Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole
A new silver coordination compound [Ag(sac)(pbi)] was synthesized by reaction of silver(I) saccharinate with 2-(2-pyridyl)benzimidazole (pbi) in 64% yield. The characterization was performed by elemental analysis, IR, UV-Visible, XPS, 1H-NMR, and 13C-NMR spectroscopy. According to the results, silve...
- Autores:
-
Ceroni Galloso, Mario
Angulo-Cornejo, Jorge Reynaldo
Lino-Pacaheco, Maria Nieves
Villanueva Huerta, Claudia Cecilia
Casimiro Soriano, Enzo Martín
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2018
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/66248
- Acceso en línea:
- https://repositorio.unal.edu.co/handle/unal/66248
http://bdigital.unal.edu.co/67272/
- Palabra clave:
- 54 Química y ciencias afines / Chemistry
saccharinate
silver
2-(2-pyridyl)benzimidazole
XPS
sacarinato
plata
2-(2-piridil)bencimidazol
XPS
sacarina
prata
2-(2-piridil)benzimidazol
XPS
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional
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Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Ceroni Galloso, Mario9c1a0985-83ef-4683-8765-99bfc6a0b872300Angulo-Cornejo, Jorge Reynaldo9e5e2da2-346f-49ef-84d0-1c2d532a4644300Lino-Pacaheco, Maria Nieves65f5a898-3263-403a-8ed4-344c9f8e366c300Villanueva Huerta, Claudia Ceciliae73373e3-ad79-4af2-9210-f4628ba3441b300Casimiro Soriano, Enzo Martín39408726-0194-4e54-9999-81461625751a3002019-07-03T01:45:49Z2019-07-03T01:45:49Z2018-05-01ISSN: 2357-3791https://repositorio.unal.edu.co/handle/unal/66248http://bdigital.unal.edu.co/67272/A new silver coordination compound [Ag(sac)(pbi)] was synthesized by reaction of silver(I) saccharinate with 2-(2-pyridyl)benzimidazole (pbi) in 64% yield. The characterization was performed by elemental analysis, IR, UV-Visible, XPS, 1H-NMR, and 13C-NMR spectroscopy. According to the results, silver is coordinating through three nitrogen atoms: one from saccharinate and the others from 2-(2-pyridyl)benzimidazole forming with this ligand a five-membered chelate ring.Se sintetizó un nuevo compuesto de coordinación de plata, [Ag(sac)(pbi)], por reacción de sacarinato de plata(I) con 2-(2-piridil)bencimidazol (pbi) con un rendimiento de 64%. La caracterización se realizó por análisis elemental, espectroscopia IR, UV-Visible, XPS, 1H-RMN y 13C-RMN. De acuerdo con los resultados obtenidos la plata está coordinada a través de tres átomos de nitrógeno, uno del sacarinato y los dos restantes del 2-(2-piridil)-bencimidazol formando con este ligando un anillo quelato de cinco miembros.O presente trabalho compreende a síntese do composto de coordenação de prata, [Ag(sac)(pbi)], por reação de sacarinato de prata(I) com 2-(2-piridil)benzimidazol (pbi) com 64% de rendimento. A caracterização foi realizada por análise elementar, espectroscopia IR, UV-Visível, XPS, 1H-RMN e 13C-RMN. De acordo com os resultados obtidos, a prata é coordenada através de três átomos de nitrogênio, um do sacarinato e os outros dois do 2-(2-piridil)benzimidazol que formam com este ligando um anel de quelato de cinco membros.application/pdfspaUniversidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Químicahttps://revistas.unal.edu.co/index.php/rcolquim/article/view/68225Universidad Nacional de Colombia Revistas electrónicas UN Revista Colombiana de QuímicaRevista Colombiana de QuímicaCeroni Galloso, Mario and Angulo-Cornejo, Jorge Reynaldo and Lino-Pacaheco, Maria Nieves and Villanueva Huerta, Claudia Cecilia and Casimiro Soriano, Enzo Martín (2018) Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole. Revista Colombiana de Química, 47 (2). pp. 73-78. ISSN 2357-379154 Química y ciencias afines / Chemistrysaccharinatesilver2-(2-pyridyl)benzimidazoleXPSsacarinatoplata2-(2-piridil)bencimidazolXPSsacarinaprata2-(2-piridil)benzimidazolXPSSynthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazoleArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTORIGINAL68225-385731-1-PB.pdfapplication/pdf563755https://repositorio.unal.edu.co/bitstream/unal/66248/1/68225-385731-1-PB.pdf2c8c63b2343ccc3d92e299b23a4014f8MD51THUMBNAIL68225-385731-1-PB.pdf.jpg68225-385731-1-PB.pdf.jpgGenerated Thumbnailimage/jpeg6241https://repositorio.unal.edu.co/bitstream/unal/66248/2/68225-385731-1-PB.pdf.jpg94b31e6e27f34f35a1bd49526ae55433MD52unal/66248oai:repositorio.unal.edu.co:unal/662482024-05-15 23:09:07.211Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co |
| dc.title.spa.fl_str_mv |
Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole |
| title |
Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole |
| spellingShingle |
Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole 54 Química y ciencias afines / Chemistry saccharinate silver 2-(2-pyridyl)benzimidazole XPS sacarinato plata 2-(2-piridil)bencimidazol XPS sacarina prata 2-(2-piridil)benzimidazol XPS |
| title_short |
Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole |
| title_full |
Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole |
| title_fullStr |
Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole |
| title_full_unstemmed |
Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole |
| title_sort |
Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole |
| dc.creator.fl_str_mv |
Ceroni Galloso, Mario Angulo-Cornejo, Jorge Reynaldo Lino-Pacaheco, Maria Nieves Villanueva Huerta, Claudia Cecilia Casimiro Soriano, Enzo Martín |
| dc.contributor.author.spa.fl_str_mv |
Ceroni Galloso, Mario Angulo-Cornejo, Jorge Reynaldo Lino-Pacaheco, Maria Nieves Villanueva Huerta, Claudia Cecilia Casimiro Soriano, Enzo Martín |
| dc.subject.ddc.spa.fl_str_mv |
54 Química y ciencias afines / Chemistry |
| topic |
54 Química y ciencias afines / Chemistry saccharinate silver 2-(2-pyridyl)benzimidazole XPS sacarinato plata 2-(2-piridil)bencimidazol XPS sacarina prata 2-(2-piridil)benzimidazol XPS |
| dc.subject.proposal.spa.fl_str_mv |
saccharinate silver 2-(2-pyridyl)benzimidazole XPS sacarinato plata 2-(2-piridil)bencimidazol XPS sacarina prata 2-(2-piridil)benzimidazol XPS |
| description |
A new silver coordination compound [Ag(sac)(pbi)] was synthesized by reaction of silver(I) saccharinate with 2-(2-pyridyl)benzimidazole (pbi) in 64% yield. The characterization was performed by elemental analysis, IR, UV-Visible, XPS, 1H-NMR, and 13C-NMR spectroscopy. According to the results, silver is coordinating through three nitrogen atoms: one from saccharinate and the others from 2-(2-pyridyl)benzimidazole forming with this ligand a five-membered chelate ring. |
| publishDate |
2018 |
| dc.date.issued.spa.fl_str_mv |
2018-05-01 |
| dc.date.accessioned.spa.fl_str_mv |
2019-07-03T01:45:49Z |
| dc.date.available.spa.fl_str_mv |
2019-07-03T01:45:49Z |
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Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_6501 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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Text |
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http://purl.org/redcol/resource_type/ART |
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http://purl.org/coar/resource_type/c_6501 |
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publishedVersion |
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ISSN: 2357-3791 |
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https://repositorio.unal.edu.co/handle/unal/66248 |
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http://bdigital.unal.edu.co/67272/ |
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ISSN: 2357-3791 |
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https://repositorio.unal.edu.co/handle/unal/66248 http://bdigital.unal.edu.co/67272/ |
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spa |
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spa |
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https://revistas.unal.edu.co/index.php/rcolquim/article/view/68225 |
| dc.relation.ispartof.spa.fl_str_mv |
Universidad Nacional de Colombia Revistas electrónicas UN Revista Colombiana de Química Revista Colombiana de Química |
| dc.relation.references.spa.fl_str_mv |
Ceroni Galloso, Mario and Angulo-Cornejo, Jorge Reynaldo and Lino-Pacaheco, Maria Nieves and Villanueva Huerta, Claudia Cecilia and Casimiro Soriano, Enzo Martín (2018) Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole. Revista Colombiana de Química, 47 (2). pp. 73-78. ISSN 2357-3791 |
| dc.rights.spa.fl_str_mv |
Derechos reservados - Universidad Nacional de Colombia |
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http://purl.org/coar/access_right/c_abf2 |
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Atribución-NoComercial 4.0 Internacional |
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http://creativecommons.org/licenses/by-nc/4.0/ |
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info:eu-repo/semantics/openAccess |
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Atribución-NoComercial 4.0 Internacional Derechos reservados - Universidad Nacional de Colombia http://creativecommons.org/licenses/by-nc/4.0/ http://purl.org/coar/access_right/c_abf2 |
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openAccess |
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Universidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Química |
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