Comportamiento cinético de la hidrogenación de furfural sobre catalizadores de ir soportados en tio₂
The kinetics of the liquidphase hydrogenation of furfuraldehyde to furfuryl alcohol over Ir catalysts supported over TiO₂ was studied in the temperature range of 323 to 373 K. The effect of furfural concentration, hydrogen pressure and the solvent effect were also studied. A high selectivity towards...
- Autores:
-
Rojas Sarmiento, Hugo Alfonso
Martínez-Zambrano, José Jobanny
Reyes Nuñez, Patricio
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2010
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/37594
- Acceso en línea:
- https://repositorio.unal.edu.co/handle/unal/37594
http://bdigital.unal.edu.co/27678/
- Palabra clave:
- Furfural
hydrogenation
SMSI effect
kinetic study.
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional
| Summary: | The kinetics of the liquidphase hydrogenation of furfuraldehyde to furfuryl alcohol over Ir catalysts supported over TiO₂ was studied in the temperature range of 323 to 373 K. The effect of furfural concentration, hydrogen pressure and the solvent effect were also studied. A high selectivity towards furfuryl alcohol was demonstrated. Initial rates describes the order global of the reaction. The experimental data could also be explained using the Langmuir-Hinshelwood model with of a single-site with dissociative adsorption of hydrogen and the surface reaction as the rate-controlling step provided the best fit of the experimental data. |
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