Promoting effect of mo on pd / g-al2o3 supported catalysts in the oxidative dehydrogenation of propane

Bimetallic catalysts of Pd-Mo supported on g-Al2O3 were prepared to study the interaction of Pd-Mo in terms of their structural properties and their catalytic activity for the reaction of oxidative dehydrogenation of propane (ODHP). The catalysts contain distributions of Pd- Mo loads between 0 and 5...

Full description

Autores:
Zea Ramirez, Hugo Ricardo
Figueiredo, José Luís
Carballo Suárez, Luis María
Tipo de recurso:
Article of journal
Fecha de publicación:
2011
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/40462
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/40462
http://bdigital.unal.edu.co/30559/
Palabra clave:
Bimetallic Pd-Mo catalyst
propane reactions
oxidative dehydrogenation
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional
Description
Summary:Bimetallic catalysts of Pd-Mo supported on g-Al2O3 were prepared to study the interaction of Pd-Mo in terms of their structural properties and their catalytic activity for the reaction of oxidative dehydrogenation of propane (ODHP). The catalysts contain distributions of Pd- Mo loads between 0 and 5 wt %, and were characterized by total surface area (TSA), total pore volume (TPV), active surface area (ASA), XRD, and TEM-EDS. The results indicate that the addition of Mo to catalysts of Pd/g-Al2O3 modifies its catalytic activity for the ODHP reaction. The influence of the load relationship Pd-Mo in the catalytic activity was determined. Monometallic catalysts were prepared for purposes of comparison.