ab-a81181706281300Martins Rodrigues, Ana Cândida1d80bfe9-daf9-40e6-9973-aa626b79d4e2300Muñoz Meneses, Rodrigo Arbeyeefc731e-cec6-4677-9234-10bc9a95f5d9300Muñoz-Hoyos, José Rodrigo0f066429-c86c-4a83-9d78-797949a1fb8b300Villamarín, Juliánb5c17d7b-8b1c-469e-b18a-ac17da947f8d3002019-07-03T07:02:52Z2019-07-03T07:02:52Z2018-04-01ISSN: 2346-2183https://repositorio.unal.edu.co/handle/unal/68531http://bdigital.unal.edu.co/69564/This paper proposes the glass-ceramics method for obtaining lithium ion (Li+) solid electrolytes. This technique provides high chemical and microstructural homogeneity as well as low porosity. Glass samples were subjected to either single or double heat treatments, between 700 °C and 1000 °C, in order to obtain the glass-ceramics. Differential Scanning Calorimetry – DSC – results evidenced the possibility of fabricating these ceramics from glass in the system Li2O·Al2O3·TiO2·P2O5. Samples observed by Scanning Electron Microscopy – SEM – showed a finely grained microstructure which was homogeneously distributed and non-porous. X-ray Diffraction – XRD – patterns showed the formation of the high conducting phase LiTi2(PO4)3. A high ionic conductivity, in the order of 10-3 S/cm at 1000 °C, was measured by Impedance Spectroscopy – IS. It suggests that the synthesis method used in this research is useful for fabricating lithium ion glass-ceramics and opens up a new alternative for manufacturing different electrical ceramics.Este artículo propone la ruta vitrocerámica para obtener electrolitos sólidos por ion litio (Li+). Esta técnica provee alta homogeneidad química y microestructural, así como baja porosidad. Muestras vítreas fueron sometidas a tratamientos térmicos, simples y dobles, entre 700 °C y 1000 °C, para obtener las vitrocerámicas. Resultados de calorimetría diferencial de barrido – DSC – evidenciaron la posibilidad de fabricar estas cerámicas a partir de vidrios del sistema Li2O·Al2O3·TiO2·P2O5. Muestras observadas por microscopía electrónica de barrido – SEM – mostraron una microestructura de granos finos, homogéneamente distribuidos y sin porosidad. Patrones de difracción de rayos-x – XRD – permitieron verificar la formación de la fase altamente conductora LiTi2(PO4)3. Una conductividad iónica alta, del orden de 10-3 S/cm a 1000°C, fue medida utilizando espectroscopía de impedancia – IS. Lo anterior sugiere que el método de síntesis, utilizado en este trabajo, es útil para fabricar vitrocerámicas de ion litio y abre una nueva alternativa para fabricar diferentes cerámicas eléctricas.application/pdfspaUniversidad Nacional de Colombia - Sede Medellín - Facultad de Minashttps://revistas.unal.edu.co/index.php/dyna/article/view/70273Universidad Nacional de Colombia Revistas electrónicas UN DynaDynaNarváez-Semanate, Jose Luis and Martins Rodrigues, Ana Cândida and Muñoz Meneses, Rodrigo Arbey and Muñoz-Hoyos, José Rodrigo and Villamarín, Julián (2018) Obtention and characterization of lithium superionic conductors using the glass-ceramic method. DYNA, 85 (205). pp. 148-156. ISSN 2346-218362 Ingeniería y operaciones afines / Engineeringvitrocerámicasbaterías de ion litioespectroscopía de impedanciaconductores superiónicossistema Li2O·Al2O3·TiO2·P2O5glass-ceramicslithium ion batteriesimpedance spectroscopysuperionic conductorsLi2O·Al2O3·TiO2·P2O5 systemObtention and characterization of lithium superionic conductors using the glass-ceramic methodArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTORIGINAL70273-384404-1-PB.pdfapplication/pdf2294793https://repositorio.unal.edu.co/bitstream/unal/68531/1/70273-384404-1-PB.pdfd3f54e35041b9890be7d9d3fa1050be1MD51THUMBNAIL70273-384404-1-PB.pdf.jpg70273-384404-1-PB.pdf.jpgGenerated Thumbnailimage/jpeg9864https://repositorio.unal.edu.co/bitstream/unal/68531/2/70273-384404-1-PB.pdf.jpgee911c55ef411d273d0b1b3f6369c589MD52unal/68531oai:repositorio.unal.edu.co:unal/685312023-06-04 23:03:11.902Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co |