Síntesis y desarrollo de un anclaje químico estable de MOF-199 y MOF UiO-66-NH2 obtenidos ex situ sobre poliéster y celulosa, con potencial aplicación como textiles antibacteriales
ilustraciones, fotografías, gráficas, tablas
- Autores:
-
Torres Cortés, Sergio Alejandro
- Tipo de recurso:
- Fecha de publicación:
- 2021
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/81572
- Palabra clave:
- 540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales
Anti-Bacterial Agents
Antibacterianos
Textile chemistry
Chemistry, organic
Química textil
Química orgánica
Red metalorgánica
Inhibición bacteriana
Anclaje químico
Estado sólido
Bacterial inhibition
Reticular chemistry
Metalorganic framework
- Rights
- openAccess
- License
- Atribución-NoComercial-CompartirIgual 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Síntesis y desarrollo de un anclaje químico estable de MOF-199 y MOF UiO-66-NH2 obtenidos ex situ sobre poliéster y celulosa, con potencial aplicación como textiles antibacteriales |
| dc.title.translated.eng.fl_str_mv |
Synthesis and development of a stable chemical anchor of MOF-199 and MOF UiO-66-NH2 obtained ex situ on polyester and cellulose, with potential application as antibacterial textiles |
| title |
Síntesis y desarrollo de un anclaje químico estable de MOF-199 y MOF UiO-66-NH2 obtenidos ex situ sobre poliéster y celulosa, con potencial aplicación como textiles antibacteriales |
| spellingShingle |
Síntesis y desarrollo de un anclaje químico estable de MOF-199 y MOF UiO-66-NH2 obtenidos ex situ sobre poliéster y celulosa, con potencial aplicación como textiles antibacteriales 540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales Anti-Bacterial Agents Antibacterianos Textile chemistry Chemistry, organic Química textil Química orgánica Red metalorgánica Inhibición bacteriana Anclaje químico Estado sólido Bacterial inhibition Reticular chemistry Metalorganic framework |
| title_short |
Síntesis y desarrollo de un anclaje químico estable de MOF-199 y MOF UiO-66-NH2 obtenidos ex situ sobre poliéster y celulosa, con potencial aplicación como textiles antibacteriales |
| title_full |
Síntesis y desarrollo de un anclaje químico estable de MOF-199 y MOF UiO-66-NH2 obtenidos ex situ sobre poliéster y celulosa, con potencial aplicación como textiles antibacteriales |
| title_fullStr |
Síntesis y desarrollo de un anclaje químico estable de MOF-199 y MOF UiO-66-NH2 obtenidos ex situ sobre poliéster y celulosa, con potencial aplicación como textiles antibacteriales |
| title_full_unstemmed |
Síntesis y desarrollo de un anclaje químico estable de MOF-199 y MOF UiO-66-NH2 obtenidos ex situ sobre poliéster y celulosa, con potencial aplicación como textiles antibacteriales |
| title_sort |
Síntesis y desarrollo de un anclaje químico estable de MOF-199 y MOF UiO-66-NH2 obtenidos ex situ sobre poliéster y celulosa, con potencial aplicación como textiles antibacteriales |
| dc.creator.fl_str_mv |
Torres Cortés, Sergio Alejandro |
| dc.contributor.advisor.spa.fl_str_mv |
Sierra Ávila, César Augusto |
| dc.contributor.author.spa.fl_str_mv |
Torres Cortés, Sergio Alejandro |
| dc.contributor.researchgroup.spa.fl_str_mv |
Grupo de Investigación en Macromoléculas |
| dc.subject.ddc.spa.fl_str_mv |
540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales |
| topic |
540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales Anti-Bacterial Agents Antibacterianos Textile chemistry Chemistry, organic Química textil Química orgánica Red metalorgánica Inhibición bacteriana Anclaje químico Estado sólido Bacterial inhibition Reticular chemistry Metalorganic framework |
| dc.subject.decs.eng.fl_str_mv |
Anti-Bacterial Agents |
| dc.subject.decs.spa.fl_str_mv |
Antibacterianos |
| dc.subject.lemb.eng.fl_str_mv |
Textile chemistry Chemistry, organic |
| dc.subject.lemb.spa.fl_str_mv |
Química textil Química orgánica |
| dc.subject.proposal.spa.fl_str_mv |
Red metalorgánica Inhibición bacteriana Anclaje químico Estado sólido |
| dc.subject.proposal.eng.fl_str_mv |
Bacterial inhibition Reticular chemistry Metalorganic framework |
| description |
ilustraciones, fotografías, gráficas, tablas |
| publishDate |
2021 |
| dc.date.issued.none.fl_str_mv |
2021 |
| dc.date.accessioned.none.fl_str_mv |
2022-06-13T19:26:41Z |
| dc.date.available.none.fl_str_mv |
2022-06-13T19:26:41Z |
| dc.type.spa.fl_str_mv |
Trabajo de grado - Maestría |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/masterThesis |
| dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/acceptedVersion |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/TM |
| status_str |
acceptedVersion |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/81572 |
| dc.identifier.instname.spa.fl_str_mv |
Universidad Nacional de Colombia |
| dc.identifier.reponame.spa.fl_str_mv |
Repositorio Institucional Universidad Nacional de Colombia |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.unal.edu.co/ |
| url |
https://repositorio.unal.edu.co/handle/unal/81572 https://repositorio.unal.edu.co/ |
| identifier_str_mv |
Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia |
| dc.language.iso.spa.fl_str_mv |
spa |
| language |
spa |
| dc.relation.references.spa.fl_str_mv |
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McFarland Standard. McFarland Standards for in Vitro Use Only. 2014, p 2. Mahmoodi, N. M.; Abdi, J. Nanoporous Metal-Organic Framework (MOF-199): Synthesis, Characterization and Photocatalytic Degradation of Basic Blue 41. Microchem. J. 2019. https://doi.org/10.1016/j.microc.2018.09.033. Rowsell, J. L. C.; Yaghi, O. M. Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal-Organic Frameworks. J. Am. Chem. Soc. 2006, 128 (4), 1304–1315. https://doi.org/10.1021/ja056639q. Neufeld, M. J.; Harding, J. L.; Reynolds, M. M. Immobilization of Metal-Organic Framework Copper(II) Benzene-1,3,5-Tricarboxylate (CuBTC) onto Cotton Fabric as a Nitric Oxide Release Catalyst. ACS Appl. Mater. Interfaces 2015, 7 (48), 26742–26750. https://doi.org/10.1021/acsami.5b08773. Du, X. D.; Yi, X. H.; Wang, P.; Zheng, W.; Deng, J.; Wang, C. C. Robust Photocatalytic Reduction of Cr(VI) on UiO-66-NH2(Zr/Hf) Metal-Organic Framework Membrane under Sunlight Irradiation. Chem. Eng. J. 2019, 356 (September 2018), 393–399. https://doi.org/10.1016/j.cej.2018.09.084. Decoste, J. B.; Peterson, G. W.; Jasuja, H.; Glover, T. G.; Huang, Y. G.; Walton, K. S. Stability and Degradation Mechanisms of Metal-Organic Frameworks Containing the Zr6O4(OH)4 Secondary Building Unit. J. Mater. Chem. A 2013, 1 (18), 5642–5650. https://doi.org/10.1039/c3ta10662d. Xi, F. G.; Liu, H.; Yang, N. N.; Gao, E. Q. Aldehyde-Tagged Zirconium Metal-Organic Frameworks: A Versatile Platform for Postsynthetic Modification. Inorg. Chem. 2016, 55 (10), 4701–4703. https://doi.org/10.1021/acs.inorgchem.6b00598. Jung, H.; Kim, M. K.; Lee, J.; Kwon, J. H.; Lee, J. Characterization of the Zirconium Metal-Organic Framework (MOF) UiO-66-NH2 for the Decomposition of Nerve Agents in Solid-State Conditions Using Phosphorus-31 Solid State-Magic Angle Spinning Nuclear Magnetic Resonance (31P SS-MAS NMR) and Gas Chromatogra. Anal. Lett. 2021, 54 (3), 468–480. https://doi.org/10.1080/00032719.2020.1768399. Tian, P.; He, X.; Li, W.; et al. Zr-MOFs Based on Keggin-Type Polyoxometalates for Photocatalytic Hydrogen Production. J. Mater. Sci. 2018, 53 (17), 12016–12029. https://doi.org/10.1007/s10853-018-2476-0. Zhang, X. F.; Feng, Y.; Wang, Z.; Jia, M.; Yao, J. Fabrication of Cellulose Nanofibrils/UiO-66-NH2 Composite Membrane for CO2/N2 Separation. J. Memb. Sci. 2018, 568, 10–16. https://doi.org/10.1016/j.memsci.2018.09.055. Habibi, Y.; Chanzy, H.; Vignon, M. R. TEMPO-Mediated Surface Oxidation of Cellulose Whiskers. Cellulose 2006, 13 (6), 679–687. https://doi.org/10.1007/s10570-006-9075-y. Segal, L.; Creely, J. J.; Martin, A. E.; Conrad, C. M. 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Asp. 2021, 611, 125888. https://doi.org/10.1016/j.colsurfa.2020.125888. Kaur, N.; Tiwari, P.; Kapoor, K. S.; Saini, A. K.; Sharma, V.; Mobin, S. M. Metal-Organic Framework Based Antibiotic Release and Antimicrobial Response: An Overview. CrystEngComm 2020, 22 (44), 7513–7527. https://doi.org/10.1039/d0ce01215g. Madigan, M.; Martinko, J.; Bender, K.; Buckley, D.; Stahl, D. Brock - Biología de Los Microorganismos, 14th ed.; Education, P., Ed.; Pearson: Madrid, 2015. |
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Universidad Nacional de Colombia |
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Bogotá - Ciencias - Maestría en Ciencias - Química |
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Departamento de Química |
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Facultad de Ciencias |
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Atribución-NoComercial-CompartirIgual 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Sierra Ávila, César Augusto394dd93f7303a80405d9212168b6c837Torres Cortés, Sergio Alejandro95c5981ea3a2ffcf45ea3846227d8bf8600Grupo de Investigación en Macromoléculas2022-06-13T19:26:41Z2022-06-13T19:26:41Z2021https://repositorio.unal.edu.co/handle/unal/81572Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, fotografías, gráficas, tablasEn este trabajo, se realizó la síntesis y caracterización de dos Redes Metalorgánicas (MOFs): MOF-199 (HKUST-1) y MOF UiO-66-NH2. Asimismo, se realizó la funcionalización y grafting de sustratos textiles de poliéster (PET), PET/algodón 50:50 y celulosa (algodón) a través de reacciones de polimerización ATRPARGET-SI y oxidación selectiva con el sistema TEMPO/NaClO/NaBr/NaClO2, con el fin de incrementar la concentración de grupos carboxilato (-COO-) en la superficie del textil, y así, convertirlos en puntos de anclaje químico por enlaces de coordinación con los MOFs previamente obtenidos. Acorde con los resultados de este proceso, se obtuvieron concentraciones promedio de grupos carboxilato de 0,019 mmol/g para el algodón y 0,022 mmol/g para el PET/algodón, respecto a blanco de algodón. Respecto al anclaje de MOF-199 y MOF UiO-66-NH2 producidos ex situ sobre las telas funcionalizadas, se obtuvo una concentración de Cu(II) de 4.73% atómico en algodón y 4.47% para el PET/algodón, de acuerdo a la cuantificación realizada en superficie por espectroscopia fotoelectrónica de rayos X (XPS), así como una concentración promedio de Zr(IV) de 10,04% para el algodón y 12,06% para el PET/algodón (por espectroscopía XPS). Estos materiales, fueron caracterizados mediante difracción de rayos X (DRXP), espectroscopía de infrarrojo por reflectancia total atenuada (FTIR-ATR), microscopia electrónica de barrido (SEM), espectroscopía fotoelectrónica de Rayos X (XPS), espectroscopía de electrones dispersados (EDS) y coulombimetría. Finalmente, se llevaron a cabo ensayos de inhibición bacteriana de los MOFs anclados a las fibras textiles, usando sepas de referencia de S. aureus (G+) y E. coli (G-), utilizando las metodologías de halos de inhibición y de estándares de McFarland, encontrándose un considerable efecto inhibidor principalmente en S. aureus posiblemente debida a la acción de los compositos obtenidos. (Texto tomado de la fuente).In this work, the synthesis and characterization of two Metalorganic Networks (MOFs): MOF-199 (HKUST-1) and MOF UiO-66-NH2, was carried out. Likewise, the functionalization and grafting of textile substrates of polyester (PET), cellulose (cotton), and PET/cotton 50:50 were carried out through ATRP-ARGET-SI polymerization reactions and selective carboxylation with the TEMPO/NaClO/NaBr/NaClO2 system, to increase the concentration of carboxylate groups (-COO-) and turn them into suitable surfaces for the subsequent chemical anchoring by coordination bonds of the previously obtained MOFs. Average concentrations of carboxylate groups of 0,019 mmol/g for cotton and 0,020 mmol/g for PET/cotton were obtained, with respect to a cotton blank. Similarly, the anchoring of MOF-199 and MOF UiO-66-NH2 produced ex-situ was carried out. An average concentration of Cu(II) of 4,73% was obtained for cotton and 4,47% for PET/cotton, as well as an average concentration of Zr4+ of 10,04% for cotton and 12,06% for PET/cotton. These materials, rarely obtained from solid-state MOFs, were characterized by X-Ray Diffraction (XRD), Furier-transformed Infrared Spectroscopy by Attenuated Total Reflectance (FTIR-ATR), Scanning Electron Microscopy (SEM), X-ray Photoelectron Spectroscopy (XPS), Scattered Electron Spectroscopy (EDS), and coulometry. Finally, bacterial inhibition assays of the MOFs anchored to the substrates were carried out using reference strains of S. aureus (G+) and E. coli (G-), using the methodologies of inhibition zones and reduction of the units. Colony-forming (CFU), finding a considerable antibacterial activity, possibly accomplished by the action of the obtained materials.Incluye anexosMaestríaMagíster en Ciencias - QuímicaQuímica de compuestos de coordinación y metalorgánicaQuímica de polímerosxviii, 152 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ciencias - Maestría en Ciencias - QuímicaDepartamento de QuímicaFacultad de CienciasBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materialesAnti-Bacterial AgentsAntibacterianosTextile chemistryChemistry, organicQuímica textilQuímica orgánicaRed metalorgánicaInhibición bacterianaAnclaje químicoEstado sólidoBacterial inhibitionReticular chemistryMetalorganic frameworkSíntesis y desarrollo de un anclaje químico estable de MOF-199 y MOF UiO-66-NH2 obtenidos ex situ sobre poliéster y celulosa, con potencial aplicación como textiles antibacterialesSynthesis and development of a stable chemical anchor of MOF-199 and MOF UiO-66-NH2 obtained ex situ on polyester and cellulose, with potential application as antibacterial textilesTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMGupta, A.; Mumtaz, S.; Li, C.-H.; Hussain, I.; Rotello, V. M. Combatting Antibiotic-Resistant Bacteria Using Nanomaterials. Chem. Soc. Rev. 2019, 48, 415–427. https://doi.org/10.1039/C7CS00748E.Wyszogrodzka, G.; Marszałek, B.; Gil, B.; Dorożyński, P. Metal-Organic Frameworks: Mechanisms of Antibacterial Action and Potential Applications. Drug Discov. Today 2016, 21 (6), 1009–1018. https://doi.org/10.1016/j.drudis.2016.04.009.Aguado, S.; Quirós, J.; Canivet, J.; Farrusseng, D.; Boltes, K. Antimicrobial Activity of Cobalt Imidazolate Metal-Organic Frameworks. Chemosphere 2014, 113, 188–192. https://doi.org/10.1016/j.chemosphere.2014.05.029.Hinestroza, J. P.; Ochoa-puentes, C.; Sierra, C. A.; Soto, C. Y. Antibacterial Activity Against Escherichia Coli of Cu-BTC (MOF-199) Metal-Organic Framework Immobilized onto Cellulosic Fibers. J. Appl. Polym. Sci. 2014, 40815, 1–5. https://doi.org/https://doi.org/10.1002/app.40815.Abbasi, A. R.; Akhbari, K.; Morsali, A. 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Convocatoria 812 de 2018 de Jóvenes InvestigadoresMinisterio de Ciencia, Tecnología e Innovación (MinCiencias)EstudiantesInvestigadoresMaestrosORIGINAL1016049086.2021.pdf1016049086.2021.pdfTesis de Maestría en Ciencias - Químicaapplication/pdf5147792https://repositorio.unal.edu.co/bitstream/unal/81572/3/1016049086.2021.pdf35539d315d8c77872fe805cf9f63ababMD53LICENSElicense.txtlicense.txttext/plain; charset=utf-84074https://repositorio.unal.edu.co/bitstream/unal/81572/4/license.txt8153f7789df02f0a4c9e079953658ab2MD54THUMBNAIL1016049086.2021.pdf.jpg1016049086.2021.pdf.jpgGenerated Thumbnailimage/jpeg5296https://repositorio.unal.edu.co/bitstream/unal/81572/5/1016049086.2021.pdf.jpgd59ce0f982c81ebfe37a2cf46cb8cf99MD55unal/81572oai:repositorio.unal.edu.co:unal/815722023-08-04 23:04:42.286Repositorio Institucional Universidad Nacional de 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