Production of carbon nanotubes and hydrogen by catalytic ethanol decomposition

This work reports the synthesis of multiwall carbon nanotubes (MWCNTs) by the catalytic decomposition of ethanol using the perovskite-type oxide LaNiO3 as catalyst precursor. The carbon nanotubes were characterized by transmission electronic microscopy (TEM), scanning electronic microscopy (SEM) and...

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Autores:
Gallego, Jaime
Sierra Gallego, Germán
Daza, Carlos
Molina, Rafael
Barrault, Joël
Batiot Dupeyat, Catherine
Mondragón, Fanor
Tipo de recurso:
Article of journal
Fecha de publicación:
2013
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/39880
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/39880
http://bdigital.unal.edu.co/29977/
Palabra clave:
Carbon nanotubes
perovskites
nickel
hydrogen
ethanol decomposition
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional
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spelling Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Gallego, Jaime577fdb21-9ed1-431c-b5a9-e39b62efa0a9300Sierra Gallego, Germánd12d7e75-dfe4-4bb5-a2a1-de626f2a24b7300Daza, Carlos40e5dd7a-04ce-4d6d-ab5a-2408dd7ab4c0300Molina, Rafael070c1158-3cb2-4586-8a9f-e1f69b546b41300Barrault, Joël1b3dbdcb-7c21-433e-a887-43f606bf6172300Batiot Dupeyat, Catherined0cdf43c-217e-46f6-9dc1-06e42f83010b300Mondragón, Fanora0c9d798-edf2-40b2-8e35-64a77e6998933002019-06-28T04:36:25Z2019-06-28T04:36:25Z2013https://repositorio.unal.edu.co/handle/unal/39880http://bdigital.unal.edu.co/29977/This work reports the synthesis of multiwall carbon nanotubes (MWCNTs) by the catalytic decomposition of ethanol using the perovskite-type oxide LaNiO3 as catalyst precursor. The carbon nanotubes were characterized by transmission electronic microscopy (TEM), scanning electronic microscopy (SEM) and thermogravimetric analysis (TGA). TEM micrographs show that the carbon nanotubes were multi-walled with inner diameters ranging from 3 nm to 12 nm and outer diameters up to 42 nm. The yield of CNT and H2 were 3.5 gCNT?(gcat?h)-1 and 39 LH2?(g?h)-1 respectively at 700 °C. TGA data show that nanotube carbon purity was about 95 % by weight and the oxidation temperature was around 620 °C.application/pdfspaUniversidad Nacional de Colombia Sede Medellínhttp://revistas.unal.edu.co/index.php/dyna/article/view/28717Universidad Nacional de Colombia Revistas electrónicas UN DynaDynaDyna; Vol. 80, núm. 178 (2013); 78-85 DYNA; Vol. 80, núm. 178 (2013); 78-85 2346-2183 0012-7353Gallego, Jaime and Sierra Gallego, Germán and Daza, Carlos and Molina, Rafael and Barrault, Joël and Batiot Dupeyat, Catherine and Mondragón, Fanor (2013) Production of carbon nanotubes and hydrogen by catalytic ethanol decomposition. Dyna; Vol. 80, núm. 178 (2013); 78-85 DYNA; Vol. 80, núm. 178 (2013); 78-85 2346-2183 0012-7353 .Production of carbon nanotubes and hydrogen by catalytic ethanol decompositionArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTCarbon nanotubesperovskitesnickelhydrogenethanol decompositionORIGINAL28717-167424-1-PB.pdfapplication/pdf1604651https://repositorio.unal.edu.co/bitstream/unal/39880/1/28717-167424-1-PB.pdf3c89436c4ceeb765585626c32fb4bb6bMD5128717-102853-1-SP.docapplication/msword358912https://repositorio.unal.edu.co/bitstream/unal/39880/2/28717-102853-1-SP.docbbb5749091cbd6a9e004a82c0c7f1badMD5228717-197849-1-PB.htmltext/html33946https://repositorio.unal.edu.co/bitstream/unal/39880/3/28717-197849-1-PB.html21e7f194ae9a1366f03042154ce9bea1MD53THUMBNAIL28717-167424-1-PB.pdf.jpg28717-167424-1-PB.pdf.jpgGenerated Thumbnailimage/jpeg9143https://repositorio.unal.edu.co/bitstream/unal/39880/4/28717-167424-1-PB.pdf.jpg62ff147a11e70b1e0fcc70d699d57913MD54unal/39880oai:repositorio.unal.edu.co:unal/398802024-01-22 23:06:06.634Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co
dc.title.spa.fl_str_mv Production of carbon nanotubes and hydrogen by catalytic ethanol decomposition
title Production of carbon nanotubes and hydrogen by catalytic ethanol decomposition
spellingShingle Production of carbon nanotubes and hydrogen by catalytic ethanol decomposition
Carbon nanotubes
perovskites
nickel
hydrogen
ethanol decomposition
title_short Production of carbon nanotubes and hydrogen by catalytic ethanol decomposition
title_full Production of carbon nanotubes and hydrogen by catalytic ethanol decomposition
title_fullStr Production of carbon nanotubes and hydrogen by catalytic ethanol decomposition
title_full_unstemmed Production of carbon nanotubes and hydrogen by catalytic ethanol decomposition
title_sort Production of carbon nanotubes and hydrogen by catalytic ethanol decomposition
dc.creator.fl_str_mv Gallego, Jaime
Sierra Gallego, Germán
Daza, Carlos
Molina, Rafael
Barrault, Joël
Batiot Dupeyat, Catherine
Mondragón, Fanor
dc.contributor.author.spa.fl_str_mv Gallego, Jaime
Sierra Gallego, Germán
Daza, Carlos
Molina, Rafael
Barrault, Joël
Batiot Dupeyat, Catherine
Mondragón, Fanor
dc.subject.proposal.spa.fl_str_mv Carbon nanotubes
perovskites
nickel
hydrogen
ethanol decomposition
topic Carbon nanotubes
perovskites
nickel
hydrogen
ethanol decomposition
description This work reports the synthesis of multiwall carbon nanotubes (MWCNTs) by the catalytic decomposition of ethanol using the perovskite-type oxide LaNiO3 as catalyst precursor. The carbon nanotubes were characterized by transmission electronic microscopy (TEM), scanning electronic microscopy (SEM) and thermogravimetric analysis (TGA). TEM micrographs show that the carbon nanotubes were multi-walled with inner diameters ranging from 3 nm to 12 nm and outer diameters up to 42 nm. The yield of CNT and H2 were 3.5 gCNT?(gcat?h)-1 and 39 LH2?(g?h)-1 respectively at 700 °C. TGA data show that nanotube carbon purity was about 95 % by weight and the oxidation temperature was around 620 °C.
publishDate 2013
dc.date.issued.spa.fl_str_mv 2013
dc.date.accessioned.spa.fl_str_mv 2019-06-28T04:36:25Z
dc.date.available.spa.fl_str_mv 2019-06-28T04:36:25Z
dc.type.spa.fl_str_mv Artículo de revista
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url https://repositorio.unal.edu.co/handle/unal/39880
http://bdigital.unal.edu.co/29977/
dc.language.iso.spa.fl_str_mv spa
language spa
dc.relation.spa.fl_str_mv http://revistas.unal.edu.co/index.php/dyna/article/view/28717
dc.relation.ispartof.spa.fl_str_mv Universidad Nacional de Colombia Revistas electrónicas UN Dyna
Dyna
dc.relation.ispartofseries.none.fl_str_mv Dyna; Vol. 80, núm. 178 (2013); 78-85 DYNA; Vol. 80, núm. 178 (2013); 78-85 2346-2183 0012-7353
dc.relation.references.spa.fl_str_mv Gallego, Jaime and Sierra Gallego, Germán and Daza, Carlos and Molina, Rafael and Barrault, Joël and Batiot Dupeyat, Catherine and Mondragón, Fanor (2013) Production of carbon nanotubes and hydrogen by catalytic ethanol decomposition. Dyna; Vol. 80, núm. 178 (2013); 78-85 DYNA; Vol. 80, núm. 178 (2013); 78-85 2346-2183 0012-7353 .
dc.rights.spa.fl_str_mv Derechos reservados - Universidad Nacional de Colombia
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dc.rights.license.spa.fl_str_mv Atribución-NoComercial 4.0 Internacional
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dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv Atribución-NoComercial 4.0 Internacional
Derechos reservados - Universidad Nacional de Colombia
http://creativecommons.org/licenses/by-nc/4.0/
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
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