Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures
The thermodynamic properties of the 3-chloro-N-phenyl-phthalimide in acetone + methanol cosolvent mixtures were obtained from solubility data report in literature. The solubility was higher in near acetone and lower in pure methanol at all temperatures studied. A non-linear plot of ∆solnH° vs. ∆soln...
- Autores:
-
Areiza Aldana, Grecia Angeline del Mar
Cavides Rubio, Diego Iván
Rodríguez Rodríguez, Gerson Andrés
Cuellar Lozano, Aleida
Mehrdad, Abbas
Delgado, Daniel Ricardo
Peña Carmona, Nasly Alexandra
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2016
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/66609
- Acceso en línea:
- https://repositorio.unal.edu.co/handle/unal/66609
http://bdigital.unal.edu.co/67637/
- Palabra clave:
- 66 Ingeniería química y Tecnologías relacionadas/ Chemical engineering
61 Ciencias médicas; Medicina / Medicine and health
3-Chloro-N-phenylphthalimide
solubility
solution thermodynamics
activity coefficients
preferential solvation
3-cloro-N-fenil-ftalimida
solubilidad
termodinámica de soluciones
coeficiente de actividad
solvatación preferencial
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures |
| title |
Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures |
| spellingShingle |
Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures 66 Ingeniería química y Tecnologías relacionadas/ Chemical engineering 61 Ciencias médicas; Medicina / Medicine and health 3-Chloro-N-phenylphthalimide solubility solution thermodynamics activity coefficients preferential solvation 3-cloro-N-fenil-ftalimida solubilidad termodinámica de soluciones coeficiente de actividad solvatación preferencial |
| title_short |
Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures |
| title_full |
Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures |
| title_fullStr |
Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures |
| title_full_unstemmed |
Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures |
| title_sort |
Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures |
| dc.creator.fl_str_mv |
Areiza Aldana, Grecia Angeline del Mar Cavides Rubio, Diego Iván Rodríguez Rodríguez, Gerson Andrés Cuellar Lozano, Aleida Mehrdad, Abbas Delgado, Daniel Ricardo Peña Carmona, Nasly Alexandra |
| dc.contributor.author.spa.fl_str_mv |
Areiza Aldana, Grecia Angeline del Mar Cavides Rubio, Diego Iván Rodríguez Rodríguez, Gerson Andrés Cuellar Lozano, Aleida Mehrdad, Abbas Delgado, Daniel Ricardo Peña Carmona, Nasly Alexandra |
| dc.subject.ddc.spa.fl_str_mv |
66 Ingeniería química y Tecnologías relacionadas/ Chemical engineering 61 Ciencias médicas; Medicina / Medicine and health |
| topic |
66 Ingeniería química y Tecnologías relacionadas/ Chemical engineering 61 Ciencias médicas; Medicina / Medicine and health 3-Chloro-N-phenylphthalimide solubility solution thermodynamics activity coefficients preferential solvation 3-cloro-N-fenil-ftalimida solubilidad termodinámica de soluciones coeficiente de actividad solvatación preferencial |
| dc.subject.proposal.spa.fl_str_mv |
3-Chloro-N-phenylphthalimide solubility solution thermodynamics activity coefficients preferential solvation 3-cloro-N-fenil-ftalimida solubilidad termodinámica de soluciones coeficiente de actividad solvatación preferencial |
| description |
The thermodynamic properties of the 3-chloro-N-phenyl-phthalimide in acetone + methanol cosolvent mixtures were obtained from solubility data report in literature. The solubility was higher in near acetone and lower in pure methanol at all temperatures studied. A non-linear plot of ∆solnH° vs. ∆solnG° shows a negative slope from pure acetone up to x1 = 0.691. Beyond this composition, a variable positive slope is obtained with the exception of mixtures with x1 = 0.121, x1 = 0.272 and x1 = 0.356 which is a not common trend in these systems. The preferential solvation of 3-chloro-N-phenyl-phthalimide by the components of the solvents was estimated by means of the inverse Kirkwood–Buff integral method, showing the 3-chloro-Nphenyl-phthalimide is preferential solvated by methanol in more polar mixtures and by acetone in less polar ones. |
| publishDate |
2016 |
| dc.date.issued.spa.fl_str_mv |
2016-05-01 |
| dc.date.accessioned.spa.fl_str_mv |
2019-07-03T02:28:38Z |
| dc.date.available.spa.fl_str_mv |
2019-07-03T02:28:38Z |
| dc.type.spa.fl_str_mv |
Artículo de revista |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_6501 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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Text |
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http://purl.org/redcol/resource_type/ART |
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http://purl.org/coar/resource_type/c_6501 |
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publishedVersion |
| dc.identifier.issn.spa.fl_str_mv |
ISSN: 1909-6356 |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/66609 |
| dc.identifier.eprints.spa.fl_str_mv |
http://bdigital.unal.edu.co/67637/ |
| identifier_str_mv |
ISSN: 1909-6356 |
| url |
https://repositorio.unal.edu.co/handle/unal/66609 http://bdigital.unal.edu.co/67637/ |
| dc.language.iso.spa.fl_str_mv |
spa |
| language |
spa |
| dc.relation.spa.fl_str_mv |
https://revistas.unal.edu.co/index.php/rccquifa/article/view/59941 |
| dc.relation.ispartof.spa.fl_str_mv |
Universidad Nacional de Colombia Revistas electrónicas UN Revista Colombiana de Ciencias Químico Farmacéuticas Revista Colombiana de Ciencias Químico Farmacéuticas |
| dc.relation.references.spa.fl_str_mv |
Areiza Aldana, Grecia Angeline del Mar and Cavides Rubio, Diego Iván and Rodríguez Rodríguez, Gerson Andrés and Cuellar Lozano, Aleida and Mehrdad, Abbas and Delgado, Daniel Ricardo and Peña Carmona, Nasly Alexandra (2016) Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures. Revista Colombiana de Ciencias Químico-Farmacéuticas, 45 (2). pp. 256-274. ISSN 1909-6356 |
| dc.rights.spa.fl_str_mv |
Derechos reservados - Universidad Nacional de Colombia |
| dc.rights.coar.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
| dc.rights.license.spa.fl_str_mv |
Atribución-NoComercial 4.0 Internacional |
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http://creativecommons.org/licenses/by-nc/4.0/ |
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info:eu-repo/semantics/openAccess |
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Atribución-NoComercial 4.0 Internacional Derechos reservados - Universidad Nacional de Colombia http://creativecommons.org/licenses/by-nc/4.0/ http://purl.org/coar/access_right/c_abf2 |
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openAccess |
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application/pdf |
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Universidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Farmacia |
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Universidad Nacional de Colombia |
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1814090153695641600 |
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Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Areiza Aldana, Grecia Angeline del Mar507fe3b1-ee43-415f-a046-1b5ccc1bc386300Cavides Rubio, Diego Ivándebc00f2-17fe-404d-82e4-81217cca1c58300Rodríguez Rodríguez, Gerson Andrés0fda72a9-7cb7-4c74-b3b5-c08f735312be300Cuellar Lozano, Aleida13e6ceec-ca1b-4bb2-9796-496f1f5c264b300Mehrdad, Abbas7a8be490-5de7-45af-9fd5-f232f9e4df49300Delgado, Daniel Ricardodb7b15d5-a924-47e9-a3c1-ea3a0d3749c8300Peña Carmona, Nasly Alexandra0911c7dc-0168-4f56-bf09-84723ed047273002019-07-03T02:28:38Z2019-07-03T02:28:38Z2016-05-01ISSN: 1909-6356https://repositorio.unal.edu.co/handle/unal/66609http://bdigital.unal.edu.co/67637/The thermodynamic properties of the 3-chloro-N-phenyl-phthalimide in acetone + methanol cosolvent mixtures were obtained from solubility data report in literature. The solubility was higher in near acetone and lower in pure methanol at all temperatures studied. A non-linear plot of ∆solnH° vs. ∆solnG° shows a negative slope from pure acetone up to x1 = 0.691. Beyond this composition, a variable positive slope is obtained with the exception of mixtures with x1 = 0.121, x1 = 0.272 and x1 = 0.356 which is a not common trend in these systems. The preferential solvation of 3-chloro-N-phenyl-phthalimide by the components of the solvents was estimated by means of the inverse Kirkwood–Buff integral method, showing the 3-chloro-Nphenyl-phthalimide is preferential solvated by methanol in more polar mixtures and by acetone in less polar ones.Las propiedades termodinámicas de 3-cloro-N-fenil-ftalimida en mezclas cosolventes acetona + metanol fueron obtenidas a partir de los datos de solubilidad reportados en la literatura. La mayor solubilidad se presentó en acetona y la menor en metanol puro en todas las temperaturas estudiadas. La grafica ΔsolnH° vs. ΔsolnG° presenta una tendencia no lineal, con una pendiente negativa desde la acetona pura hasta x1 = 0,691 a partir de esta composición hasta el metanol puro se obtiene una pendiente positiva variable con la excepción de las mezclas con x1 = 0,121, x1 = 0,272 y x1 = 0,356, la cual es una tendencia poco común en estos sistemas. La solvatación preferencial de 3-cloro-N-fenil-ftalimida por cada uno de los solventes de la mezcla se estimó por medio del método de las integrales inversas de Kirkwood-Buff mostrando que la 3-cloro-N-fenil-ftalimida se solvata preferencialmente por metanol en las mezclas más polares y por acetona en las menos polares.application/pdfspaUniversidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Farmaciahttps://revistas.unal.edu.co/index.php/rccquifa/article/view/59941Universidad Nacional de Colombia Revistas electrónicas UN Revista Colombiana de Ciencias Químico FarmacéuticasRevista Colombiana de Ciencias Químico FarmacéuticasAreiza Aldana, Grecia Angeline del Mar and Cavides Rubio, Diego Iván and Rodríguez Rodríguez, Gerson Andrés and Cuellar Lozano, Aleida and Mehrdad, Abbas and Delgado, Daniel Ricardo and Peña Carmona, Nasly Alexandra (2016) Solution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixtures. Revista Colombiana de Ciencias Químico-Farmacéuticas, 45 (2). pp. 256-274. ISSN 1909-635666 Ingeniería química y Tecnologías relacionadas/ Chemical engineering61 Ciencias médicas; Medicina / Medicine and health3-Chloro-N-phenylphthalimidesolubilitysolution thermodynamicsactivity coefficientspreferential solvation3-cloro-N-fenil-ftalimidasolubilidadtermodinámica de solucionescoeficiente de actividadsolvatación preferencialSolution thermodynamics and preferential solvation of 3-chloro-N-phenyl-phthalimide in acetone + methanol mixturesArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTORIGINAL59941-304245-2-PB.pdfapplication/pdf874931https://repositorio.unal.edu.co/bitstream/unal/66609/1/59941-304245-2-PB.pdf980b571b07ff5cfbde9fcccd5349107aMD51THUMBNAIL59941-304245-2-PB.pdf.jpg59941-304245-2-PB.pdf.jpgGenerated Thumbnailimage/jpeg6315https://repositorio.unal.edu.co/bitstream/unal/66609/2/59941-304245-2-PB.pdf.jpgf65ef9645fb699bcdb1ca06fc317c524MD52unal/66609oai:repositorio.unal.edu.co:unal/666092024-05-17 23:08:50.532Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co |