Producción de biodiésel no éster mediante desoxigenación catalítica de aceite de palma con generación de hidrógeno in situ

ilustraciones, diagramas

Autores:: Mayorga Betancourt, Manuel Alejandro

Tipo de recurso:: Doctoral thesis

Fecha de publicación:: 2023

Institución:: Universidad Nacional de Colombia

Repositorio:: Universidad Nacional de Colombia

Idioma:: spa

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network_acronym_str	UNACIONAL2
network_name_str	Universidad Nacional de Colombia
repository_id_str
dc.title.spa.fl_str_mv	Producción de biodiésel no éster mediante desoxigenación catalítica de aceite de palma con generación de hidrógeno in situ
dc.title.translated.eng.fl_str_mv	Non-ester biodiesel production by catalytic deoxygenation of palm oil with in situ hydrogen generation
title	Producción de biodiésel no éster mediante desoxigenación catalítica de aceite de palma con generación de hidrógeno in situ
spellingShingle	Producción de biodiésel no éster mediante desoxigenación catalítica de aceite de palma con generación de hidrógeno in situ 660 - Ingeniería química::661 - Tecnología de químicos industriales 660 - Ingeniería química::665 - Tecnología de aceites, grasas, ceras, gases industriales 660 - Ingeniería química::668 - Tecnología de otros productos orgánicos 540 - Química y ciencias afines::547 - Química orgánica 620 - Ingeniería y operaciones afines::628 - Ingeniería sanitaria 620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingeniería Energía biomásica Vital force Biomass energy Diésel renovable Donante Desoxigenación catalítica Generación de hidrógeno in situ Aceite de palma Hidrogenación por transferencia catalítica Reformado en fase acuosa Green diesel Donor Catalytic deoxygenation On-site hydrogen generation Palm oil Catalytic transfer hydrogenation (CTH) Aqueous phase reforming (APR)
title_short	Producción de biodiésel no éster mediante desoxigenación catalítica de aceite de palma con generación de hidrógeno in situ
title_full	Producción de biodiésel no éster mediante desoxigenación catalítica de aceite de palma con generación de hidrógeno in situ
title_fullStr	Producción de biodiésel no éster mediante desoxigenación catalítica de aceite de palma con generación de hidrógeno in situ
title_full_unstemmed	Producción de biodiésel no éster mediante desoxigenación catalítica de aceite de palma con generación de hidrógeno in situ
title_sort	Producción de biodiésel no éster mediante desoxigenación catalítica de aceite de palma con generación de hidrógeno in situ
dc.creator.fl_str_mv	Mayorga Betancourt, Manuel Alejandro
dc.contributor.advisor.none.fl_str_mv	Cadavid Estrada, Juan Guillermo Narváez Rincón, Paulo César
dc.contributor.author.none.fl_str_mv	Mayorga Betancourt, Manuel Alejandro
dc.contributor.researchgroup.spa.fl_str_mv	Grupo de Investigación en Procesos Químicos y Bioquímicos
dc.contributor.orcid.spa.fl_str_mv	Mayorga, Manuel A. [0000-0001-6207-8338]
dc.contributor.cvlac.spa.fl_str_mv	Mayorga Betancourt, Manuel Alejandro [https://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0000947229]
dc.contributor.scopus.spa.fl_str_mv	Mayorga Betancourt, Manuel Alejandro [57209243312]
dc.contributor.researchgate.spa.fl_str_mv	Manuel Alejandro Mayorga Betancourt [https://www.researchgate.net/profile/Manuel-Mayorga-Betancourt-2/stats]
dc.contributor.googlescholar.spa.fl_str_mv	Manuel Alejandro Mayorga Betancourt [https://scholar.google.com/citations?user=wyQTSPEAAAAJ&hl=es]
dc.subject.ddc.spa.fl_str_mv	660 - Ingeniería química::661 - Tecnología de químicos industriales 660 - Ingeniería química::665 - Tecnología de aceites, grasas, ceras, gases industriales 660 - Ingeniería química::668 - Tecnología de otros productos orgánicos 540 - Química y ciencias afines::547 - Química orgánica 620 - Ingeniería y operaciones afines::628 - Ingeniería sanitaria 620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingeniería
topic	660 - Ingeniería química::661 - Tecnología de químicos industriales 660 - Ingeniería química::665 - Tecnología de aceites, grasas, ceras, gases industriales 660 - Ingeniería química::668 - Tecnología de otros productos orgánicos 540 - Química y ciencias afines::547 - Química orgánica 620 - Ingeniería y operaciones afines::628 - Ingeniería sanitaria 620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingeniería Energía biomásica Vital force Biomass energy Diésel renovable Donante Desoxigenación catalítica Generación de hidrógeno in situ Aceite de palma Hidrogenación por transferencia catalítica Reformado en fase acuosa Green diesel Donor Catalytic deoxygenation On-site hydrogen generation Palm oil Catalytic transfer hydrogenation (CTH) Aqueous phase reforming (APR)
dc.subject.lemb.spa.fl_str_mv	Energía biomásica
dc.subject.lemb.eng.fl_str_mv	Vital force Biomass energy
dc.subject.proposal.spa.fl_str_mv	Diésel renovable Donante Desoxigenación catalítica Generación de hidrógeno in situ Aceite de palma Hidrogenación por transferencia catalítica Reformado en fase acuosa
dc.subject.proposal.eng.fl_str_mv	Green diesel Donor Catalytic deoxygenation On-site hydrogen generation Palm oil Catalytic transfer hydrogenation (CTH) Aqueous phase reforming (APR)
description	ilustraciones, diagramas
publishDate	2023
dc.date.accessioned.none.fl_str_mv	2023-09-01T19:24:45Z
dc.date.available.none.fl_str_mv	2023-09-01T19:24:45Z
dc.date.issued.none.fl_str_mv	2023
dc.type.spa.fl_str_mv	Trabajo de grado - Doctorado
dc.type.driver.spa.fl_str_mv	info:eu-repo/semantics/doctoralThesis
dc.type.version.spa.fl_str_mv	info:eu-repo/semantics/acceptedVersion
dc.type.coar.spa.fl_str_mv	http://purl.org/coar/resource_type/c_db06
dc.type.content.spa.fl_str_mv	DataPaper Text
dc.type.redcol.spa.fl_str_mv	http://purl.org/redcol/resource_type/TD
format	http://purl.org/coar/resource_type/c_db06
status_str	acceptedVersion
dc.identifier.uri.none.fl_str_mv	https://repositorio.unal.edu.co/handle/unal/84628
dc.identifier.instname.spa.fl_str_mv	Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv	Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv	https://repositorio.unal.edu.co/
url	https://repositorio.unal.edu.co/handle/unal/84628 https://repositorio.unal.edu.co/
identifier_str_mv	Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv	spa
language	spa
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dc.publisher.spa.fl_str_mv	Universidad Nacional de Colombia
dc.publisher.program.spa.fl_str_mv	Bogotá - Ingeniería - Doctorado en Ingeniería - Ingeniería Química
dc.publisher.faculty.spa.fl_str_mv	Facultad de Ingeniería
dc.publisher.place.spa.fl_str_mv	Bogotá, Colombia
dc.publisher.branch.spa.fl_str_mv	Universidad Nacional de Colombia - Sede Bogotá
institution	Universidad Nacional de Colombia
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spelling	Atribución-NoComercial 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Cadavid Estrada, Juan Guillermobc8a518da0b6532a694c51e2d0e34e1dNarváez Rincón, Paulo César1424150a73b4193d8936a493fb231fd5Mayorga Betancourt, Manuel Alejandro3ace50d44cc941fe7e14ce57e90a29bcGrupo de Investigación en Procesos Químicos y BioquímicosMayorga, Manuel A. [0000-0001-6207-8338]Mayorga Betancourt, Manuel Alejandro [https://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0000947229]Mayorga Betancourt, Manuel Alejandro [57209243312]Manuel Alejandro Mayorga Betancourt [https://www.researchgate.net/profile/Manuel-Mayorga-Betancourt-2/stats]Manuel Alejandro Mayorga Betancourt [https://scholar.google.com/citations?user=wyQTSPEAAAAJ&hl=es]2023-09-01T19:24:45Z2023-09-01T19:24:45Z2023https://repositorio.unal.edu.co/handle/unal/84628Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, diagramasEl desarrollo de biocombustibles avanzados es una opción que contribuye a la transición energética a corto y mediano plazo. Así, en esta investigación se verificó experimentalmente la obtención de biodiésel no éster por desoxigenación catalítica de aceite de palma con hidrógeno generado in situ en lugar de alimentarlo. Entonces se definieron dos sistemas catalíticos capaces de generarlo, por transferencia catalítica y/o reformado en fase acuosa, a partir de donantes como ácido fórmico y etanol, para luego hidrotratar los triglicéridos. Se seleccionaron como fases activas platino y paladio soportadas al 5% en carbono, así como su mezcla equimásica. Para estudiar primordialmente el rendimiento de hidrocarburos y la selectividad hacia hidrodesoxigenación, se evaluó el proceso con exceso hidrógeno del 50% y 100%, a 250 °C y 300 °C. El sistema 5% Pt/C con ácido fórmico en un exceso del 50% a 300 °C presentó el mejor desempeño en la producción de hidrocarburos, pues se obtuvo un producto líquido con 94% principalmente de n-pentadecano y n-heptadecano, por lo que favoreció la descarbonilación-descarboxilación, minimizando la selectividad. La temperatura es la variable de mayor incidencia en la producción de hidrocarburos, tal que para el mismo sistema de platino con 100% de exceso de fórmico a 250 °C se obtuvieron menos hidrocarburos aunque se maximizó la selectividad. Mientras que el sistema platino-paladio con un exceso del 50% de ácido fórmico a 300 °C fue el más equilibrado en rendimiento y selectividad. Las diferencias observadas en la actividad de ambos catalizadores, se explican en parte por la mayor mesoporosidad y dispersión del platino. (Texto tomado de la fuente)The development of advanced biofuels is an option that contributes to the energy transition in the short and medium term. Thus, in this research, the obtaining of non-ester biodiesel by catalytic deoxygenation of palm oil with hydrogen generated in situ instead of feeding it was experimentally verified. Two catalytic systems capable of generating it were then defined, by catalytic transfer and/or reforming in the aqueous phase, from donors such as formic acid and ethanol, to then hydrotreat the triglycerides. Platinum and palladium supported at 5% on carbon were selected as active phases, as well as their of equal mass mixture. To primarily study the yield of hydrocarbons and the selectivity towards hydrodeoxygenation, the process was evaluated with excess hydrogen of 50% and 100%, at 250 °C and 300 °C. The 5% Pt/C system with formic acid in excess of 50% at 300 °C presented the best performance in the production of hydrocarbons, since a liquid product with 94% mainly n-pentadecane and n-heptadecane was obtained, for which favored decarbonylation-decarboxylation, minimizing selectivity. Temperature is the variable with the highest incidence in the production of hydrocarbons, such that for the same platinum system with 100% excess formic at 250 °C, the less hydrocarbons were obtained, although selectivity was maximized. While the platinum-palladium system with a 50% excess of formic acid at 300 °C was the most balanced in yield and selectivity. The differences observed in the activity of both catalysts are partly explained by the higher mesoporosity and dispersion of platinum.Universidad ECCIInstituto de Investigaciones en Catálisis y Petroquímica, INCAPE, de la Universidad Nacional del Litoral (UNL) y del Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) de Santa Fe, ArgentinaDoctoradoDoctor en IngenieríaExperimental, empleando un diseño factorial con cuatro (4) factores: tres (3) sistemas catalíticos (5%Pt/C, 5% Pd/C y Mezcla equimásica 5% Pt/C - 5% Pd/C), dos (2) donantes de hidrógeno (ácido fórmico y alcohol etílico), dos (2) excesos de donante (50% y 100%), y dos (2) temperaturas (250 °C y 300 °C). Las variables de respuesta fueron el rendimiento en la producción de hidrocarburos, la selectividad por la ruta de la hidrodesoxigenación, la concentración de hidrógeno generado y la conversión del aceite de palma. El análisis químico se realizó mediante GC y HPLC, mientras que los catalizadores empleados fueron caracterización en estado fresco y usado.Biorrefinerías y Biocombustiblesxiii, 352application/pdfspaUniversidad Nacional de ColombiaBogotá - Ingeniería - Doctorado en Ingeniería - Ingeniería QuímicaFacultad de IngenieríaBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá660 - Ingeniería química::661 - Tecnología de químicos industriales660 - Ingeniería química::665 - Tecnología de aceites, grasas, ceras, gases industriales660 - Ingeniería química::668 - Tecnología de otros productos orgánicos540 - Química y ciencias afines::547 - Química orgánica620 - Ingeniería y operaciones afines::628 - Ingeniería sanitaria620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingenieríaEnergía biomásicaVital forceBiomass energyDiésel renovableDonanteDesoxigenación catalíticaGeneración de hidrógeno in situAceite de palmaHidrogenación por transferencia catalíticaReformado en fase acuosaGreen dieselDonorCatalytic deoxygenationOn-site hydrogen generationPalm oilCatalytic transfer hydrogenation (CTH)Aqueous phase reforming (APR)Producción de biodiésel no éster mediante desoxigenación catalítica de aceite de palma con generación de hidrógeno in situNon-ester biodiesel production by catalytic deoxygenation of palm oil with in situ hydrogen generationTrabajo de grado - Doctoradoinfo:eu-repo/semantics/doctoralThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_db06DataPaperTexthttp://purl.org/redcol/resource_type/TDAatola, H., Larmi, M., Sarjovaara, T., & Mikkonen, S. (2008). Hydrotreated Vegetable Oil (HVO) as a Renewable Diesel Fuel: Trade-off between NOx, Particulate Emission, and Fuel Consumption of a Heavy Duty Engine. SAE Technical Paper 2008-01-2500. SAE Technical Papers, 724, 12. https://doi.org/10.4271/2008-01-2500Aatola, H., Larmi, M., Sarjovaara, T., & Mikkonen, S. (2008). Hydrotreated Vegetable Oil (HVO) as a Renewable Diesel Fuel: Trade-off between NOx, Particulate Emission, and Fuel Consumption of a Heavy Duty Engine. SAE Technical Paper 2008-01-2500. SAE Technical Papers, 724, 12. https://doi.org/10.4271/2008-01-2500Acid, F. (1960). Phys. Org. 1923. 1923–1925Afonso, M., Pedroza, P., Soter, I., Segtovich, V., Sermoud, V. D. M., & Antunes, M. (2022). Hydrodeoxygenation of stearic acid to produce diesel – like hydrocarbons: kinetic modeling, parameter estimation and simulation. Chemical Engineering Science, 254, 117576. https://doi.org/10.1016/j.ces.2022.117576Ahmadi, M., Nambo, A., Jasinski, J. B., Ratnasamy, P., & Carreon, M. A. 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Chemical Engineering Journal, 444(February), 1–25. https://doi.org/10.1016/j.cej.2022.136564Producción de Biodiésel No Éster Mediante Desoxigenación Catalítica de Aceite de Palma con Generación de Hidrógeno In Situ - Convocatoria Nacional de Proyectos para el Fortalecimiento de la Investigación, Creación e Innovación de la Universidad Nacional de Colombia 2016-20 (Código Hermes 37622)Producción de Biodiésel No Éster Mediante Desoxigenación Catalítica de Aceite de Palma con Generación de Hidrógeno In Situ - crédito-beca de la Convocatoria Doctorado Nacional 647 de 2014 (asignado mediante la Resolución 23 de 2015 de la Vicerrectoría Académica de la Universidad Nacional de Colombia)Ministerio de Ciencia, Tecnología e InnovaciónUniversidad Nacional de ColombiaEstudiantesInvestigadoresMaestrosLICENSElicense.txtlicense.txttext/plain; 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Producción de biodiésel no éster mediante desoxigenación catalítica de aceite de palma con generación de hidrógeno in situ

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