Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon

The main difficulty with fossil fuel combustión lies in sulphur and nitrogen becoming converted to their respective oxides, forming part of the acid rain which deteriorates the environment and infrastructure. Removing sulphur from organo-sulfur compounds by using micro-organisms has become an altern...

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Autores:
Alméciga-Díaz, Carlos Javier
Sánchez Medina, Óscar Fernando
Silva Gómez, Edelberto
Tipo de recurso:
Article of journal
Fecha de publicación:
2005
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/22082
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/22082
http://bdigital.unal.edu.co/13116/
Palabra clave:
dibenzotiofeno
desulfurización
Pseudomonas spp
keroseno
dibenzothiophene
desulphurisation
Pseudomonas spp.
kerosene
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional
id UNACIONAL2_8721ebd913a547cd270a31adaf16e315
oai_identifier_str oai:repositorio.unal.edu.co:unal/22082
network_acronym_str UNACIONAL2
network_name_str Universidad Nacional de Colombia
repository_id_str
dc.title.spa.fl_str_mv Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon
title Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon
spellingShingle Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon
dibenzotiofeno
desulfurización
Pseudomonas spp
keroseno
dibenzothiophene
desulphurisation
Pseudomonas spp.
kerosene
title_short Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon
title_full Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon
title_fullStr Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon
title_full_unstemmed Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon
title_sort Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon
dc.creator.fl_str_mv Alméciga-Díaz, Carlos Javier
Sánchez Medina, Óscar Fernando
Silva Gómez, Edelberto
dc.contributor.author.spa.fl_str_mv Alméciga-Díaz, Carlos Javier
Sánchez Medina, Óscar Fernando
Silva Gómez, Edelberto
dc.subject.proposal.spa.fl_str_mv dibenzotiofeno
desulfurización
Pseudomonas spp
keroseno
dibenzothiophene
desulphurisation
Pseudomonas spp.
kerosene
topic dibenzotiofeno
desulfurización
Pseudomonas spp
keroseno
dibenzothiophene
desulphurisation
Pseudomonas spp.
kerosene
description The main difficulty with fossil fuel combustión lies in sulphur and nitrogen becoming converted to their respective oxides, forming part of the acid rain which deteriorates the environment and infrastructure. Removing sulphur from organo-sulfur compounds by using micro-organisms has become an alternative to hydrodesulphurisation (HDS). Twenty-three Pseudomonas spp. native strains' desulphurisation activity on dibenzothiophene (DBT) was evaluated by using a fermentation system having equal proportions of aqueous and organic (n-hexane) phases in the presence of ethanolamine oléate. The 02, 05 and 06 strains maintained their viability in this médium, presenting 6,0% to 9,4% sulphur removal, producing DBT-sulphone, DBT-sulphoxide, 2-hydroxybiphenyl (2-HBP) metabolites and sulphate belonging to the 4S pathway. These native strains' desulphurisation activity was evaluated on kerosene, presenting 19,9% to 62,2% sulphur removal having 0,45% to 5,55% calorific power loss. Key words: dibenzothiophene, desulphurisation, Pseudomonas spp. kerosene.
publishDate 2005
dc.date.issued.spa.fl_str_mv 2005
dc.date.accessioned.spa.fl_str_mv 2019-06-25T20:33:04Z
dc.date.available.spa.fl_str_mv 2019-06-25T20:33:04Z
dc.type.spa.fl_str_mv Artículo de revista
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dc.identifier.eprints.spa.fl_str_mv http://bdigital.unal.edu.co/13116/
url https://repositorio.unal.edu.co/handle/unal/22082
http://bdigital.unal.edu.co/13116/
dc.language.iso.spa.fl_str_mv spa
language spa
dc.relation.spa.fl_str_mv http://revistas.unal.edu.co/index.php/biotecnologia/article/view/472
dc.relation.ispartof.spa.fl_str_mv Universidad Nacional de Colombia Revistas electrónicas UN Revista Colombiana de Biotecnología
Revista Colombiana de Biotecnología
dc.relation.ispartofseries.none.fl_str_mv Revista Colombiana de Biotecnología; Vol. 7, núm. 1 (2005); 15-24 1909-8758 0123-3475
dc.relation.references.spa.fl_str_mv Alméciga-Díaz, Carlos Javier and Sánchez Medina, Óscar Fernando and Silva Gómez, Edelberto (2005) Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon. Revista Colombiana de Biotecnología; Vol. 7, núm. 1 (2005); 15-24 1909-8758 0123-3475 .
dc.rights.spa.fl_str_mv Derechos reservados - Universidad Nacional de Colombia
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.rights.license.spa.fl_str_mv Atribución-NoComercial 4.0 Internacional
dc.rights.uri.spa.fl_str_mv http://creativecommons.org/licenses/by-nc/4.0/
dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv Atribución-NoComercial 4.0 Internacional
Derechos reservados - Universidad Nacional de Colombia
http://creativecommons.org/licenses/by-nc/4.0/
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.mimetype.spa.fl_str_mv text/html
dc.publisher.spa.fl_str_mv Universidad Nacional de Colombia
institution Universidad Nacional de Colombia
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spelling Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Alméciga-Díaz, Carlos Javier4a8b31ed-aa3a-4b68-a6cb-646516aef74c300Sánchez Medina, Óscar Fernando4da58ae5-59a2-457b-9433-689a3069773c300Silva Gómez, Edelbertoac0c90db-e5b8-4d90-8d3a-02d58bf5d62a3002019-06-25T20:33:04Z2019-06-25T20:33:04Z2005https://repositorio.unal.edu.co/handle/unal/22082http://bdigital.unal.edu.co/13116/The main difficulty with fossil fuel combustión lies in sulphur and nitrogen becoming converted to their respective oxides, forming part of the acid rain which deteriorates the environment and infrastructure. Removing sulphur from organo-sulfur compounds by using micro-organisms has become an alternative to hydrodesulphurisation (HDS). Twenty-three Pseudomonas spp. native strains' desulphurisation activity on dibenzothiophene (DBT) was evaluated by using a fermentation system having equal proportions of aqueous and organic (n-hexane) phases in the presence of ethanolamine oléate. The 02, 05 and 06 strains maintained their viability in this médium, presenting 6,0% to 9,4% sulphur removal, producing DBT-sulphone, DBT-sulphoxide, 2-hydroxybiphenyl (2-HBP) metabolites and sulphate belonging to the 4S pathway. These native strains' desulphurisation activity was evaluated on kerosene, presenting 19,9% to 62,2% sulphur removal having 0,45% to 5,55% calorific power loss. Key words: dibenzothiophene, desulphurisation, Pseudomonas spp. kerosene.El principal inconveniente en la combustión de los hidrocarburos es la conversión del azufre y el nitrógeno a sus respectivos óxidos, los cuales participan en la formación de lluvia acida y deterioran el medio ambiente e infraestructuras. La remoción de azufre a partir de compuestos órgano-azufrados mediante el uso de microorganismos ha surgido como una alternativa frente al proceso catalítico de hidrodesulfurización (HDS). En el presente trabajo se evaluó la actividad desulfurizadora de veintitrés aislados nativos de Pseudomonas spp. sobre dibenzotiofeno (DBT), usando un sistema de fermentación con igual proporción de fase acuosa y orgánica (n-hexano) en presencia de oleato de etanolamina. Los aislados 02,05 y 06 conservaron su viabilidad en este medio y presentaron una remoción de azufre entre 6,0 y 9,4%, generando los metabolitos DBT-sulfona, DBT-sulfóxido, 2-hidroxibifenilo (2-HBP) y sulfato presentes en la ruta metabólica 4S. Con estos aislados se evaluó la actividad desulfurizadora sobre keroseno y se observó una remoción de azufre entre 19,9 y 62,6% y una disminución del poder calorífico entre 0,45 y 5,55%. Palabras clave: dibenzotiofeno, desulfurización, Pseudomonas spp., keroseno.text/htmlspaUniversidad Nacional de Colombiahttp://revistas.unal.edu.co/index.php/biotecnologia/article/view/472Universidad Nacional de Colombia Revistas electrónicas UN Revista Colombiana de BiotecnologíaRevista Colombiana de BiotecnologíaRevista Colombiana de Biotecnología; Vol. 7, núm. 1 (2005); 15-24 1909-8758 0123-3475Alméciga-Díaz, Carlos Javier and Sánchez Medina, Óscar Fernando and Silva Gómez, Edelberto (2005) Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon. Revista Colombiana de Biotecnología; Vol. 7, núm. 1 (2005); 15-24 1909-8758 0123-3475 .Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbonArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTdibenzotiofenodesulfurizaciónPseudomonas sppkerosenodibenzothiophenedesulphurisationPseudomonas spp.keroseneORIGINAL472-3169-1-PB.docapplication/msword225792https://repositorio.unal.edu.co/bitstream/unal/22082/1/472-3169-1-PB.doc3ede6f23506f94b73b56c827beb760d2MD51472-3168-1-PB.pdfapplication/pdf174515https://repositorio.unal.edu.co/bitstream/unal/22082/2/472-3168-1-PB.pdf721c048f035ff8b307c90352ad3b92d6MD52472-3149-1-PB.htmtext/html86170https://repositorio.unal.edu.co/bitstream/unal/22082/3/472-3149-1-PB.htm58a8b459962aa4844fb0d3fc37d7f5ceMD53THUMBNAIL472-3168-1-PB.pdf.jpg472-3168-1-PB.pdf.jpgGenerated Thumbnailimage/jpeg6697https://repositorio.unal.edu.co/bitstream/unal/22082/4/472-3168-1-PB.pdf.jpg674da34831841745d0152a867a373c35MD54unal/22082oai:repositorio.unal.edu.co:unal/220822023-10-05 23:04:48.803Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co