Biobased plasticizer from agroindustrial residual streams
ilustraciones, fotografías, graficas
- Autores:
-
Nájera Losada, Laura Nathalia
- Tipo de recurso:
- Fecha de publicación:
- 2023
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/83816
- Palabra clave:
- 660 - Ingeniería química
PRODUCTOS DE RESIDUOS
INDUSTRIAS DE PLASTICOS
Waste products
Plastics industry and trade
Esterificación
Acidos grasos
Destilado desodorizado de aceite de soya
Isobutanol
Epoxidación
Esteres de isobutilo epoxidados
Cinética
Plastificante
PVC
Esterification
Fatty acids
Soybean oil deodorizer distillate
Isobutanol
Epoxidation
Epoxidized isobutyl esters
Kinetics
Plasticizer
PVC
- Rights
- openAccess
- License
- Atribución-NoComercial-SinDerivadas 4.0 Internacional
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| dc.title.eng.fl_str_mv |
Biobased plasticizer from agroindustrial residual streams |
| dc.title.translated.spa.fl_str_mv |
Plastificante biobasado obtenido a partir de corrientes residuales agroindustriales |
| title |
Biobased plasticizer from agroindustrial residual streams |
| spellingShingle |
Biobased plasticizer from agroindustrial residual streams 660 - Ingeniería química PRODUCTOS DE RESIDUOS INDUSTRIAS DE PLASTICOS Waste products Plastics industry and trade Esterificación Acidos grasos Destilado desodorizado de aceite de soya Isobutanol Epoxidación Esteres de isobutilo epoxidados Cinética Plastificante PVC Esterification Fatty acids Soybean oil deodorizer distillate Isobutanol Epoxidation Epoxidized isobutyl esters Kinetics Plasticizer PVC |
| title_short |
Biobased plasticizer from agroindustrial residual streams |
| title_full |
Biobased plasticizer from agroindustrial residual streams |
| title_fullStr |
Biobased plasticizer from agroindustrial residual streams |
| title_full_unstemmed |
Biobased plasticizer from agroindustrial residual streams |
| title_sort |
Biobased plasticizer from agroindustrial residual streams |
| dc.creator.fl_str_mv |
Nájera Losada, Laura Nathalia |
| dc.contributor.advisor.none.fl_str_mv |
Orjuela Londoño, Alvaro Narvaez Rincon, Paulo Cesar |
| dc.contributor.author.none.fl_str_mv |
Nájera Losada, Laura Nathalia |
| dc.contributor.researchgroup.spa.fl_str_mv |
Grupo de investigación en procesos químicos y bioquímicos |
| dc.subject.ddc.spa.fl_str_mv |
660 - Ingeniería química |
| topic |
660 - Ingeniería química PRODUCTOS DE RESIDUOS INDUSTRIAS DE PLASTICOS Waste products Plastics industry and trade Esterificación Acidos grasos Destilado desodorizado de aceite de soya Isobutanol Epoxidación Esteres de isobutilo epoxidados Cinética Plastificante PVC Esterification Fatty acids Soybean oil deodorizer distillate Isobutanol Epoxidation Epoxidized isobutyl esters Kinetics Plasticizer PVC |
| dc.subject.lemb.spa.fl_str_mv |
PRODUCTOS DE RESIDUOS INDUSTRIAS DE PLASTICOS |
| dc.subject.lemb.eng.fl_str_mv |
Waste products Plastics industry and trade |
| dc.subject.proposal.spa.fl_str_mv |
Esterificación Acidos grasos Destilado desodorizado de aceite de soya Isobutanol Epoxidación Esteres de isobutilo epoxidados Cinética Plastificante PVC |
| dc.subject.proposal.eng.fl_str_mv |
Esterification Fatty acids Soybean oil deodorizer distillate Isobutanol Epoxidation Epoxidized isobutyl esters Kinetics Plasticizer PVC |
| description |
ilustraciones, fotografías, graficas |
| publishDate |
2023 |
| dc.date.accessioned.none.fl_str_mv |
2023-05-17T20:30:32Z |
| dc.date.available.none.fl_str_mv |
2023-05-17T20:30:32Z |
| dc.date.issued.none.fl_str_mv |
2023-05-17 |
| dc.type.spa.fl_str_mv |
Trabajo de grado - Maestría |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/masterThesis |
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info:eu-repo/semantics/acceptedVersion |
| dc.type.content.spa.fl_str_mv |
Text |
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http://purl.org/redcol/resource_type/TM |
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acceptedVersion |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/83816 |
| dc.identifier.instname.spa.fl_str_mv |
Universidad Nacional de Colombia |
| dc.identifier.reponame.spa.fl_str_mv |
Repositorio Institucional Universidad Nacional de Colombia |
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https://repositorio.unal.edu.co/ |
| url |
https://repositorio.unal.edu.co/handle/unal/83816 https://repositorio.unal.edu.co/ |
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Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.references.spa.fl_str_mv |
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Atribución-NoComercial-SinDerivadas 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Orjuela Londoño, Alvaroa583c5015d0fe88a7d62aa2891228b13600Narvaez Rincon, Paulo Cesar22477493aa08b1516693b84f069835dc600Nájera Losada, Laura Nathaliadd3407c306fa0864f64d82f74398351fGrupo de investigación en procesos químicos y bioquímicos2023-05-17T20:30:32Z2023-05-17T20:30:32Z2023-05-17https://repositorio.unal.edu.co/handle/unal/83816Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, fotografías, graficasBiobased plasticizer from agro-industrial residual streams Soybean Oil Deodorizer Distillate (SODD) is a valuable agro-industrial waste stream that can be used as feedstock for a wide range of oleochemicals. In this regard, this work evaluates the production of biobased green plasticizers from SODD. A potential oleochemical plasticizer was selected through a computer-aided product design method that performed a screening of potential candidate molecules by assessing different criteria associated to their plasticizing performance. The selected criteria were compatibility, efficiency, permanence, toxicity, and cost, which were predicted for the potential molecule candidates using group contribution methods and empirical correlations. As a result of the screening method, epoxidized isobutyl esters were found to be the most promising plasticizers for polymers such as PVC. Subsequently, isobutyl fatty ester epoxides were produced experimentally using a two-step reaction process: esterification and epoxidation. Additionally, a kinetic model of the epoxidation of isobutyl esters was obtained and the influence of reaction conditions on selectivity, efficiency, and yield was studied. As a result, the best operating conditions for the synthesis of epoxidized isobutyl fatty esters were determined. Finally, the performance of the assessed epoxides as plasticizers for PVC was evaluated in terms of mechanical, optical, rheological, and barrier properties. These epoxides exhibited exceptional mechanical performance and thermal stability compared to traditional petrochemical plasticizers (i.e. phthalates). However, in terms of overall performance, they cannot be considered as general-purpose plasticizers and are expected to be used in specific applications.El destilado del desodorizado de aceite de soya (SODD) es un residuo agroindustrial que se puede utilizar como materia prima para obtener un amplio espectro de productos oleoquímicos. En esta dirección, se realizó inicialmente la selección de un derivado oleoquímico con potencial plastificante mediante un método de diseño de producto asistido por computador. Este método permitió realizar una selección entre moléculas potencialmente útiles mediante la evaluación de diferentes criterios asociados con su desempeño como plastificante. Los criterios seleccionados fueron compatibilidad, eficiencia, permanencia, toxicidad y costo. Estos criterios se predijeron para las moléculas candidatas utilizando métodos de contribución de grupo y correlaciones empíricas. Como resultado del método de selección, se encontró que los ésteres de isobutilo epoxidados pueden ser plastificantes promisorios para polímeros como el PVC. Posteriormente, los epóxidos de ésteres grasos de isobutilo se produjeron experimentalmente utilizando un proceso de reacción de dos pasos: esterificación y epoxidación. Además, se obtuvo un modelo cinético de epoxidación de ésteres de isobutilo y se estudió la influencia de las condiciones de reacción sobre la selectividad, la eficiencia y el rendimiento. Como resultado, se obtuvieron las mejores condiciones de operación para la síntesis de ésteres grasos de isobutilo epoxidados. Finalmente, se evaluó el desempeño de los epóxidos isobutílicos como plastificantes para PVC en términos de propiedades mecánicas, ópticas, reológicas y de barrera. Estos epóxidos mostraron un rendimiento mecánico y una estabilidad térmica excepcional en comparación con los plastificantes petroquímicos tradicionales (es decir, los ftalatos). No obstante, en cuanto a su desempeño general, no pueden ser considerados como plastificantes de uso general y se espera que puedan ser utilizados en aplicaciones específicas. (Texto tomado de la fuente)MaestríaMagíster en Ingeniería - Ingeniería QuímicaOleochemical processesxvii, 143 páginasapplication/pdfengUniversidad Nacional de ColombiaBogotá - Ingeniería - Maestría en Ingeniería - Ingeniería QuímicaFacultad de IngenieríaBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá660 - Ingeniería químicaPRODUCTOS DE RESIDUOSINDUSTRIAS DE PLASTICOSWaste productsPlastics industry and tradeEsterificaciónAcidos grasosDestilado desodorizado de aceite de soyaIsobutanolEpoxidaciónEsteres de isobutilo epoxidadosCinéticaPlastificantePVCEsterificationFatty acidsSoybean oil deodorizer distillateIsobutanolEpoxidationEpoxidized isobutyl estersKineticsPlasticizerPVCBiobased plasticizer from agroindustrial residual streamsPlastificante biobasado obtenido a partir de corrientes residuales agroindustrialesTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMA. D. 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