Desulfurization activity evaluation of native strains of pseudomonas spp. in the presence of hydrocarbon

The main difficulty with fossil fuel combustión lies in sulphur and nitrogen becoming converted to their respective oxides, forming part of the acid rain which deteriorates the environment and infrastructure. Removing sulphur from organo-sulfur compounds by using micro-organisms has become an altern...

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Autores:
Alméciga-Díaz, Carlos Javier
Sánchez Medina, Óscar Fernando
Silva Gómez, Edelberto
Tipo de recurso:
Article of journal
Fecha de publicación:
2005
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/22082
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/22082
http://bdigital.unal.edu.co/13116/
Palabra clave:
dibenzotiofeno
desulfurización
Pseudomonas spp
keroseno
dibenzothiophene
desulphurisation
Pseudomonas spp.
kerosene
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional
Description
Summary:The main difficulty with fossil fuel combustión lies in sulphur and nitrogen becoming converted to their respective oxides, forming part of the acid rain which deteriorates the environment and infrastructure. Removing sulphur from organo-sulfur compounds by using micro-organisms has become an alternative to hydrodesulphurisation (HDS). Twenty-three Pseudomonas spp. native strains' desulphurisation activity on dibenzothiophene (DBT) was evaluated by using a fermentation system having equal proportions of aqueous and organic (n-hexane) phases in the presence of ethanolamine oléate. The 02, 05 and 06 strains maintained their viability in this médium, presenting 6,0% to 9,4% sulphur removal, producing DBT-sulphone, DBT-sulphoxide, 2-hydroxybiphenyl (2-HBP) metabolites and sulphate belonging to the 4S pathway. These native strains' desulphurisation activity was evaluated on kerosene, presenting 19,9% to 62,2% sulphur removal having 0,45% to 5,55% calorific power loss. Key words: dibenzothiophene, desulphurisation, Pseudomonas spp. kerosene.