Producción y caracterización de propiedades anticorrosivas del recubrimiento TiAlSiN depositadas con el sistema de sputtering reactivo

ilustraciones, graficas, tablas

Autores:: Cañon Tafur, Luis Alejandro

Tipo de recurso:

Fecha de publicación:: 2017

Institución:: Universidad Nacional de Colombia

Repositorio:: Universidad Nacional de Colombia

Idioma:: spa

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network_acronym_str	UNACIONAL2
network_name_str	Universidad Nacional de Colombia
repository_id_str
dc.title.spa.fl_str_mv	Producción y caracterización de propiedades anticorrosivas del recubrimiento TiAlSiN depositadas con el sistema de sputtering reactivo
dc.title.translated.eng.fl_str_mv	Production and characterization of anticorrosive properties of the TiAlSiN coating deposited with the reactive sputtering system
title	Producción y caracterización de propiedades anticorrosivas del recubrimiento TiAlSiN depositadas con el sistema de sputtering reactivo
spellingShingle	Producción y caracterización de propiedades anticorrosivas del recubrimiento TiAlSiN depositadas con el sistema de sputtering reactivo 670 - Manufactura::671 - Proceso de metalurgia y productos metálicos primarios 620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingeniería Recubrimiento TiAlSiN Sputtering Magnetrón Corrosión Microdureza Desgaste Factorial Fraccionado TiAlSiN Coating Sputtering Magnetron Corrosion Microhardness Wear Fractional Factorial Design Corrosión Corrosion
title_short	Producción y caracterización de propiedades anticorrosivas del recubrimiento TiAlSiN depositadas con el sistema de sputtering reactivo
title_full	Producción y caracterización de propiedades anticorrosivas del recubrimiento TiAlSiN depositadas con el sistema de sputtering reactivo
title_fullStr	Producción y caracterización de propiedades anticorrosivas del recubrimiento TiAlSiN depositadas con el sistema de sputtering reactivo
title_full_unstemmed	Producción y caracterización de propiedades anticorrosivas del recubrimiento TiAlSiN depositadas con el sistema de sputtering reactivo
title_sort	Producción y caracterización de propiedades anticorrosivas del recubrimiento TiAlSiN depositadas con el sistema de sputtering reactivo
dc.creator.fl_str_mv	Cañon Tafur, Luis Alejandro
dc.contributor.advisor.none.fl_str_mv	Jhon Jairo, Olaya Florez Luis Camilo, Jimenez Borrego
dc.contributor.author.none.fl_str_mv	Cañon Tafur, Luis Alejandro
dc.contributor.researchgroup.spa.fl_str_mv	GRUPO DE INVESTIGACIÓN AFIS (ANÁLISIS DE FALLAS, INTEGRIDAD Y SUPERFICIES)
dc.subject.ddc.spa.fl_str_mv	670 - Manufactura::671 - Proceso de metalurgia y productos metálicos primarios 620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingeniería
topic	670 - Manufactura::671 - Proceso de metalurgia y productos metálicos primarios 620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingeniería Recubrimiento TiAlSiN Sputtering Magnetrón Corrosión Microdureza Desgaste Factorial Fraccionado TiAlSiN Coating Sputtering Magnetron Corrosion Microhardness Wear Fractional Factorial Design Corrosión Corrosion
dc.subject.proposal.spa.fl_str_mv	Recubrimiento TiAlSiN Sputtering Magnetrón Corrosión Microdureza Desgaste Factorial Fraccionado
dc.subject.proposal.eng.fl_str_mv	TiAlSiN Coating Sputtering Magnetron Corrosion Microhardness Wear Fractional Factorial Design
dc.subject.unesco.none.fl_str_mv	Corrosión Corrosion
description	ilustraciones, graficas, tablas
publishDate	2017
dc.date.issued.none.fl_str_mv	2017
dc.date.accessioned.none.fl_str_mv	2021-05-04T21:41:33Z
dc.date.available.none.fl_str_mv	2021-05-04T21:41:33Z
dc.type.spa.fl_str_mv	Trabajo de grado - Maestría
dc.type.driver.spa.fl_str_mv	info:eu-repo/semantics/masterThesis
dc.type.version.spa.fl_str_mv	info:eu-repo/semantics/acceptedVersion
dc.type.content.spa.fl_str_mv	Text
dc.type.redcol.spa.fl_str_mv	http://purl.org/redcol/resource_type/TM
status_str	acceptedVersion
dc.identifier.uri.none.fl_str_mv	https://repositorio.unal.edu.co/handle/unal/79475
dc.identifier.instname.spa.fl_str_mv	Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv	Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv	https://repositorio.unal.edu.co/
url	https://repositorio.unal.edu.co/handle/unal/79475 https://repositorio.unal.edu.co/
identifier_str_mv	Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv	spa
language	spa
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dc.rights.spa.spa.fl_str_mv	Acceso abierto
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rights_invalid_str_mv	Atribución-SinDerivadas 4.0 Internacional http://creativecommons.org/licenses/by-nd/4.0/ Acceso abierto http://purl.org/coar/access_right/c_abf2
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dc.format.extent.spa.fl_str_mv	1 recurso en linea (208 paginas)
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dc.publisher.spa.fl_str_mv	Universidad Nacional de Colombia
dc.publisher.program.spa.fl_str_mv	Bogotá - Ingeniería - Maestría en Ingeniería - Materiales y Procesos Bogotá - Ingeniería - Maestría en Ingeniería - Materiales y Procesos
dc.publisher.faculty.spa.fl_str_mv	Facultad de Ingeniería
dc.publisher.place.spa.fl_str_mv	Bogotá
dc.publisher.branch.spa.fl_str_mv	Universidad Nacional de Colombia - Sede Bogotá
institution	Universidad Nacional de Colombia
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spelling	Atribución-SinDerivadas 4.0 Internacionalhttp://creativecommons.org/licenses/by-nd/4.0/Acceso abiertoinfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Jhon Jairo, Olaya Florez84912df202553b9a5e7ef52e04211d3bLuis Camilo, Jimenez Borregof46e9dce295463521b1c833476660778Cañon Tafur, Luis Alejandro8f9c0c1f8f62107443ee1945dab82aebGRUPO DE INVESTIGACIÓN AFIS (ANÁLISIS DE FALLAS, INTEGRIDAD Y SUPERFICIES)2021-05-04T21:41:33Z2021-05-04T21:41:33Z2017https://repositorio.unal.edu.co/handle/unal/79475Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, graficas, tablasEn este trabajo se elaboraron recubrimientos nano-estructuradas de TiAlSiN sobre sustratos de acero 316l, mediante la técnica sputtering magnetrón reactivo, se evaluó su Microdureza, rugosidad, adherencia, resistencia a la corrosión y al desgaste. La micro estructura de los recubrimientos se analizó por medio de Difracción de rayos x por medio de la técnica Bragg- Bretano, Microscopio electrónica de barrido, Microscopia de fuerza atómica, y interferómetro. Los recubrimientos obtenidos poseen una superficie de muy baja rugosidad, esta magnitud disminuye con un aumento de la cantidad de silicio sobre el recubrimiento y además factores como la cantidad de nitrógeno y potencia tienen un mayor efecto sobre la morfología de la superficie, esta relación se establece de acuerdo al diseño de experimentos factorial fraccionado establecido para este trabajo. Los recubrimientos se realizaron en una atmosfera reactiva 40%N y 60%Ar, con una potencia de 150 W durante 30 minutos sobre sustratos de acero 316l y silicio con orientación preferencial (100). De la caracterización electroquímica, los recubrimientos disminuyeron la velocidad de corrosión del sustrato cerca a los 2 órdenes de magnitud, a la pruebas de impedancia electroquímica se en diferentes intervalos de tiempo (0h, 24h, 48h, 72h, y 168h)muestran una variación de tipo farádico, controlado por elementos capacitores y fue representado por un circuito equivalente que se ajusta a los resultados de la respuesta según el diagrama de bode y al ajuste Kramers Kroning, la resistencia a la corrosión para los recubrimientos obtenidos no depende de la cantidad de silicio de los recubrimientos, pero se relaciona con el espesor. Los recubrimientos obtenidos muestran que la resistencia al desgaste depende de la dureza del recubrimiento y la rugosidad, en nuestro sistema estos parámetros se controlaron con la cantidad de silicio que fueron agregados al blanco durante la deposición.In this work, nano-structured TiAlSiN coatings on 316l steel substrates were prepared using the reactive magnetron sputtering technique. Their microhardness, roughness, adhesion, corrosion resistance and wear were evaluated. The microstructure of the coatings was analyzed by X-ray diffraction using the Bragg-Bretano technique, scanning electron microscope, atomic force microscopy, and interferometer. The obtained coatings have a surface of very low roughness, this quantity decreases with an increase of the amount of silicon on the coating and also factors like the quantity of nitrogen and power have a greater effect on the surface morphology, this relation is established According to the design of fractional factorial experiments established for this work. The coatings were made in a 40% N and 60% Ar reactive atmosphere, with a power of 150 W for 30 minutes on substrates of 316l steel and silicon with preferential orientation (100). From the electrochemical characterization, the coatings decreased the corrosion rate of the substrate near 2 orders of magnitude, the tests of electrochemical impedance at different time intervals (0h, 24h, 48h, 72h, and 168h) show a variation of Faronic type, controlled by capacitors and was represented by an equivalent circuit that conforms to the results of the response according to the bode diagram and the Kramers Kroning setting, the corrosion resistance for the coatings obtained does not depend on the amount of silicon Of the coatings, but is related to the thickness. The obtained coatings show that the resistance to the wear depends on the hardness of the coating and the roughness, in our system these parameters were controlled with the amount of silicon that were added to the target during the deposition.MaestríaIngeniería de Superficies Corrosión1 recurso en linea (208 paginas)application/pdfspaUniversidad Nacional de ColombiaBogotá - Ingeniería - Maestría en Ingeniería - Materiales y ProcesosBogotá - Ingeniería - Maestría en Ingeniería - Materiales y ProcesosFacultad de IngenieríaBogotáUniversidad Nacional de Colombia - Sede Bogotá670 - Manufactura::671 - Proceso de metalurgia y productos metálicos primarios620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingenieríaRecubrimientoTiAlSiNSputteringMagnetrónCorrosiónMicrodurezaDesgasteFactorialFraccionadoTiAlSiN CoatingSputtering MagnetronCorrosionMicrohardnessWearFractional Factorial DesignCorrosiónCorrosionProducción y caracterización de propiedades anticorrosivas del recubrimiento TiAlSiN depositadas con el sistema de sputtering reactivoProduction and characterization of anticorrosive properties of the TiAlSiN coating deposited with the reactive sputtering systemTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TM[1] V. K. Sarin, Comprehensive Hard Materials Vol I, Elsevier. Boston, MA: 2014, 2014.[2] H. C. B. Ã, B. Deepthi, and K. S. Rajam, “Deposition and characterization of TiAlN / Si 3 N 4 superhard nanocomposite coatings prepared by reactive direct current unbalanced magnetron sputtering,” vol. 81, pp. 479–488, 2006.[3] J. C. Oliveira, A. Manaia, and A. Cavaleiro, “Hard amorphous Ti-Al-N coatings deposited by sputtering,” Thin Solid Films, vol. 516, no. 15, pp. 5032–5038, 2008.[4] S. po Wam, “Struture Characterization and Mechanical Properties of Industrial PVD-TiAlN Coatings,” Run Run Shaw Libr. Copyr., p. 269, 2005.[5] L. Velasco, J. J. Olaya, and S. E. Rodil, “Effect of Si addition on the structure and corrosion behavior of NbN thin films deposited by unbalanced magnetron sputtering,” Appl. Phys. A Mater. Sci. Process., vol. 122, no. 2, pp. 1–10, 2016.[6] A. Miletić, P. Panjan, B. Škorić, M. Čekada, G. Dražič, and J. 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