Degradation of pharmaceuticals from municipal wastewater effluents by ozone-based advanced oxidation processes

Ilustraciones

Autores:: Prada Vásquez, María Angélica

Tipo de recurso:

Fecha de publicación:: 2023

Institución:: Universidad Nacional de Colombia

Repositorio:: Universidad Nacional de Colombia

Idioma:: eng

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network_acronym_str	UNACIONAL2
network_name_str	Universidad Nacional de Colombia
repository_id_str
dc.title.none.fl_str_mv	Degradation of pharmaceuticals from municipal wastewater effluents by ozone-based advanced oxidation processes
dc.title.translated.none.fl_str_mv	Degradación de compuestos farmacéuticos presentes en efluentes de aguas residuales municipales mediante procesos de oxidación avanzada-basados en ozono
title	Degradation of pharmaceuticals from municipal wastewater effluents by ozone-based advanced oxidation processes
spellingShingle	Degradation of pharmaceuticals from municipal wastewater effluents by ozone-based advanced oxidation processes 540 - Química y ciencias afines 660 - Ingeniería química 600 - Tecnología (Ciencias aplicadas) Purificación de aguas residuales Oxidación Transformación de residuos Ozono Contaminantes de preocupación emergente Tratamiento de aguas residuales Ozone Contaminants of emerging concern Wastewater treatment
title_short	Degradation of pharmaceuticals from municipal wastewater effluents by ozone-based advanced oxidation processes
title_full	Degradation of pharmaceuticals from municipal wastewater effluents by ozone-based advanced oxidation processes
title_fullStr	Degradation of pharmaceuticals from municipal wastewater effluents by ozone-based advanced oxidation processes
title_full_unstemmed	Degradation of pharmaceuticals from municipal wastewater effluents by ozone-based advanced oxidation processes
title_sort	Degradation of pharmaceuticals from municipal wastewater effluents by ozone-based advanced oxidation processes
dc.creator.fl_str_mv	Prada Vásquez, María Angélica
dc.contributor.advisor.none.fl_str_mv	Cardona Gallo, Santiago Alonso (Thesis advisor) Torres Palma, Ricardo Antonio
dc.contributor.author.none.fl_str_mv	Prada Vásquez, María Angélica
dc.contributor.orcid.spa.fl_str_mv	0000-0002-3814-3686
dc.contributor.cvlac.spa.fl_str_mv	Prada Vásquez, María Angélica
dc.contributor.researchgate.spa.fl_str_mv	Prada Vásquez, María Angélica
dc.subject.ddc.spa.fl_str_mv	540 - Química y ciencias afines 660 - Ingeniería química 600 - Tecnología (Ciencias aplicadas)
topic	540 - Química y ciencias afines 660 - Ingeniería química 600 - Tecnología (Ciencias aplicadas) Purificación de aguas residuales Oxidación Transformación de residuos Ozono Contaminantes de preocupación emergente Tratamiento de aguas residuales Ozone Contaminants of emerging concern Wastewater treatment
dc.subject.lemb.none.fl_str_mv	Purificación de aguas residuales Oxidación Transformación de residuos
dc.subject.proposal.spa.fl_str_mv	Ozono Contaminantes de preocupación emergente Tratamiento de aguas residuales
dc.subject.proposal.eng.fl_str_mv	Ozone Contaminants of emerging concern Wastewater treatment
description	Ilustraciones
publishDate	2023
dc.date.issued.none.fl_str_mv	2023-11-24
dc.date.accessioned.none.fl_str_mv	2024-01-22T15:41:31Z
dc.date.available.none.fl_str_mv	2024-01-22T15:41:31Z
dc.type.spa.fl_str_mv	Trabajo de grado - Doctorado
dc.type.coarversion.fl_str_mv	http://purl.org/coar/version/c_b1a7d7d4d402bcce
dc.type.coar.fl_str_mv	http://purl.org/coar/resource_type/c_db06
dc.type.driver.spa.fl_str_mv	info:eu-repo/semantics/doctoralThesis
dc.type.content.spa.fl_str_mv	Text
dc.identifier.uri.none.fl_str_mv	https://repositorio.unal.edu.co/handle/unal/85389
dc.identifier.instname.spa.fl_str_mv	Universidad Nacional de Colombia
dc.identifier.repo.none.fl_str_mv	Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv	https://repositorio.unal.edu.co/
url	https://repositorio.unal.edu.co/handle/unal/85389 https://repositorio.unal.edu.co/
identifier_str_mv	Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv	eng
language	eng
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dc.publisher.spa.fl_str_mv	Universidad Nacional de Colombia
dc.publisher.program.spa.fl_str_mv	Medellín - Minas - Doctorado en Ingeniería - Recursos Hidráulicos
dc.publisher.faculty.spa.fl_str_mv	Facultad de Minas
dc.publisher.place.spa.fl_str_mv	Medellín, Colombia
dc.publisher.branch.spa.fl_str_mv	Universidad Nacional de Colombia - Sede Medellín
institution	Universidad Nacional de Colombia
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spelling	Atribución-NoComercial-SinDerivadas 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Cardona Gallo, Santiago Alonso (Thesis advisor)ed832e8a644c502568ddcd0286e9c465600Torres Palma, Ricardo Antonioeae2230df3b2a080091e3554126869fbPrada Vásquez, María Angélica67c61ca9bf2fcfce9a0fa6d84db359b20000-0002-3814-3686Prada Vásquez, María AngélicaPrada Vásquez, María Angélica2024-01-22T15:41:31Z2024-01-22T15:41:31Z2023-11-24https://repositorio.unal.edu.co/handle/unal/85389Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/IlustracionesDebido a la creciente preocupación sobre la liberación de contaminantes de preocupación emergente (CECs) en diferentes compartimentos de agua, la necesidad de métodos efectivos y sostenibles de tratamiento de agua se ha convertido en un tema significativo. Estos CECs, que incluyen varios compuestos activos farmacéuticos (PhACs), productos de cuidado personal y otros contaminantes, plantean desafíos a los procesos convencionales de tratamiento de agua. Como resultado, existe una creciente necesidad de implementar soluciones alternativas para abordar este problema apremiante y garantizar la protección de nuestros recursos hídricos. En este contexto, la aplicación de tecnologías avanzadas como los procesos de tratamiento de agua mediante ozonación ha surgido como un enfoque prometedor para abordar la eliminación de compuestos orgánicos recalcitrantes, especialmente PhACs y salvaguardar la calidad de nuestro fuentes de agua. La ozonación se destaca como una tecnología versátil y poderosa capaz de atacar directa y selectivamente compuestos orgánicos, especialmente bajo condiciones de pH ácido. Simultáneamente, bajo condiciones de pH alcalino, el ozono puede sufrir descomposición a través de un mecanismo de reacción en cadena y generar radicales hidroxilo (HO•) altamente reactivos y menos selectivos. A pesar de su alta efectividad como técnica de tratamiento de agua, la ozonación convencional enfrenta dos desventajas principales: la mineralización incompleta y, en consecuencia, acumulación de subproductos de reacción desconocidos, así como limitaciones en la transferencia de masa gas-líquido. Este trabajo de tesis de doctorado se enfoca en contribuir al conocimiento existente sobre los diferentes procesos avanzados de oxidación (AOPs) basados en ozono como estrategias para mejorar o intensificar el rendimiento químico del proceso de ozonación para la eliminación de PhACs. Además, tiene como objetivo ampliar el conocimiento sobre la evaluación del rendimiento de un contactor de membrana para la inyección de ozono como una estrategia potencial para intensificar la transferencia de masa ozono-líquido y su aplicación en la eliminación de PhACs en muestras de aguas residuales reales.DoctoradoDoctorado en Ingeniería - Recursos HidráulicosTratamiento de aguasÁrea Curricular de Medio Ambiente175 páginasapplication/pdfengUniversidad Nacional de ColombiaMedellín - Minas - Doctorado en Ingeniería - Recursos HidráulicosFacultad de MinasMedellín, ColombiaUniversidad Nacional de Colombia - Sede Medellín540 - Química y ciencias afines660 - Ingeniería química600 - Tecnología (Ciencias aplicadas)Purificación de aguas residualesOxidaciónTransformación de residuosOzonoContaminantes de preocupación emergenteTratamiento de aguas residualesOzoneContaminants of emerging concernWastewater treatmentDegradation of pharmaceuticals from municipal wastewater effluents by ozone-based advanced oxidation processesDegradación de compuestos farmacéuticos presentes en efluentes de aguas residuales municipales mediante procesos de oxidación avanzada-basados en ozonoTrabajo de grado - Doctoradoinfo:eu-repo/semantics/doctoralThesishttp://purl.org/coar/version/c_b1a7d7d4d402bcceTexthttp://purl.org/coar/resource_type/c_db06Aa van der, N.G.F.M., Van Vlaardingen, P.L.A., Van Leeuwen, L.C., Post, M., 2001. Assessment of potential risks of 11 pharmaceuticals for the environment: Using environmental information from public databases.Adityosulindro, S., Julcour, C., Riboul, D., Barthe, L., 2022. Degradation of ibuprofen by photo-based advanced oxidation processes: exploring methods of activation and related reaction routes. International Journal of Environmental Science and Technology 19, 3247–3260. https://doi.org/10.1007/s13762-021-03372-5Al-Abduly, A., Christensen, P., Harvey, A., Zahng, K., 2014. Characterization and optimization of an oscillatory baffled reactor (OBR) for ozone-water mass transfer. Chemical Engineering and Processing - Process Intensification 84, 82–89. https://doi.org/10.1016/j.cep.2014.03.015Alejandro, S., Valdés, H., Zaror, Claudio.A., 2011. Natural Zeolite Reactivity Towards Ozone: The Role of Acid Surface Sites. Journal of Advanced Oxidation Technologies 14. https://doi.org/10.1515/jaots-2011-0201Alejandro-Martín, S., Valdés, H., Manero, M.H., Zaror, C.A., 2018. 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Water (Switzerland) 10, 1416. https://doi.org/10.3390/w10101416Ministerio de Ciencia, Tecnología e Innovación de Colombia (MINCIENCIAS)EstudiantesInvestigadoresMaestrosPúblico generalORIGINAL1065593928.2023.pdf1065593928.2023.pdfTesis de Doctorado en Ingeniería - Recursos Hidráulicosapplication/pdf5899914https://repositorio.unal.edu.co/bitstream/unal/85389/2/1065593928.2023.pdfee44ae8a9cc93e76efb6a32c77836867MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-85879https://repositorio.unal.edu.co/bitstream/unal/85389/3/license.txteb34b1cf90b7e1103fc9dfd26be24b4aMD53THUMBNAIL1065593928.2023.pdf.jpg1065593928.2023.pdf.jpgGenerated Thumbnailimage/jpeg4325https://repositorio.unal.edu.co/bitstream/unal/85389/4/1065593928.2023.pdf.jpg270a0685f350e2416748768c3d6dee4cMD54unal/85389oai:repositorio.unal.edu.co:unal/853892024-08-21 23:13:33.316Repositorio Institucional Universidad Nacional de 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

Degradation of pharmaceuticals from municipal wastewater effluents by ozone-based advanced oxidation processes

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