Synthesis and characterization of mixed-ligand silver(I) saccharinate complex containing (2-(2-pyridyl)benzimidazole

A new silver coordination compound [Ag(sac)(pbi)] was synthesized by reaction of silver(I) saccharinate with 2-(2-pyridyl)benzimidazole (pbi) in 64% yield. The characterization was performed by elemental analysis, IR, UV-Visible, XPS, 1H-NMR, and 13C-NMR spectroscopy. According to the results, silver is coordinating through three nitrogen atoms: one from saccharinate and the others from 2-(2-pyridyl)benzimidazole forming with this ligand a five-membered chelate ring.

• Autores: Ceroni Galloso, Mario; Angulo-Cornejo, Jorge Reynaldo; Lino-Pacaheco, Maria Nieves; Villanueva Huerta, Claudia Cecilia; Casimiro Soriano, Enzo Martín
• Tipo de recurso: Article of journal
• Fecha de publicación: 2018
• Institución: Universidad Nacional de Colombia
• Repositorio: Universidad Nacional de Colombia
• Idioma: spa
• OAI Identifier: oai:repositorio.unal.edu.co:unal/66248
• Acceso en línea: https://repositorio.unal.edu.co/handle/unal/66248; http://bdigital.unal.edu.co/67272/
• Palabra clave: 54 Química y ciencias afines / Chemistry; saccharinate; silver; 2-(2-pyridyl)benzimidazole; XPS; sacarinato; plata; 2-(2-piridil)bencimidazol; XPS; sacarina; prata; 2-(2-piridil)benzimidazol; XPS
• Rights: openAccess
• License: Atribución-NoComercial 4.0 Internacional