Síntesis y caracterización de recubrimientos compuestos de Ni-P-VC depositados mediante niquelado químico sobre fundición nodular Austemperizada
Ilustraciones, fotografías a blanco y negro, fotografías a color,
- Autores:
-
Ortiz Godoy, Nicolás
- Tipo de recurso:
- Fecha de publicación:
- 2023
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/82975
- Palabra clave:
- 620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingeniería
Deterioración de materiales
Materials - deterioration
Austempering
Austemperado
codeposición
niquelado químico compuesto
material ADI
resistencia al desgaste
- Rights
- openAccess
- License
- Atribución-NoComercial-SinDerivadas 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Síntesis y caracterización de recubrimientos compuestos de Ni-P-VC depositados mediante niquelado químico sobre fundición nodular Austemperizada |
| dc.title.translated.eng.fl_str_mv |
Synthesis and characterization of Ni-P-VC composite coatings deposited by electroless nickel plating on Austempered nodular cast iron. |
| title |
Síntesis y caracterización de recubrimientos compuestos de Ni-P-VC depositados mediante niquelado químico sobre fundición nodular Austemperizada |
| spellingShingle |
Síntesis y caracterización de recubrimientos compuestos de Ni-P-VC depositados mediante niquelado químico sobre fundición nodular Austemperizada 620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingeniería Deterioración de materiales Materials - deterioration Austempering Austemperado codeposición niquelado químico compuesto material ADI resistencia al desgaste |
| title_short |
Síntesis y caracterización de recubrimientos compuestos de Ni-P-VC depositados mediante niquelado químico sobre fundición nodular Austemperizada |
| title_full |
Síntesis y caracterización de recubrimientos compuestos de Ni-P-VC depositados mediante niquelado químico sobre fundición nodular Austemperizada |
| title_fullStr |
Síntesis y caracterización de recubrimientos compuestos de Ni-P-VC depositados mediante niquelado químico sobre fundición nodular Austemperizada |
| title_full_unstemmed |
Síntesis y caracterización de recubrimientos compuestos de Ni-P-VC depositados mediante niquelado químico sobre fundición nodular Austemperizada |
| title_sort |
Síntesis y caracterización de recubrimientos compuestos de Ni-P-VC depositados mediante niquelado químico sobre fundición nodular Austemperizada |
| dc.creator.fl_str_mv |
Ortiz Godoy, Nicolás |
| dc.contributor.advisor.none.fl_str_mv |
Ortiz Godoy, Nicolás |
| dc.contributor.author.none.fl_str_mv |
Ortiz Godoy, Nicolás |
| dc.contributor.researchgroup.spa.fl_str_mv |
Análisis de falla, integridad y superficies AFIS |
| dc.contributor.orcid.spa.fl_str_mv |
0000000344684603 |
| dc.contributor.cvlac.spa.fl_str_mv |
Nicolas Ortiz Godoy |
| dc.contributor.researchgate.spa.fl_str_mv |
Nicolas Ortiz Godoy |
| dc.contributor.googlescholar.spa.fl_str_mv |
Nicolas Ortiz Godoy |
| dc.subject.ddc.spa.fl_str_mv |
620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingeniería |
| topic |
620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingeniería Deterioración de materiales Materials - deterioration Austempering Austemperado codeposición niquelado químico compuesto material ADI resistencia al desgaste |
| dc.subject.lemb.spa.fl_str_mv |
Deterioración de materiales |
| dc.subject.lemb.eng.fl_str_mv |
Materials - deterioration |
| dc.subject.proposal.eng.fl_str_mv |
Austempering |
| dc.subject.proposal.spa.fl_str_mv |
Austemperado codeposición niquelado químico compuesto material ADI resistencia al desgaste |
| description |
Ilustraciones, fotografías a blanco y negro, fotografías a color, |
| publishDate |
2023 |
| dc.date.accessioned.none.fl_str_mv |
2023-01-17T13:51:40Z |
| dc.date.available.none.fl_str_mv |
2023-01-17T13:51:40Z |
| dc.date.issued.none.fl_str_mv |
2023-01-16 |
| dc.type.spa.fl_str_mv |
Trabajo de grado - Maestría |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/masterThesis |
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info:eu-repo/semantics/acceptedVersion |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/TM |
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acceptedVersion |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/82975 |
| dc.identifier.instname.spa.fl_str_mv |
Universidad Nacional de Colombia |
| dc.identifier.reponame.spa.fl_str_mv |
Repositorio Institucional Universidad Nacional de Colombia |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.unal.edu.co/ |
| url |
https://repositorio.unal.edu.co/handle/unal/82975 https://repositorio.unal.edu.co/ |
| identifier_str_mv |
Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia |
| dc.language.iso.spa.fl_str_mv |
spa |
| language |
spa |
| dc.relation.references.spa.fl_str_mv |
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Krishnaveni, and S. Parthiban, “Deposition of electroless Ni-P graded coatings and evaluation of their corrosion resistance,” Surf Coat Technol, vol. 200, no. 11, pp. 3438–3445, 2006, doi: 10.1016/j.surfcoat.2004.10.014. |
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Atribución-NoComercial-SinDerivadas 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Ortiz Godoy, Nicolásb3141f0fb5d548012ccbe187dbe7c998Ortiz Godoy, Nicolásb3141f0fb5d548012ccbe187dbe7c998Análisis de falla, integridad y superficies AFIS0000000344684603Nicolas Ortiz GodoyNicolas Ortiz GodoyNicolas Ortiz Godoy2023-01-17T13:51:40Z2023-01-17T13:51:40Z2023-01-16https://repositorio.unal.edu.co/handle/unal/82975Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/Ilustraciones, fotografías a blanco y negro, fotografías a color,Las piezas de ingeniería usadas en la industria automotriz como ejes, cardanes, bielas, cigüeñales, engranajes y calipers, entre otros, son fabricados en material ADI, estas piezas están sometidas principalmente a condiciones de desgaste y corrosión. El objetivo principal de esta investigación es alargar la vida útil de componentes de ingeniería de material ADI, mediante la mejora de la resistencia al desgaste y a la corrosión del sustrato, al implementar recubrimientos compuestos de Ni-P-VC usando la técnica de niquelado químico. El material ADI fue obtenido mediante la aplicación de un tratamiento térmico de Austempering en una fundición nodular grado 2, y los recubrimientos fueron obtenidos mediante la técnica de niquelado químico compuesto, realizando la coprecipitación de las partículas de VC mediante un procedimiento de bajo impacto ambiental, variando el tiempo de inmersión en el baño químico para obtener distintos espesores de recubrimiento. El sustrato y los recubrimientos fueron caracterizados estructuralmente mediante difracción de rayos X (XRD), morfológicamente mediante microscopia óptica y microscopia electrónica de barrido (SEM), rugosidad de los recubrimientos mediante interferometría, química elemental mediante (EDS) y espectroscopia de emisión óptica, la dureza mediante dureza HRC y microdureza HV, desgaste mediante Pin On Disk, adherencia mediante Scratch y electroquímica mediante EIS y TAFEL. Se encontró que los recubrimientos tienen una dureza de hasta 1013.9 ± 10 HV, presentando superficies homogéneas. Los recubrimientos con un tiempo mayor de inmersión obtuvieron un porcentaje mayor de partículas de VC y un espesor de 35 µm los cuales presentan una mejor resistencia al desgaste y a la corrosión, mejorando la resistencia al desgaste y corrosión del sustrato de material ADI en un 4772 % y 259 % respectivamente, con una tasa de desgaste de 3,14〖x10〗^(-8) 〖mm〗^3⁄Nmm y potencial de corrosión de -22 V. (Texto tomado de la fuente)The engineering parts used in the automotive industry such as axles, cardan shafts, connecting rods, crankshafts, gears and calipers, among others, are manufactured in ADI material, these parts are mainly subjected to wear and corrosion conditions. The main objective of this research is to extend the service life of engineering components made of ADI material, by improving the wear and corrosion resistance of the substrate, by implementing Ni-P-VC composite coatings using the electroless nickel plating technique. The ADI material was obtained by applying an Austempering heat treatment on a grade 2 nodular cast iron, and the coatings were obtained using the composite electroless nickel plating technique, performing the co-precipitation of VC particles using a low environmental impact procedure, varying the immersion time in the chemical bath to obtain different coating thicknesses. The substrate and coatings were characterized structurally by X-ray diffraction (XRD), morphologically by optical microscopy and scanning electron microscopy (SEM), roughness of the coatings by interferometry, elemental chemistry by (EDS) and optical emission spectroscopy, hardness by hardness HRC and microhardness HV, wear by Pin On Disk, adhesion by Scratch and electrochemistry by EIS and TAFEL. The coatings were found to have hardness up to 1013.9 ±10 HV, with homogeneous surfaces. The coatings with longer immersion time obtained a higher percentage of VC particles and a thickness of 35 µm present better wear and corrosion resistance, improving the wear and corrosion resistance of the 4772 % y 259 % respectively, with a wear rate of 3,14〖x10〗^(-8) 〖mm〗^3⁄Nmm and corrosion potential of -22 V.MaestríaMagíster en Ingeniería - Materiales y ProcesosPara el desarrollo de este trabajo se tienen en cuenta todas las variables de entrada que afectan directamente los resultados en este trabajo, las cuales son: La composición del recubrimiento, Ni-P y Ni-P-VC, y el espesor de los recubrimientos. Por lo tanto, este es un diseño factorial con dos factores de variación. Se debe establecer el error experimental y el grado de confiabilidad para elegir así la cantidad de repeticiones necesarias al realizar cada experimentación, para lo cual es necesario realizar una prueba piloto o realizar una búsqueda bibliográfica que permita determinar este parámetro [77]. Al realizar la revisión bibliográfica, de artículos y tesis en los que se realizaran procedimientos en los cuales se tienen deposición de recubrimientos mediante niquelado químico, utilizaron un número de repeticiones de los ensayos de entre 3 y 5 veces [35], [94], [45], [52], [95].Ingeniería de superficiesxviii, 95 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ingeniería - Maestría en Ingeniería - Materiales y ProcesosFacultad de IngenieríaBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingenieríaDeterioración de materialesMaterials - deteriorationAustemperingAustemperadocodeposiciónniquelado químico compuestomaterial ADIresistencia al desgasteSíntesis y caracterización de recubrimientos compuestos de Ni-P-VC depositados mediante niquelado químico sobre fundición nodular AustemperizadaSynthesis and characterization of Ni-P-VC composite coatings deposited by electroless nickel plating on Austempered nodular cast iron.Trabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TM[1] A. 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Parthiban, “Deposition of electroless Ni-P graded coatings and evaluation of their corrosion resistance,” Surf Coat Technol, vol. 200, no. 11, pp. 3438–3445, 2006, doi: 10.1016/j.surfcoat.2004.10.014.LICENSElicense.txtlicense.txttext/plain; charset=utf-85879https://repositorio.unal.edu.co/bitstream/unal/82975/1/license.txteb34b1cf90b7e1103fc9dfd26be24b4aMD51ORIGINALSíntesis y caracterización de recubrimientos compuestos de Ni-P-VC.pdfSíntesis y caracterización de recubrimientos compuestos de Ni-P-VC.pdfTesis de Maestría en Ingenieria - Materiales y Procesosapplication/pdf4916593https://repositorio.unal.edu.co/bitstream/unal/82975/2/S%c3%adntesis%20y%20caracterizaci%c3%b3n%20de%20recubrimientos%20compuestos%20de%20Ni-P-VC.pdf6beed8fe361338fba81d11b57dec58beMD52THUMBNAILSíntesis y caracterización de recubrimientos compuestos de Ni-P-VC.pdf.jpgSíntesis y caracterización de recubrimientos compuestos de Ni-P-VC.pdf.jpgGenerated 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