Modelamiento y simulación de un reactor de hidrotratamiento para la producción de biodiésel no-éster

ilustraciones, gráficas, tablas

Autores:
Cortés Conde, Felix Fabián
Tipo de recurso:
Fecha de publicación:
2021
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/81095
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/81095
https://repositorio.unal.edu.co/
Palabra clave:
660 - Ingeniería química
Vegetable oils as fuel
Palm-oil
Chemical engineering
Aceites vegetales como combustibles
Aceites de palma
Ingeniería química
Biodiesel
Modelamiento
Reactor trickle bed
Aceite de palma
Biodiesel
Palm oil
Trickle bed reactor
Hydrotreatment
Rights
openAccess
License
Reconocimiento 4.0 Internacional
id UNACIONAL2_93ccee3e3b6f2a3037ae11b7bd540c74
oai_identifier_str oai:repositorio.unal.edu.co:unal/81095
network_acronym_str UNACIONAL2
network_name_str Universidad Nacional de Colombia
repository_id_str
dc.title.spa.fl_str_mv Modelamiento y simulación de un reactor de hidrotratamiento para la producción de biodiésel no-éster
dc.title.translated.eng.fl_str_mv Modeling and simulation of a hydrotreatment reactor for the production of non-ester biodiesel
title Modelamiento y simulación de un reactor de hidrotratamiento para la producción de biodiésel no-éster
spellingShingle Modelamiento y simulación de un reactor de hidrotratamiento para la producción de biodiésel no-éster
660 - Ingeniería química
Vegetable oils as fuel
Palm-oil
Chemical engineering
Aceites vegetales como combustibles
Aceites de palma
Ingeniería química
Biodiesel
Modelamiento
Reactor trickle bed
Aceite de palma
Biodiesel
Palm oil
Trickle bed reactor
Hydrotreatment
title_short Modelamiento y simulación de un reactor de hidrotratamiento para la producción de biodiésel no-éster
title_full Modelamiento y simulación de un reactor de hidrotratamiento para la producción de biodiésel no-éster
title_fullStr Modelamiento y simulación de un reactor de hidrotratamiento para la producción de biodiésel no-éster
title_full_unstemmed Modelamiento y simulación de un reactor de hidrotratamiento para la producción de biodiésel no-éster
title_sort Modelamiento y simulación de un reactor de hidrotratamiento para la producción de biodiésel no-éster
dc.creator.fl_str_mv Cortés Conde, Felix Fabián
dc.contributor.advisor.spa.fl_str_mv Oscar Yesid, Suárez Palacios
dc.contributor.author.spa.fl_str_mv Cortés Conde, Felix Fabián
dc.contributor.researchgroup.spa.fl_str_mv Grupo de Investigación en Procesos Químicos y Bioquímicos
dc.subject.ddc.spa.fl_str_mv 660 - Ingeniería química
topic 660 - Ingeniería química
Vegetable oils as fuel
Palm-oil
Chemical engineering
Aceites vegetales como combustibles
Aceites de palma
Ingeniería química
Biodiesel
Modelamiento
Reactor trickle bed
Aceite de palma
Biodiesel
Palm oil
Trickle bed reactor
Hydrotreatment
dc.subject.lemb.eng.fl_str_mv Vegetable oils as fuel
Palm-oil
Chemical engineering
dc.subject.lemb.spa.fl_str_mv Aceites vegetales como combustibles
Aceites de palma
Ingeniería química
dc.subject.proposal.spa.fl_str_mv Biodiesel
Modelamiento
Reactor trickle bed
Aceite de palma
dc.subject.proposal.eng.fl_str_mv Biodiesel
Palm oil
Trickle bed reactor
Hydrotreatment
description ilustraciones, gráficas, tablas
publishDate 2021
dc.date.issued.none.fl_str_mv 2021
dc.date.accessioned.none.fl_str_mv 2022-03-01T16:40:11Z
dc.date.available.none.fl_str_mv 2022-03-01T16:40:11Z
dc.type.spa.fl_str_mv Trabajo de grado - Maestría
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/masterThesis
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
dc.type.content.spa.fl_str_mv Text
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/TM
status_str acceptedVersion
dc.identifier.uri.none.fl_str_mv https://repositorio.unal.edu.co/handle/unal/81095
dc.identifier.instname.spa.fl_str_mv Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv https://repositorio.unal.edu.co/
url https://repositorio.unal.edu.co/handle/unal/81095
https://repositorio.unal.edu.co/
identifier_str_mv Universidad Nacional de Colombia
Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv spa
language spa
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dc.rights.license.spa.fl_str_mv Reconocimiento 4.0 Internacional
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dc.publisher.spa.fl_str_mv Universidad Nacional de Colombia
dc.publisher.program.spa.fl_str_mv Bogotá - Ingeniería - Maestría en Ingeniería - Ingeniería Química
dc.publisher.department.spa.fl_str_mv Departamento de Ingeniería Química y Ambiental
dc.publisher.faculty.spa.fl_str_mv Facultad de Ingeniería
dc.publisher.place.spa.fl_str_mv Bogotá, Colombia
dc.publisher.branch.spa.fl_str_mv Universidad Nacional de Colombia - Sede Bogotá
institution Universidad Nacional de Colombia
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spelling Reconocimiento 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Oscar Yesid, Suárez Palaciosef7976d2b572437b937e97b07deacc04600Cortés Conde, Felix Fabián0fc97c4fa550590117267e960249048b600Grupo de Investigación en Procesos Químicos y Bioquímicos2022-03-01T16:40:11Z2022-03-01T16:40:11Z2021https://repositorio.unal.edu.co/handle/unal/81095Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, gráficas, tablasLas materias primas derivadas biológicamente son una fuente altamente deseable de combustibles renovables para la producción de combustibles. Se pueden cultivar de forma renovable y pueden producir combustibles similares en composición a los combustibles fósiles convencionales. Los aceites vegetales al utilizar el hidrotratamiento catalítico reducen el contenido de oxígeno aumentando su viabilidad para su uso a nivel industrial. El proceso de hidrotratamiento de aceites vegetales es un proceso el cual depende en gran medida de la composición de la materia prima y de los parámetros de operación, especialmente de la temperatura, tipo de catalizador, propiedades de transporte. Para el aceite utilizado en el hidrotratamiento, las vías de reacción asociadas se han explorado a través de estudios experimentales proporcionando modelos aplicables para determinar la tasa de producción de los hidrocarburos. Se investiga el modelo de la triestearina-hidrógeno soportado sobre un catalizador, en un reactor no isotérmico, donde se calcula las velocidades de transferencia de masa gas-líquido y sólido-liquido por medio de las correlaciones de Fillion, Forghani y Treybal. Asimismo, para el cálculo de las velocidades de transferencia de masa se tomó como base teórica la teoría de la doble película, cuyas ecuaciones con los balances de masa y energía se resuelven simultáneamente utilizando técnicas numéricas cuya fiabilidad se evaluó mediante la comparación con resultados reportados en la literatura. El presente trabajo utiliza un reactor Trickle bed para representar el comportamiento en la producción de alcanos C17 y C18 para poder determinar las composiciones de la triestearina, acido esteárico, octadecano y heptadecano utilizando el modelo propuesto por Zhang y ajustar las constantes del modelo para obtener una mayor predicción del mecanismo de reacción. También, se investigó la distribución de la concentración y la temperatura a lo largo del reactor variando variables como la presión de hidrógeno y las velocidades de transferencia de masa de cada reacción involucrada en el modelamiento. (Texto tomado de la fuente).Biologically derived raw materials are a highly desirable source of renewable fuels for fuel production. They can be grown renewablely and can be used to produce fuels with similar composition compared to conventional fossil fuels. Vegetable oils raw material for this purpose have increased their viability for industrial use. The process of hydrotreatment of vegetable oils is a process which depends largely on the composition of the raw material and the operating parameters, especially the temperature, type of catalyst and transport properties. For the oil used in hydrotreatment, the associated reaction pathways have been explored through experimental studies providing applicable models to determine the rate of hydrocarbons production. The model of the reaction of triestearin with hydrogen with supported catalyst, in a non-isothermal reactor, is investigated. The gas-liquid and solid-liquid mass transfer rates are calculated with several correlations proposed by Forghani and Trybal correlations. Likewise, for the calculation of mass transfer velocities, the double film theory was taken as theoretical basis, whose equations with mass and energy balances are solved simultaneously using numerical techniques whose reliability was evaluated by comparison with results reported in the literature. The present work models a Trickle bed reactor to represent the production of alkanes C17 and C18 to determine the compositions of triestearine, stearic acid, octadecan and heptadecan using a chemical kinetic model proposed in other study and adjusting the constants of the model to obtain a better prediction of the concentrations. Also, the distribution of concentration and temperature throughout the reactor was calculated using variables such as hydrogen pressure and mass transfer rates of each reaction involved in modeling.MaestríaMagíster en Ingeniería - Ingeniería QuímicaBiorrefinería y biorrefinaciónxx, 90 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ingeniería - Maestría en Ingeniería - Ingeniería QuímicaDepartamento de Ingeniería Química y AmbientalFacultad de IngenieríaBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá660 - Ingeniería químicaVegetable oils as fuelPalm-oilChemical engineeringAceites vegetales como combustiblesAceites de palmaIngeniería químicaBiodieselModelamientoReactor trickle bedAceite de palmaBiodieselPalm oilTrickle bed reactorHydrotreatmentModelamiento y simulación de un reactor de hidrotratamiento para la producción de biodiésel no-ésterModeling and simulation of a hydrotreatment reactor for the production of non-ester biodieselTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMAli, M. 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Industrial & Engineering Chemistry Research, 1-37.EstudiantesGrupos comunitariosInvestigadoresMaestrosPúblico generalORIGINAL1022345193.2022.pdf1022345193.2022.pdfTesis de Maestría en Ingeniería - Ingeniería Químicaapplication/pdf1921851https://repositorio.unal.edu.co/bitstream/unal/81095/3/1022345193.2022.pdf72ceebeaa340b80c4fdbd1a72fd78a9cMD53LICENSElicense.txtlicense.txttext/plain; charset=utf-84074https://repositorio.unal.edu.co/bitstream/unal/81095/4/license.txt8153f7789df02f0a4c9e079953658ab2MD54THUMBNAIL1022345193.2022.pdf.jpg1022345193.2022.pdf.jpgGenerated Thumbnailimage/jpeg4360https://repositorio.unal.edu.co/bitstream/unal/81095/5/1022345193.2022.pdf.jpg59e9656584faae647beb21c1bc63da25MD55unal/81095oai:repositorio.unal.edu.co:unal/810952024-08-03 23:10:38.414Repositorio Institucional Universidad Nacional de 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EVESURBIFBPUiBMQSBTRUNSRVRBUsONQSBHRU5FUkFMLiAqTEEgVEVTSVMgQSBQVUJMSUNBUiBERUJFIFNFUiBMQSBWRVJTScOTTiBGSU5BTCBBUFJPQkFEQS4gCgpBbCBoYWNlciBjbGljIGVuIGVsIHNpZ3VpZW50ZSBib3TDs24sIHVzdGVkIGluZGljYSBxdWUgZXN0w6EgZGUgYWN1ZXJkbyBjb24gZXN0b3MgdMOpcm1pbm9zLiBTaSB0aWVuZSBhbGd1bmEgZHVkYSBzb2JyZSBsYSBsaWNlbmNpYSwgcG9yIGZhdm9yLCBjb250YWN0ZSBjb24gZWwgYWRtaW5pc3RyYWRvciBkZWwgc2lzdGVtYS4KClVOSVZFUlNJREFEIE5BQ0lPTkFMIERFIENPTE9NQklBIC0gw5psdGltYSBtb2RpZmljYWNpw7NuIDE5LzEwLzIwMjEK

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