Estudio isotópico de carbono (δ13C) en carbones colombianos y su relación con las propiedades fisicoquímicas para la identificación de procesos biogeoquímicos asociados a sus ambientes de formación
ilustraciones, diagramas, fotografías a color, mapas
- Autores:
-
Moreno Forero, Maribel
- Tipo de recurso:
- Fecha de publicación:
- 2023
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/84350
- Palabra clave:
- 540 - Química y ciencias afines::543 - Química analítica
Fenómenos químicos
Chemical Phenomena
Ciclos biogeoquímicos
Ciclo del carbono (biogeoquímica)
Biogeochemical cycles
Carbon cycle (biogeochemistry)
Isótopos estables
IRMS (Espectrometría de Masas de Relaciones Isotópicas)
Carbón
Validación
Material de referencia
Stables Isotopes
IRMS (Isotopic Ratio Mass Spectrometry)
Carbon
Validation
Reference Material
- Rights
- openAccess
- License
- Reconocimiento 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Estudio isotópico de carbono (δ13C) en carbones colombianos y su relación con las propiedades fisicoquímicas para la identificación de procesos biogeoquímicos asociados a sus ambientes de formación |
| dc.title.translated.eng.fl_str_mv |
Isotopic study of carbon (δ13C) in colombian coals and its relationship with physicochemical properties for the identification of biogeochemical processes associated with their formation environments |
| title |
Estudio isotópico de carbono (δ13C) en carbones colombianos y su relación con las propiedades fisicoquímicas para la identificación de procesos biogeoquímicos asociados a sus ambientes de formación |
| spellingShingle |
Estudio isotópico de carbono (δ13C) en carbones colombianos y su relación con las propiedades fisicoquímicas para la identificación de procesos biogeoquímicos asociados a sus ambientes de formación 540 - Química y ciencias afines::543 - Química analítica Fenómenos químicos Chemical Phenomena Ciclos biogeoquímicos Ciclo del carbono (biogeoquímica) Biogeochemical cycles Carbon cycle (biogeochemistry) Isótopos estables IRMS (Espectrometría de Masas de Relaciones Isotópicas) Carbón Validación Material de referencia Stables Isotopes IRMS (Isotopic Ratio Mass Spectrometry) Carbon Validation Reference Material |
| title_short |
Estudio isotópico de carbono (δ13C) en carbones colombianos y su relación con las propiedades fisicoquímicas para la identificación de procesos biogeoquímicos asociados a sus ambientes de formación |
| title_full |
Estudio isotópico de carbono (δ13C) en carbones colombianos y su relación con las propiedades fisicoquímicas para la identificación de procesos biogeoquímicos asociados a sus ambientes de formación |
| title_fullStr |
Estudio isotópico de carbono (δ13C) en carbones colombianos y su relación con las propiedades fisicoquímicas para la identificación de procesos biogeoquímicos asociados a sus ambientes de formación |
| title_full_unstemmed |
Estudio isotópico de carbono (δ13C) en carbones colombianos y su relación con las propiedades fisicoquímicas para la identificación de procesos biogeoquímicos asociados a sus ambientes de formación |
| title_sort |
Estudio isotópico de carbono (δ13C) en carbones colombianos y su relación con las propiedades fisicoquímicas para la identificación de procesos biogeoquímicos asociados a sus ambientes de formación |
| dc.creator.fl_str_mv |
Moreno Forero, Maribel |
| dc.contributor.advisor.none.fl_str_mv |
Agámez Pertuz, Yazmin Yaneth |
| dc.contributor.author.none.fl_str_mv |
Moreno Forero, Maribel |
| dc.contributor.orcid.spa.fl_str_mv |
MORENO FORERO, MARIBEL [0000-0002-3410-8760] |
| dc.contributor.cvlac.spa.fl_str_mv |
MORENO FORERO, MARIBEL |
| dc.subject.ddc.spa.fl_str_mv |
540 - Química y ciencias afines::543 - Química analítica |
| topic |
540 - Química y ciencias afines::543 - Química analítica Fenómenos químicos Chemical Phenomena Ciclos biogeoquímicos Ciclo del carbono (biogeoquímica) Biogeochemical cycles Carbon cycle (biogeochemistry) Isótopos estables IRMS (Espectrometría de Masas de Relaciones Isotópicas) Carbón Validación Material de referencia Stables Isotopes IRMS (Isotopic Ratio Mass Spectrometry) Carbon Validation Reference Material |
| dc.subject.decs.spa.fl_str_mv |
Fenómenos químicos |
| dc.subject.decs.eng.fl_str_mv |
Chemical Phenomena |
| dc.subject.lemb.spa.fl_str_mv |
Ciclos biogeoquímicos Ciclo del carbono (biogeoquímica) |
| dc.subject.lemb.eng.fl_str_mv |
Biogeochemical cycles Carbon cycle (biogeochemistry) |
| dc.subject.proposal.spa.fl_str_mv |
Isótopos estables IRMS (Espectrometría de Masas de Relaciones Isotópicas) Carbón Validación Material de referencia |
| dc.subject.proposal.eng.fl_str_mv |
Stables Isotopes IRMS (Isotopic Ratio Mass Spectrometry) Carbon Validation Reference Material |
| description |
ilustraciones, diagramas, fotografías a color, mapas |
| publishDate |
2023 |
| dc.date.accessioned.none.fl_str_mv |
2023-07-28T13:52:00Z |
| dc.date.available.none.fl_str_mv |
2023-07-28T13:52:00Z |
| dc.date.issued.none.fl_str_mv |
2023-07-26 |
| dc.type.spa.fl_str_mv |
Trabajo de grado - Maestría |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/masterThesis |
| dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/acceptedVersion |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/TM |
| status_str |
acceptedVersion |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/84350 |
| dc.identifier.instname.spa.fl_str_mv |
Universidad Nacional de Colombia |
| dc.identifier.reponame.spa.fl_str_mv |
Repositorio Institucional Universidad Nacional de Colombia |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.unal.edu.co/ |
| url |
https://repositorio.unal.edu.co/handle/unal/84350 https://repositorio.unal.edu.co/ |
| identifier_str_mv |
Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia |
| dc.relation.references.spa.fl_str_mv |
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Geol., vol. 453, pp. 1–11, 2017, doi: 10.1016/j.chemgeo.2017.02.012. Y. Liu, G. Liu, B. Yousaf, J. Zhang, and L. Zhou, “Carbon fractionation and stable carbon isotopic fingerprint of road dusts near coal power plant with emphases on coal-related source apportionment,” Ecotoxicol. Environ. Saf., vol. 202, no. June, p. 110888, 2020, doi: 10.1016/j.ecoenv.2020.110888. M. J. Kotarba and J. L. Clayton, “A stable carbon isotope and biological marker study of Polish bituminous coals and carbonaceous shales,” Int. J. Coal Geol., vol. 55, no. 2–4, pp. 73–94, 2003, doi: 10.1016/S0166-5162(03)00082-X. M. Panda, S. M. Equeenuddin, and D. Mohanty, “Organic petrography and stable isotopic characteristics of Permian Talcher coal, India: Implications on depositional environment,” Int. J. Coal Geol., vol. 264, no. December, 2022, doi: 10.1016/j.coal.2022.104130. T. Kanduč, M. Markič, S. Zavšek, and J. McIntosh, “Carbon cycling in the Pliocene Velenje Coal Basin, Slovenia, inferred from stable carbon isotopes,” Int. J. Coal Geol., vol. 89, no. 1, pp. 70–83, 2012, doi: 10.1016/j.coal.2011.08.008. M. K. Bertil Magnusson, Teemu Näykki, Håvard Hovind, “HANDBOOK FOR CALCULATION OF MEASUREMENT UNCERTAINTY IN Håvard Hovind,” 2003. J. H. Lee, J. H. Choi, J. S. Youn, Y. J. Cha, W. Song, and A. J. Park, “Comparison between bottom-up and top-down approaches in the estimation of measurement uncertainty,” Clin. Chem. Lab. Med., vol. 53, no. 7, pp. 1025–1032, 2015, doi: 10.1515/cclm-2014-0801. M. 20742 Department of Physics - University of Maryland - College Park, “Random vs Systematic Error.” https://www.physics.umd.edu/courses/Phys276/Hill/Information/Notes/ErrorAnalysis.html (accessed Nov. 05, 2022). B. S. K. Kumar, V. V. S. S. Sarma, and D. 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A. Christin, and E. J. Edwards, “The C 4 plant lineages of planet Earth,” J. Exp. Bot., vol. 62, no. 9, pp. 3155–3169, 2011, doi: 10.1093/jxb/err048. J. R. E. á T. E. C. B. R. Helliker, “C4 photosynthesis, atmospheric CO2, and climate,” Ecologia, vol. 112, pp. 285–299, 1997. MARY LUZ PEÑA URUEÑA, “CARACTERIZACIÓN DE CENIZAS DE ALGUNOS CARBONES COLOMBIANOS IN SITU POR RETRODISPERSIÓN GAMMA-GAMMA MARY,” Universidad Nacional de Colombia, 2011. I. Journal and C. Geology, “First insights into mineralogy , geochemistry , and isotopic signatures of the Upper Triassic high-sulfur coals from the Thai Nguyen Coal field , NE Vietnam,” vol. 261, no. September, pp. 2022–2023, 2022. Y. Lin, S. Wang, H. H. Schobert, Q. Guo, and X. Li, “Sulfur and nitrogen isotopic composition of Late Permian bark coals: Source identification and associated environmental assessment,” Org. Geochem., vol. 164, no. February, 2022, doi: 10.1016/j.orggeochem.2022.104369. N. Islam, B. K. Saikia, C. H. Sampaio, T. J. Crissien, and L. F. O. Silva, “Petrography and geochemistry of exported Colombian coals : Implications from correlation and regression analyses,” Energy Geosci., vol. 2, 2021. E. GALLEGO CARMONA and J. V. REALPE SALCEDO, “Poder calorífico de carbones colombianos a partir de análisis próximo,” pp. 1–78, 2015. IGME, “Abundancia y fracionamiento de los isótopos estables,” Inst. Geológico y Min. España. A. N. De Hidrocarburos and H. Office, “Análisis de tecnología y estrategia de promoción para desarrollos de Gas Metano Asociado al Carbón ( CBM ) en Colombia Fase I : Caracterización de Cuencas de CBM en Colombia,” no. 1, 2010. J. C. M. James N. Miller, Estadística y Quimiometría para Química Analítica, 4th ed. Madrid, 2002. |
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Reconocimiento 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Agámez Pertuz, Yazmin Yaneth05f2a50538617c040700e693ed0c0baf600Moreno Forero, Maribelcf4398dfcd1beb61c9fbb90e2e36c0fdMORENO FORERO, MARIBEL [0000-0002-3410-8760]MORENO FORERO, MARIBEL2023-07-28T13:52:00Z2023-07-28T13:52:00Z2023-07-26https://repositorio.unal.edu.co/handle/unal/84350Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, diagramas, fotografías a color, mapasLa caracterización química de algunas sustancias presentes en la tierra permite identificar la formación, evolución y el cambio en las condiciones ambientales derivadas de procesos naturales como la respiración, la fotosíntesis o los fenómenos geológicos dados por la dinámica interna y externa de las capas de la tierra. El conocimiento de estos cambios en matrices como el carbón, en el territorio colombiano contribuye a una mayor caracterización de los recursos del país y por ende a su mejor aprovechamiento de estos. Con este fin se desarrolló y validó un método para la determinación isotópica de carbono en carbones mediante Espectrometría de Masas de Relaciones Isotópicas (IRMS). Mediante el proceso de validación se encontró que el método es apto para las determinaciones de δ13C en carbones de las diferentes zonas carboníferas del país en el intervalo de -32,151 ‰ a -16,049 ‰ de δ13C con una precisión menor al 0,2 ‰. El método validado fue empleado en la evaluación de carbones provenientes de las zonas Boyacá, la Guajira, Cundinamarca, Santander, Córdoba, y Antioquía, cubriendo las principales zonas carboníferas del país, con el objeto de correlacionar los resultados de la relación isotópica con análisis fisicoquímicos que permitan establecer diferentes características de este recurso, así como de sus ambientes de formación. Se encontraron relaciones isotópicas en el intervalo de −27,08 ‰ y -26,20 ‰. Uno de los problemas que presenta este tipo de técnicas es el de no contar con Materiales de Referencia (MR) de matrices de las muestras similares o iguales a las muestras rutinarias del laboratorio, además que las que se consiguen en el mercado solo pueden ser adquiridas cada cierto periodo de tiempo (3 años), por lo tanto, esta investigación contribuyó en la producción, de un material de referencia in-house con el fin de ser empleado como control y aseguramiento de calidad del método desarrollado. Durante todo el proceso se evaluó su homogeneidad, estabilidad y uso repetido. (Texto tomado de la fuente)The chemical characterization of some substances present in the earth allows to identify the formation, evolution and change in environmental conditions derived from natural processes such as respiration, photosynthesis or geological phenomena given by the internal and external dynamics of the layers of the earth. The knowledge of these changes in matrices such as coal, in the Colombian territory contributes to a better characterization of the country's resources and therefore to their better use. To this end, a method for the isotopic determination of carbon in coals by Isotopic Ratio Mass Spectrometry (IRMS) was developed and validated. Through the validation process, it was found that the method is suitable for the determination of δ13C in coals from the different coal-producing areas of the country. A linear interval of -32.121 ‰ to -16.049 ‰ of δ13C and error percentages and coefficients of variation less than 5% will be completed. After the validation in a second stage, from the validated method, the coals from the Boyacá, Guajira, Cundinamarca, Santander, Córdoba y Antioquia zones were evaluated, covering the main coal-bearing zones of the country, with the in order to correlate the results of the isotopic relationship with physicochemical analyzes that allow establishing different characteristics of this resource, as well as its formation environments. Isotopic ratios between −27.96‰ to −26.11‰ were found. Due to the problem of not having enough reference materials for this type of method, the production of an in-house reference material was carried out in order to be used as control and quality assurance of the developed method.MaestríaMagister en Ciencias QuímicaAplicaciones Nucleares y Geocronológicas134 páginasapplication/pdfUniversidad Nacional de ColombiaBogotá - Ciencias - Maestría en Ciencias - QuímicaFacultad de CienciasBogotá,ColombiaUniversidad Nacional de Colombia - Sede Bogotá540 - Química y ciencias afines::543 - Química analíticaFenómenos químicosChemical PhenomenaCiclos biogeoquímicosCiclo del carbono (biogeoquímica)Biogeochemical cyclesCarbon cycle (biogeochemistry)Isótopos establesIRMS (Espectrometría de Masas de Relaciones Isotópicas)CarbónValidaciónMaterial de referenciaStables IsotopesIRMS (Isotopic Ratio Mass Spectrometry)CarbonValidationReference MaterialEstudio isotópico de carbono (δ13C) en carbones colombianos y su relación con las propiedades fisicoquímicas para la identificación de procesos biogeoquímicos asociados a sus ambientes de formaciónIsotopic study of carbon (δ13C) in colombian coals and its relationship with physicochemical properties for the identification of biogeochemical processes associated with their formation environmentsTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMColombiaA. N. de Míneria, “El futuro del carbón en Colombia no termina , se fortalece con las ruedas de negocios,” 2021. https://www.anm.gov.co/?q=rueda-de-negocios-carbon-termico-en-colombia.D. N. D. P. CONSEJO NACIONAL DE POLÍTICA ECONÓMICA Y SOCIAL, REPÚBLICA DE COLOMBIA, “Política De Transición Energética - Conpes 4075,” p. 108, 2022, [Online]. Available: https://colaboracion.dnp.gov.co/CDT/Conpes/Económicos/4075.pdf.G. Valley, “International Journal of Coal Geology Petrographic characteristics and carbon isotopic composition of Permian coal : Implications on depositional environment of Sattupalli coal fi eld ,” Int. J. Coal Geol., vol. 90–91, pp. 34–42, 2012, doi: 10.1016/j.coal.2011.10.002.M. Hámor-vidó and T. Hámor, “Sulphur and carbon isotopic composition of power supply coals in the Pannonian Basin , Hungary,” vol. 71, pp. 425–447, 2007, doi: 10.1016/j.coal.2006.11.002.M. Moreno and G. Hincapié, “ESTUDIO DE ISÓTOPOS DE CARBONO (delta 13 C) Y ESTRONCIO ( 87 Sr/ 86 Sr) EN LOS DEPÓSITOS CRETÁCEOS-TERCIARIOS DE LA CORDILLERA ORIENTAL,” Universidad de Caldas, 2010.N. Suto and H. Kawashima, “Global mapping of carbon isotope ratios in coal,” J. Geochemical Explor., vol. 167, pp. 12–19, 2016, doi: 10.1016/j.gexplo.2016.05.001.C. T. Samec, M. Pirola, and V. A. Killian Galván, “Lineamientos para la publicación de resultados isotópicos en antropología biológica y arqueología,” Rev. Argentina Antropol. Biológica, vol. 21, no. 2, p. 007, 2019, doi: 10.24215/18536387e007.G. Skrzypek et al., “Minimum requirements for publishing hydrogen, carbon, nitrogen, oxygen and sulfur stable-isotope delta results (IUPAC Technical Report),” Pure Appl. Chem., 2022, doi: 10.1515/pac-2021-1108.ISO - International Organization for Standardization, “ISO/IEC 17025:2017 General requirements for the competence of testing and calibration laboratories.,” vol. 2017, 2009.R. 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Sierra Aragón, “Petrografía del carbón,” Universidad de Granada - Instituto de Ciencia y Tecnología del Carbono (INCAR) - España, 2013. https://petrografiacarbon.es/.V. J. Cortés, “Carbón,” NA, pp. 1–47, 2015.Portafolio, “En carbón, el país es exportador de talla mundial,” Portafolio, p. 94036, 2012.E. País, “El incierto futuro del carbón en Colombia,” 2022.UPME, “El Carbón Colombiano. Fuente de Energía para el mundo,” Unidad Planeación Min. Energética, p. 53, 2005.F. Chiocchini, S. Portarena, M. Ciolfi, E. Brugnoli, and M. Lauteri, “Isoscapes of carbon and oxygen stable isotope compositions in tracing authenticity and geographical origin of Italian extra-virgin olive oils,” Food Chem., vol. 202, pp. 291–301, 2016, doi: 10.1016/j.foodchem.2016.01.146.Agencia Nacional de Mineria, “Carbón,” Producción Nacional de Minerales 2013, Bogotá, Colombia.S. G. 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In, “Stable Isotope Geochemistry III: Low Temperature Applications,” in Geol. 656 Isotope Geochemistry Chapter, 2011, pp. 276–327.Z. Muccio and G. P. Jackson, “Isotope ratio mass spectrometry,” Analyst, vol. 134, no. 2, pp. 213–222, 2009, doi: 10.1039/b808232d.G. Kaklamanos, E. Aprea, and G. Theodoridis, 11 - Mass spectrometry: principles and instrumentation, Second Edi. Elsevier Inc., 2020.Cienfuegos and Morales, “Metrología de isótopos estables y materiales de referencia utilizados para la determinación isotópica de carbono, nitrógeno, oxigeno, hidrógeno, y azufre,” Simp. Metrol., 2001, [Online]. Available: http://www.cenam.mx/Memorias/descarga/Memorias Simposio/documentos/ta-or023.pdf.I. A. E. AGENCY, “Reference and intercomparison materials for stable isotopes of light elements,” 1995.W. C. Pat, S. Iii, and U. S. G. Survey, Stable Isotope Geochemistry of Mineral Deposits, 2nd ed. Elsevier Ltd., 2014M. Moreno Sánchez and G. 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