Catálisis de la hidrogenación del ácido levulínico a γ-valerolactona con nanopartículas de oro soportadas en sílice mesoporosa

fotografías en color, gráficas, ilustraciones, tablas

Autores:
Rodriguez Gonzalez, Carolina
Tipo de recurso:
Fecha de publicación:
2022
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/81803
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/81803
https://repositorio.unal.edu.co/
Palabra clave:
546 - Química inorgánica
540 - Química y ciencias afines::547 - Química orgánica
542 - Técnicas, procedimientos, aparatos, equipos, materiales
661 - Tecnología de químicos industriales
668 - Tecnología de otros productos orgánicos
Valorización de biomasa
ácido levulínico
hidrogenación
γ-valerolactona
nanopartículas de oro
sílice mesoporosa.
Biomass valorization
levulinic acid
hydrogenation
γ-valerolactone
gold nanoparticles
mesoporous silica.
Rights
openAccess
License
Atribución-NoComercial-SinDerivadas 4.0 Internacional
id UNACIONAL2_5e320ea5c4eafbe3b365a3308d4198bf
oai_identifier_str oai:repositorio.unal.edu.co:unal/81803
network_acronym_str UNACIONAL2
network_name_str Universidad Nacional de Colombia
repository_id_str
dc.title.spa.fl_str_mv Catálisis de la hidrogenación del ácido levulínico a γ-valerolactona con nanopartículas de oro soportadas en sílice mesoporosa
dc.title.translated.eng.fl_str_mv Gold nanoparticles supported on mesoporous silica as catalyst for the production of γ-valerolactone by levulinic acid hydrogenation catalysts
title Catálisis de la hidrogenación del ácido levulínico a γ-valerolactona con nanopartículas de oro soportadas en sílice mesoporosa
spellingShingle Catálisis de la hidrogenación del ácido levulínico a γ-valerolactona con nanopartículas de oro soportadas en sílice mesoporosa
546 - Química inorgánica
540 - Química y ciencias afines::547 - Química orgánica
542 - Técnicas, procedimientos, aparatos, equipos, materiales
661 - Tecnología de químicos industriales
668 - Tecnología de otros productos orgánicos
Valorización de biomasa
ácido levulínico
hidrogenación
γ-valerolactona
nanopartículas de oro
sílice mesoporosa.
Biomass valorization
levulinic acid
hydrogenation
γ-valerolactone
gold nanoparticles
mesoporous silica.
title_short Catálisis de la hidrogenación del ácido levulínico a γ-valerolactona con nanopartículas de oro soportadas en sílice mesoporosa
title_full Catálisis de la hidrogenación del ácido levulínico a γ-valerolactona con nanopartículas de oro soportadas en sílice mesoporosa
title_fullStr Catálisis de la hidrogenación del ácido levulínico a γ-valerolactona con nanopartículas de oro soportadas en sílice mesoporosa
title_full_unstemmed Catálisis de la hidrogenación del ácido levulínico a γ-valerolactona con nanopartículas de oro soportadas en sílice mesoporosa
title_sort Catálisis de la hidrogenación del ácido levulínico a γ-valerolactona con nanopartículas de oro soportadas en sílice mesoporosa
dc.creator.fl_str_mv Rodriguez Gonzalez, Carolina
dc.contributor.advisor.none.fl_str_mv Guerrero Fajardo, Carlos Alberto
dc.contributor.author.none.fl_str_mv Rodriguez Gonzalez, Carolina
dc.contributor.researchgroup.spa.fl_str_mv Aprovechamiento Energético de Recursos Naturales
dc.subject.ddc.spa.fl_str_mv 546 - Química inorgánica
540 - Química y ciencias afines::547 - Química orgánica
542 - Técnicas, procedimientos, aparatos, equipos, materiales
661 - Tecnología de químicos industriales
668 - Tecnología de otros productos orgánicos
topic 546 - Química inorgánica
540 - Química y ciencias afines::547 - Química orgánica
542 - Técnicas, procedimientos, aparatos, equipos, materiales
661 - Tecnología de químicos industriales
668 - Tecnología de otros productos orgánicos
Valorización de biomasa
ácido levulínico
hidrogenación
γ-valerolactona
nanopartículas de oro
sílice mesoporosa.
Biomass valorization
levulinic acid
hydrogenation
γ-valerolactone
gold nanoparticles
mesoporous silica.
dc.subject.proposal.spa.fl_str_mv Valorización de biomasa
ácido levulínico
hidrogenación
γ-valerolactona
nanopartículas de oro
sílice mesoporosa.
dc.subject.proposal.eng.fl_str_mv Biomass valorization
levulinic acid
hydrogenation
γ-valerolactone
gold nanoparticles
mesoporous silica.
description fotografías en color, gráficas, ilustraciones, tablas
publishDate 2022
dc.date.accessioned.none.fl_str_mv 2022-08-08T17:27:29Z
dc.date.available.none.fl_str_mv 2022-08-08T17:27:29Z
dc.date.issued.none.fl_str_mv 2022
dc.type.spa.fl_str_mv Trabajo de grado - Maestría
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/masterThesis
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/acceptedVersion
dc.type.content.spa.fl_str_mv Text
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/TM
status_str acceptedVersion
dc.identifier.uri.none.fl_str_mv https://repositorio.unal.edu.co/handle/unal/81803
dc.identifier.instname.spa.fl_str_mv Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv https://repositorio.unal.edu.co/
url https://repositorio.unal.edu.co/handle/unal/81803
https://repositorio.unal.edu.co/
identifier_str_mv Universidad Nacional de Colombia
Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv spa
language spa
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dc.format.extent.spa.fl_str_mv xix, 109 páginas
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dc.publisher.spa.fl_str_mv Universidad Nacional de Colombia
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dc.publisher.branch.spa.fl_str_mv Universidad Nacional de Colombia - Sede Bogotá
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spelling Atribución-NoComercial-SinDerivadas 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Guerrero Fajardo, Carlos Alberto8158c2ed082a222d8fcff4117ee21159Rodriguez Gonzalez, Carolina53f82c87d3dba748e9c8b567f73b5994Aprovechamiento Energético de Recursos Naturales2022-08-08T17:27:29Z2022-08-08T17:27:29Z2022https://repositorio.unal.edu.co/handle/unal/81803Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/fotografías en color, gráficas, ilustraciones, tablasActualmente, obtener productos de interés industrial a partir de fuentes renovables ha adquirido relevancia, debido al impacto ambiental que generan los métodos de obtención tradicional y al inminente agotamiento de las fuentes fósiles. Esto ha dado paso al surgimiento de diversos procesos de valorización, con los cuales se obtienen productos de alto valor agregado a partir de biomasa. Sin embargo, una de las principales limitantes en dicha valorización es la obtención de productos con aplicación directa en la industria, debido a que la transformación de biomasa por hidrólisis, procesos termoquímicos, fermentación, entre otros métodos, da como resultado la obtención de compuestos conocidos como moléculas plataforma, que si bien son un paso adelante en el proceso de valorización, requieren un proceso de transformación adicional que permita la obtención de productos con aplicación directa. Tal es el caso del ácido levulínico, como molécula plataforma obtenida a partir de biomasa lignocelulósica, que puede valorizarse hacia γ-valerolactona, un compuesto de interés para la industria de alimentos y de biocombustibles. Por medio de esta tesis de maestría se evaluó la obtención de γ-valerolactona a partir de ácido levulínico, por medio de una reacción de hidrogenación utilizando un catalizador heterogéneo de nanopartículas de oro soportadas en sílice mesoporosa. Para esto se realizó la síntesis de la sílice mesoporosa con el método sol-gel, luego se depositaron las nanopartículas de oro (1-5% Au) empleando el método deposición-precipitación, y los catalizadores obtenidos se caracterizaron por medio de FTIR, XRD y espectroscopia Raman. Con este método, se obtuvieron efectivamente catalizadores con nanopartículas de oro (8-21 nm) cristalinas, soportadas en sílice mesoporosa, posteriormente empleados para la hidrogenación del ácido levulínico. Esta reacción se desarrolló utilizando un diseño experimental factorial multinivel en donde se evaluaron tres factores: % Au en el catalizador (0-5%), temperatura (93-177 °C) y tiempo de reacción (1-6 h), con una alimentación constante de H2, y dos variables de respuesta: conversión del ácido levulínico y selectividad de la reacción hacia γ-valerolactona. Los productos de la reacción se cuantificaron por HPLC. Como resultado se obtuvo una conversión total (100%) del ácido levulínico en temperaturas entre 135 °C y 177 °C y tiempos entre 2 h y 5 h, y una selectividad hacia γ-valerolactona del 99.49% empleando como condiciones de reacción: catalizador 5% Au, 135 °C y 3.5 h. (Texto tomado de la fuente)Currently, obtaining products of interest for industry from renewable sources has gained relevance due to the environmental impact generated by traditional production methods and the imminent depletion of fossil fuels. This has given way to the emergence of various valorization processes, with which high value-added products are obtained from biomass. However, one of the main limitations of such valorization is obtaining products with direct application in industry, because the transformation of biomass by hydrolysis, thermochemical processes, fermentation, among other methods, results in obtaining compounds known as platform molecules, which, although they are a step forward in the valorization process, require an additional transformation process that allows obtaining products with direct application. Such is the case of levulinic acid, a platform molecule obtained from lignocellulosic biomass, which can be valorized to γ-valerolactone, a compound of interest in the food and biofuel industry. By means of this master thesis, the obtaining of γ-valerolactone from levulinic acid was evaluated by a hydrogenation reaction using a heterogeneous catalyst of gold nanoparticles supported on mesoporous silica. For catalyst, the synthesis of the mesoporous silica was carried out with sol-gel method, then gold nanoparticles (1-5% Au) were deposited using deposition-precipitation method, and the catalysts obtained were dcharacterized by FTIR, XRD and Raman spectroscopy. With this method, catalysts with crystalline gold nanoparticles (8-21 nm), supported on mesoporous silica, were effectively obtained and subsequently used for the hydrogenation of levulinic acid. Hydrogenation reaction was developed using a multilevel factorial experimental design where three factors were evaluated: % Au in the catalyst (0-5%), temperature (93-177 °C) and reaction time (1-6 h), with a constant H2 feed, and two response variables: levulinic acid conversion and selectivity of the reaction to γ-valerolactone. Reaction products were quantified by HPLC. As result, a total conversion (100%) of levulinic acid was obtained at temperatures between 135 °C and 177 °C and times between 2 h and 5 h, and selectivity to γ-valerolactone of 99.49% using as reaction conditions: 5% Au catalyst, 135 °C and 3.5 h. (Text taken of the source)MaestríaProcesos catalíticos y petroquímicosxix, 109 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ingeniería - Maestría en Ingeniería - Ingeniería QuímicaDepartamento de Ingeniería Química y AmbientalFacultad de IngenieríaBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá546 - Química inorgánica540 - Química y ciencias afines::547 - Química orgánica542 - Técnicas, procedimientos, aparatos, equipos, materiales661 - Tecnología de químicos industriales668 - Tecnología de otros productos orgánicosValorización de biomasaácido levulínicohidrogenaciónγ-valerolactonananopartículas de orosílice mesoporosa.Biomass valorizationlevulinic acidhydrogenationγ-valerolactonegold nanoparticlesmesoporous silica.Catálisis de la hidrogenación del ácido levulínico a γ-valerolactona con nanopartículas de oro soportadas en sílice mesoporosaGold nanoparticles supported on mesoporous silica as catalyst for the production of γ-valerolactone by levulinic acid hydrogenation catalystsTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMS. 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Ed., vol. 54, no. 45, pp. 13187–13197, Nov. 2015.InvestigadoresORIGINAL1015450117.2022.pdf1015450117.2022.pdfTesis de Maestría en Ingeniería Químicaapplication/pdf2455513https://repositorio.unal.edu.co/bitstream/unal/81803/3/1015450117.2022.pdf8921b42260b10549b6687e8531cfc4bfMD53LICENSElicense.txtlicense.txttext/plain; charset=utf-84074https://repositorio.unal.edu.co/bitstream/unal/81803/4/license.txt8153f7789df02f0a4c9e079953658ab2MD54THUMBNAIL1015450117.2022.pdf.jpg1015450117.2022.pdf.jpgGenerated Thumbnailimage/jpeg5805https://repositorio.unal.edu.co/bitstream/unal/81803/5/1015450117.2022.pdf.jpg5c9b3a2681ec629854b86f5df2397deeMD55unal/81803oai:repositorio.unal.edu.co:unal/818032023-08-06 23:03:51.055Repositorio Institucional Universidad Nacional de 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EVESURBIFBPUiBMQSBTRUNSRVRBUsONQSBHRU5FUkFMLiAqTEEgVEVTSVMgQSBQVUJMSUNBUiBERUJFIFNFUiBMQSBWRVJTScOTTiBGSU5BTCBBUFJPQkFEQS4gCgpBbCBoYWNlciBjbGljIGVuIGVsIHNpZ3VpZW50ZSBib3TDs24sIHVzdGVkIGluZGljYSBxdWUgZXN0w6EgZGUgYWN1ZXJkbyBjb24gZXN0b3MgdMOpcm1pbm9zLiBTaSB0aWVuZSBhbGd1bmEgZHVkYSBzb2JyZSBsYSBsaWNlbmNpYSwgcG9yIGZhdm9yLCBjb250YWN0ZSBjb24gZWwgYWRtaW5pc3RyYWRvciBkZWwgc2lzdGVtYS4KClVOSVZFUlNJREFEIE5BQ0lPTkFMIERFIENPTE9NQklBIC0gw5psdGltYSBtb2RpZmljYWNpw7NuIDE5LzEwLzIwMjEK

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