Colombian fusel oil

By-products valorization in bio-fuels industry is an important issue for making the global process more efficient, more profitable and closer to the concept of biorefinery. Fusel oil is a by-product of bioethanol production that can be considered as an inexpensive and renewable raw material for manu...

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Autores:
Montoya, Natalia
Durán, Jairo
Córdoba, Fernando
Gil, Iván Darío
Trujillo, Carlos Alexander
Rodríguez, Gerardo
Tipo de recurso:
Article of journal
Fecha de publicación:
2016
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/67613
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/67613
http://bdigital.unal.edu.co/68642/
Palabra clave:
62 Ingeniería y operaciones afines / Engineering
Fuel ethanol
higher alcohols
GC-MS analysis
solid-phase microextraction
TBP
Etanol-combustible
alcoholes pesados
análisis GC-MS
micro-extracción en fase sólida
TBP
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional
id UNACIONAL2_5ead77899453cb7b7b3b63d2b9cc7f6b
oai_identifier_str oai:repositorio.unal.edu.co:unal/67613
network_acronym_str UNACIONAL2
network_name_str Universidad Nacional de Colombia
repository_id_str
dc.title.spa.fl_str_mv Colombian fusel oil
title Colombian fusel oil
spellingShingle Colombian fusel oil
62 Ingeniería y operaciones afines / Engineering
Fuel ethanol
higher alcohols
GC-MS analysis
solid-phase microextraction
TBP
Etanol-combustible
alcoholes pesados
análisis GC-MS
micro-extracción en fase sólida
TBP
title_short Colombian fusel oil
title_full Colombian fusel oil
title_fullStr Colombian fusel oil
title_full_unstemmed Colombian fusel oil
title_sort Colombian fusel oil
dc.creator.fl_str_mv Montoya, Natalia
Durán, Jairo
Córdoba, Fernando
Gil, Iván Darío
Trujillo, Carlos Alexander
Rodríguez, Gerardo
dc.contributor.author.spa.fl_str_mv Montoya, Natalia
Durán, Jairo
Córdoba, Fernando
Gil, Iván Darío
Trujillo, Carlos Alexander
Rodríguez, Gerardo
dc.subject.ddc.spa.fl_str_mv 62 Ingeniería y operaciones afines / Engineering
topic 62 Ingeniería y operaciones afines / Engineering
Fuel ethanol
higher alcohols
GC-MS analysis
solid-phase microextraction
TBP
Etanol-combustible
alcoholes pesados
análisis GC-MS
micro-extracción en fase sólida
TBP
dc.subject.proposal.spa.fl_str_mv Fuel ethanol
higher alcohols
GC-MS analysis
solid-phase microextraction
TBP
Etanol-combustible
alcoholes pesados
análisis GC-MS
micro-extracción en fase sólida
TBP
description By-products valorization in bio-fuels industry is an important issue for making the global process more efficient, more profitable and closer to the concept of biorefinery. Fusel oil is a by-product of bioethanol production that can be considered as an inexpensive and renewable raw material for manufacturing value-added products. In this work, results in terms of composition and physicochemical properties of six samples of fusel oil from industrial alcohol facilities are presented. Composition of the main components was established by gas chromatography. Complementary techniques, such as headspace solid-phase microextraction and gas chromatography–mass spectrometry (GC-MS), were used for detection of minor components. Fifty-five compounds were identified. Physicochemical properties such as density, acid value, moisture content and true boiling point curves were determined. Results are useful in the conceptual design of separation strategies for recovering higher alcohols, as well as to consider new options of valorization alternatives for fusel oil.
publishDate 2016
dc.date.issued.spa.fl_str_mv 2016-05-01
dc.date.accessioned.spa.fl_str_mv 2019-07-03T04:40:43Z
dc.date.available.spa.fl_str_mv 2019-07-03T04:40:43Z
dc.type.spa.fl_str_mv Artículo de revista
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dc.identifier.issn.spa.fl_str_mv ISSN: 2248-8723
dc.identifier.uri.none.fl_str_mv https://repositorio.unal.edu.co/handle/unal/67613
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identifier_str_mv ISSN: 2248-8723
url https://repositorio.unal.edu.co/handle/unal/67613
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dc.language.iso.spa.fl_str_mv spa
language spa
dc.relation.spa.fl_str_mv https://revistas.unal.edu.co/index.php/ingeinv/article/view/52369
dc.relation.ispartof.spa.fl_str_mv Universidad Nacional de Colombia Revistas electrónicas UN Ingeniería e Investigación
Ingeniería e Investigación
dc.relation.references.spa.fl_str_mv Montoya, Natalia and Durán, Jairo and Córdoba, Fernando and Gil, Iván Darío and Trujillo, Carlos Alexander and Rodríguez, Gerardo (2016) Colombian fusel oil. Ingeniería e Investigación, 36 (2). pp. 21-27. ISSN 2248-8723
dc.rights.spa.fl_str_mv Derechos reservados - Universidad Nacional de Colombia
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dc.rights.license.spa.fl_str_mv Atribución-NoComercial 4.0 Internacional
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dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv Atribución-NoComercial 4.0 Internacional
Derechos reservados - Universidad Nacional de Colombia
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eu_rights_str_mv openAccess
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Universidad Nacional de Colombia - Sede Bogotá - Facultad de Ingeniería
institution Universidad Nacional de Colombia
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spelling Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Montoya, Natalia997d43cb-3fa2-48bb-80aa-b8d8b8898a25300Durán, Jairoe1541366-894a-4241-914c-9d135e0b3e87300Córdoba, Fernando9bdca514-8c17-4fb3-a51d-fe9c83ef76c3300Gil, Iván Daríof1186416-7d24-46b3-9d9f-dc11fbc185a4300Trujillo, Carlos Alexander20134005-7579-4435-a511-baa5f3ef5b40300Rodríguez, Gerardo6aa8d824-beda-44ee-8171-10adc8bd6c8b3002019-07-03T04:40:43Z2019-07-03T04:40:43Z2016-05-01ISSN: 2248-8723https://repositorio.unal.edu.co/handle/unal/67613http://bdigital.unal.edu.co/68642/By-products valorization in bio-fuels industry is an important issue for making the global process more efficient, more profitable and closer to the concept of biorefinery. Fusel oil is a by-product of bioethanol production that can be considered as an inexpensive and renewable raw material for manufacturing value-added products. In this work, results in terms of composition and physicochemical properties of six samples of fusel oil from industrial alcohol facilities are presented. Composition of the main components was established by gas chromatography. Complementary techniques, such as headspace solid-phase microextraction and gas chromatography–mass spectrometry (GC-MS), were used for detection of minor components. Fifty-five compounds were identified. Physicochemical properties such as density, acid value, moisture content and true boiling point curves were determined. Results are useful in the conceptual design of separation strategies for recovering higher alcohols, as well as to consider new options of valorization alternatives for fusel oil.Los subproductos para valorización en la industria de los biocombustibles es un tema importante para alcanzar un proceso global más eficiente, más rentable y más cerca del concepto de biorrefinería. El aceite de fusel es un subproducto de la producción de bioetanol que se puede considerar como una materia prima barata y renovable para la fabricación de productos de valor agregado. En este trabajo se presentan los resultados en términos de composición y de las propiedades físico-químicas de seis muestras de aceite de fusel de las instalaciones industriales de alcohol. La composición de los componentes principales se estableció mediante cromatografía de gases. Técnicas complementarias, como espacio de cabeza, microextracción en fase sólida, y cromatografía de gasesespectrometríade masas (GC-MS), fueron utilizadas para la detección de componentes menores. Se identificaron cincuenta y cincocompuestos. Se determinaron las propiedades físico-químicas, como la densidad, el índice de acidez, el contenido de humedad y las curvas de puntos verdaderos de ebullición. Los resultados son útiles en el diseño conceptual de las estrategias de separación para la recuperación de alcoholes superiores, así como para comprobar las opciones de alternativas de valorización del aceite de fuselapplication/pdfspaUniversidad Nacional de Colombia - Sede Bogotá - Facultad de Ingenieríahttps://revistas.unal.edu.co/index.php/ingeinv/article/view/52369Universidad Nacional de Colombia Revistas electrónicas UN Ingeniería e InvestigaciónIngeniería e InvestigaciónMontoya, Natalia and Durán, Jairo and Córdoba, Fernando and Gil, Iván Darío and Trujillo, Carlos Alexander and Rodríguez, Gerardo (2016) Colombian fusel oil. Ingeniería e Investigación, 36 (2). pp. 21-27. ISSN 2248-872362 Ingeniería y operaciones afines / EngineeringFuel ethanolhigher alcoholsGC-MS analysissolid-phase microextractionTBPEtanol-combustiblealcoholes pesadosanálisis GC-MSmicro-extracción en fase sólidaTBPColombian fusel oilArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTORIGINAL52369-303220-2-PB.pdfapplication/pdf224206https://repositorio.unal.edu.co/bitstream/unal/67613/1/52369-303220-2-PB.pdfd8825eac4ef2568e733df3b253081ac3MD51THUMBNAIL52369-303220-2-PB.pdf.jpg52369-303220-2-PB.pdf.jpgGenerated Thumbnailimage/jpeg7903https://repositorio.unal.edu.co/bitstream/unal/67613/2/52369-303220-2-PB.pdf.jpg8411c22b84bc6a9b45f81fd224b20a8bMD52unal/67613oai:repositorio.unal.edu.co:unal/676132024-05-22 23:33:57.214Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co