Formulación de una ruta químico enzimática para la producción de 5 – hidroximetilfurfural de manera sostenible a partir de fibra de maíz

ilustraciones, diagramas

Autores:: Romero Castaño, Juan Felipe

Tipo de recurso:

Fecha de publicación:: 2023

Institución:: Universidad Nacional de Colombia

Repositorio:: Universidad Nacional de Colombia

Idioma:: spa

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dc.title.spa.fl_str_mv	Formulación de una ruta químico enzimática para la producción de 5 – hidroximetilfurfural de manera sostenible a partir de fibra de maíz
dc.title.translated.eng.fl_str_mv	Formulation of an enzymatic chemical route for the production of 5 hydroxymethylfurfural in a sustainable way from corn fiber
title	Formulación de una ruta químico enzimática para la producción de 5 – hidroximetilfurfural de manera sostenible a partir de fibra de maíz
spellingShingle	Formulación de una ruta químico enzimática para la producción de 5 – hidroximetilfurfural de manera sostenible a partir de fibra de maíz 660 - Ingeniería química::661 - Tecnología de químicos industriales Biomasa vegetal Plant biomass 5 – hidroximetilfurfural biomasa lignocelulósica pretratamiento líquido iónico extracción reactiva modelamiento simulación Hydroxymethylfurfural Lignocellulosic biomass Pretreatment Pretreatment Ionic liquid Reactive extraction Modeling Simulation
title_short	Formulación de una ruta químico enzimática para la producción de 5 – hidroximetilfurfural de manera sostenible a partir de fibra de maíz
title_full	Formulación de una ruta químico enzimática para la producción de 5 – hidroximetilfurfural de manera sostenible a partir de fibra de maíz
title_fullStr	Formulación de una ruta químico enzimática para la producción de 5 – hidroximetilfurfural de manera sostenible a partir de fibra de maíz
title_full_unstemmed	Formulación de una ruta químico enzimática para la producción de 5 – hidroximetilfurfural de manera sostenible a partir de fibra de maíz
title_sort	Formulación de una ruta químico enzimática para la producción de 5 – hidroximetilfurfural de manera sostenible a partir de fibra de maíz
dc.creator.fl_str_mv	Romero Castaño, Juan Felipe
dc.contributor.advisor.none.fl_str_mv	Ruiz Colorado, Angela Adriana
dc.contributor.author.none.fl_str_mv	Romero Castaño, Juan Felipe
dc.contributor.researchgroup.spa.fl_str_mv	Bioprocesos y Flujos Reactivos
dc.subject.ddc.spa.fl_str_mv	660 - Ingeniería química::661 - Tecnología de químicos industriales
topic	660 - Ingeniería química::661 - Tecnología de químicos industriales Biomasa vegetal Plant biomass 5 – hidroximetilfurfural biomasa lignocelulósica pretratamiento líquido iónico extracción reactiva modelamiento simulación Hydroxymethylfurfural Lignocellulosic biomass Pretreatment Pretreatment Ionic liquid Reactive extraction Modeling Simulation
dc.subject.lemb.spa.fl_str_mv	Biomasa vegetal
dc.subject.lemb.eng.fl_str_mv	Plant biomass
dc.subject.proposal.spa.fl_str_mv	5 – hidroximetilfurfural biomasa lignocelulósica pretratamiento líquido iónico extracción reactiva modelamiento simulación
dc.subject.proposal.eng.fl_str_mv	Hydroxymethylfurfural Lignocellulosic biomass Pretreatment Pretreatment Ionic liquid Reactive extraction Modeling Simulation
description	ilustraciones, diagramas
publishDate	2023
dc.date.accessioned.none.fl_str_mv	2023-09-11T17:43:00Z
dc.date.available.none.fl_str_mv	2023-09-11T17:43:00Z
dc.date.issued.none.fl_str_mv	2023
dc.type.spa.fl_str_mv	Trabajo de grado - Maestría
dc.type.driver.spa.fl_str_mv	info:eu-repo/semantics/masterThesis
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dc.type.content.spa.fl_str_mv	Text
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dc.identifier.uri.none.fl_str_mv	https://repositorio.unal.edu.co/handle/unal/84688
dc.identifier.instname.spa.fl_str_mv	Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv	Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv	https://repositorio.unal.edu.co/
url	https://repositorio.unal.edu.co/handle/unal/84688 https://repositorio.unal.edu.co/
identifier_str_mv	Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv	spa
language	spa
dc.relation.indexed.spa.fl_str_mv	RedCol LaReferencia
dc.relation.references.spa.fl_str_mv	ABENGOA. (2016). Estructura y función de la lignina. http://www.laenergiadelcambio.com/estructura-funcion-lignina/ Acosta Pavas, J. C., Bonilla OSpina, N., Jaimes Cruz, L. J., Correa Cardona, H. J., Giraldo Mejía, Á. M., & Ruiz Colorado, A. A. (2021). Optimization of Liquid Hot Water Pretreatment on Sugarcane and Maralfalfa Grass for Glucose Production. SSRN Electronic Journal. https://doi.org/10.2139/ssrn.3946336 Acosta Zamora, E. A. (2014). Identificación del mecanismo de solvatación de biomasa lignocelulósica con líquidos iónicos. https://repositorio.unal.edu.co/handle/unal/72478#.YnrFCXx5h5w.mendeley Altway, S., Pujar, S. C., & de Haan, A. B. (2018). Liquid-liquid equilibria of ternary and quaternary systems involving 5-hydroxymethylfurfural, water, organic solvents, and salts at 313.15 K and atmospheric pressure. Fluid Phase Equilibria, 475, 100–110. https://doi.org/https://doi.org/10.1016/j.fluid.2018.07.034 Altway, S., Pujar, S. C., & de Haan, A. B. (2019). Effect of 1-ethyl-3-methylimidazolium tetrafluoroborate on the phase equilibria for systems containing 5hydroxymethylfurfural, water, organic solvent in the absence and presence of sodium chloride. The Journal of Chemical Thermodynamics, 132, 257–267. https://doi.org/https://doi.org/10.1016/j.jct.2019.01.001 Altway, S., Pujar, S. C., & de Haan, A. B. (2019). Effect of 1-ethyl-3-methylimidazolium tetrafluoroborate on the phase equilibria for systems containing 5hydroxymethylfurfural, water, organic solvent in the absence and presence of sodium chloride. The Journal of Chemical Thermodynamics, 132, 257–267. https://doi.org/https://doi.org/10.1016/j.jct.2019.01.001 Atanda, L., Konarova, M., Ma, Q., Mukundan, S., Shrotri, A., & Beltramini, J. (2016). High yield conversion of cellulosic biomass into 5-hydroxymethylfurfural and a study of the reaction kinetics of cellulose to HMF conversion in a biphasic system. 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Reframing biorefinery processing chain of corn fiber for cellulosic ethanol production. Industrial Crops and Products, 170, 113791. https://doi.org/https://doi.org/10.1016/j.indcrop.2021.113791 Zhang, S., Sheng, K., Chen, X., Zhang, X., & Mosier, N. S. (2021). Conversion of glucose to 5-hydroxymethyl furfural in water-acetonitrile-dimethyl sulfoxide solvent with aluminum on activated carbon and maleic acid. Industrial Crops and Products, 174, 114220. https://doi.org/https://doi.org/10.1016/j.indcrop.2021.114220 Zhang, T., Kumar, R., & Wyman, C. (2013). Enhanced yields of furfural and other products by simultaneous solvent extraction during thermochemical treatment of cellulosic biomass. RSC Adv., 3, 9809–9819. https://doi.org/10.1039/C3RA41857J Zhang, Y., Guo, X., Xu, J., Wu, Y., & Lu, M. (2018). Liquid–Liquid Equilibrium for Ternary Systems, Water + 5-Hydroxymethylfurfural + (1-Butanol, Isobutanol, Methyl Isobutyl Ketone), at 313.15, 323.15, and 333.15 K. 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dc.publisher.spa.fl_str_mv	Universidad Nacional de Colombia
dc.publisher.program.spa.fl_str_mv	Medellín - Minas - Maestría en Ingeniería - Ingeniería Química
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spelling	Reconocimiento 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Ruiz Colorado, Angela Adriana60ff4330d25ddf7e73e05a4feb6fa9feRomero Castaño, Juan Felipe993146a8308d05950d5a0fc7ea67e67aBioprocesos y Flujos Reactivos2023-09-11T17:43:00Z2023-09-11T17:43:00Z2023https://repositorio.unal.edu.co/handle/unal/84688Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, diagramasEl calentamiento global generado por la fuerte dependencia de los combustibles fósiles requiere de distintos tipos de soluciones, y entre las más prometedores se encuentra la obtención de productos químicos plataforma a partir de material residual lignocelulósico. En este trabajo se formula una ruta de producción sostenible del compuesto químico plataforma 5 – hidroximetilfurfural a partir de la biomasa lignocelulósica fibra de maíz. La ruta formulada consiste primero de un pretratamiento con líquido iónico en combinación con microondas, seguido de una hidrólisis enzimática para acceder a la glucosa estructural y finalmente una etapa de reacción y separación in situ en un sistema bifásico agua – orgánico conocida como extracción reactiva. Para concluir, se presenta el modelamiento y simulación de esta última etapa del proceso desarrollada en la literatura. (Texto tomado de la fuente)Global warming generated by the strong dependence on fossil fuels requires different types of solutions, and one of the most promising is to obtain platform chemicals from residual lignocellulosic material. In this work, a route for the sustainable production of the chemical compound platform 5 – hydroxymethylfurfural is formulated from the lignocellulosic biomass of corn fiber. The formulated route consists first of a pretreatment with ionic liquid in combination with microwaves, followed by an enzymatic hydrolysis to access the structural glucose and finally a reaction and separation step in situ in a biphasic waterorganic system known as reactive extraction. To conclude, the modeling and simulation of this last stage of the process developed in the literature is presented.MaestríaMagíster en Ingeniería - Ingeniería QuímicaLínea de Investigación: Metabolitos de valor agregado de biomasas Grupo de Investigación: Bioprocesos y Flujos Reactivos - BIOFRUNMetabolitos de valor agregado de biomasasÁrea curricular de Ingeniería Química e Ingeniería de Petróleos78 páginasapplication/pdfspaUniversidad Nacional de ColombiaMedellín - Minas - Maestría en Ingeniería - Ingeniería QuímicaFacultad de MinasMedellín, ColombiaUniversidad Nacional de Colombia - Sede Medellín660 - Ingeniería química::661 - Tecnología de químicos industrialesBiomasa vegetalPlant biomass5 – hidroximetilfurfuralbiomasa lignocelulósicapretratamientolíquido iónicoextracción reactivamodelamientosimulaciónHydroxymethylfurfuralLignocellulosic biomassPretreatmentPretreatmentIonic liquidReactive extractionModelingSimulationFormulación de una ruta químico enzimática para la producción de 5 – hidroximetilfurfural de manera sostenible a partir de fibra de maízFormulation of an enzymatic chemical route for the production of 5 hydroxymethylfurfural in a sustainable way from corn fiberTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMRedColLaReferenciaABENGOA. (2016). Estructura y función de la lignina. http://www.laenergiadelcambio.com/estructura-funcion-lignina/Acosta Pavas, J. C., Bonilla OSpina, N., Jaimes Cruz, L. J., Correa Cardona, H. J., Giraldo Mejía, Á. M., & Ruiz Colorado, A. A. (2021). Optimization of Liquid Hot Water Pretreatment on Sugarcane and Maralfalfa Grass for Glucose Production. SSRN Electronic Journal. https://doi.org/10.2139/ssrn.3946336Acosta Zamora, E. A. (2014). Identificación del mecanismo de solvatación de biomasa lignocelulósica con líquidos iónicos. https://repositorio.unal.edu.co/handle/unal/72478#.YnrFCXx5h5w.mendeleyAltway, S., Pujar, S. C., & de Haan, A. B. (2018). Liquid-liquid equilibria of ternary and quaternary systems involving 5-hydroxymethylfurfural, water, organic solvents, and salts at 313.15 K and atmospheric pressure. Fluid Phase Equilibria, 475, 100–110. https://doi.org/https://doi.org/10.1016/j.fluid.2018.07.034Altway, S., Pujar, S. C., & de Haan, A. B. (2019). 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Journal of Chemical & Engineering Data, 63(8), 2775–2782. https://doi.org/10.1021/acs.jced.8b00120EstudiantesGrupos comunitariosInvestigadoresMaestrosMedios de comunicaciónPúblico generalLICENSElicense.txtlicense.txttext/plain; charset=utf-85879https://repositorio.unal.edu.co/bitstream/unal/84688/1/license.txteb34b1cf90b7e1103fc9dfd26be24b4aMD51ORIGINAL1152460928.2023.pdf1152460928.2023.pdfTesis de Maestría en Ingeniería - Ingeniería Químicaapplication/pdf1740476https://repositorio.unal.edu.co/bitstream/unal/84688/2/1152460928.2023.pdf24341f87d172e3efb142a971f1b0f06aMD52THUMBNAIL1152460928.2023.pdf.jpg1152460928.2023.pdf.jpgGenerated Thumbnailimage/jpeg5532https://repositorio.unal.edu.co/bitstream/unal/84688/3/1152460928.2023.pdf.jpgf21a2de115140e67b15902d28abfcab2MD53unal/84688oai:repositorio.unal.edu.co:unal/846882023-09-11 23:03:26.77Repositorio Institucional Universidad Nacional de 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Formulación de una ruta químico enzimática para la producción de 5 – hidroximetilfurfural de manera sostenible a partir de fibra de maíz

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