Degradación de colorantes presentes en aguas residuales usando un mineral natural basado en óxidos de hierro como catalizador
ilustraciones
- Autores:
-
Contreras Patiño, Julián Esteban
- Tipo de recurso:
- Fecha de publicación:
- 2022
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/83915
- Palabra clave:
- 540 - Química y ciencias afines::543 - Química analítica
Coloring matter
Catalysts
water pollutants
Colorantes
Catalizadores
Contaminantes del agua
Proceso Fenton
Procesos Avanzados de Oxidación (AOP´s)
Cristal violeta
Fucsina ácida
Material de hierro
Advanced Oxidation Processes (AOP)
Crystal violet
Fenton process
Acid fuchsine
Iron ore
- Rights
- openAccess
- License
- Atribución-NoComercial-SinDerivadas 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Degradación de colorantes presentes en aguas residuales usando un mineral natural basado en óxidos de hierro como catalizador |
| dc.title.translated.none.fl_str_mv |
Degradation of dyes present in wastewater using a natural material based on iron oxides as catalyst |
| title |
Degradación de colorantes presentes en aguas residuales usando un mineral natural basado en óxidos de hierro como catalizador |
| spellingShingle |
Degradación de colorantes presentes en aguas residuales usando un mineral natural basado en óxidos de hierro como catalizador 540 - Química y ciencias afines::543 - Química analítica Coloring matter Catalysts water pollutants Colorantes Catalizadores Contaminantes del agua Proceso Fenton Procesos Avanzados de Oxidación (AOP´s) Cristal violeta Fucsina ácida Material de hierro Advanced Oxidation Processes (AOP) Crystal violet Fenton process Acid fuchsine Iron ore |
| title_short |
Degradación de colorantes presentes en aguas residuales usando un mineral natural basado en óxidos de hierro como catalizador |
| title_full |
Degradación de colorantes presentes en aguas residuales usando un mineral natural basado en óxidos de hierro como catalizador |
| title_fullStr |
Degradación de colorantes presentes en aguas residuales usando un mineral natural basado en óxidos de hierro como catalizador |
| title_full_unstemmed |
Degradación de colorantes presentes en aguas residuales usando un mineral natural basado en óxidos de hierro como catalizador |
| title_sort |
Degradación de colorantes presentes en aguas residuales usando un mineral natural basado en óxidos de hierro como catalizador |
| dc.creator.fl_str_mv |
Contreras Patiño, Julián Esteban |
| dc.contributor.advisor.spa.fl_str_mv |
Hincapie Triviño, Gina Marcela Pérez Flórez, Alejandro |
| dc.contributor.author.spa.fl_str_mv |
Contreras Patiño, Julián Esteban |
| dc.contributor.researchgroup.spa.fl_str_mv |
Estado Sólido y Catálisis Ambiental |
| dc.subject.ddc.spa.fl_str_mv |
540 - Química y ciencias afines::543 - Química analítica |
| topic |
540 - Química y ciencias afines::543 - Química analítica Coloring matter Catalysts water pollutants Colorantes Catalizadores Contaminantes del agua Proceso Fenton Procesos Avanzados de Oxidación (AOP´s) Cristal violeta Fucsina ácida Material de hierro Advanced Oxidation Processes (AOP) Crystal violet Fenton process Acid fuchsine Iron ore |
| dc.subject.lemb.eng.fl_str_mv |
Coloring matter Catalysts water pollutants |
| dc.subject.lemb.spa.fl_str_mv |
Colorantes Catalizadores Contaminantes del agua |
| dc.subject.proposal.spa.fl_str_mv |
Proceso Fenton Procesos Avanzados de Oxidación (AOP´s) Cristal violeta Fucsina ácida Material de hierro |
| dc.subject.proposal.eng.fl_str_mv |
Advanced Oxidation Processes (AOP) Crystal violet Fenton process Acid fuchsine Iron ore |
| description |
ilustraciones |
| publishDate |
2022 |
| dc.date.issued.none.fl_str_mv |
2022 |
| dc.date.accessioned.none.fl_str_mv |
2023-05-30T18:56:26Z |
| dc.date.available.none.fl_str_mv |
2023-05-30T18:56:26Z |
| dc.type.spa.fl_str_mv |
Trabajo de grado - Maestría |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/masterThesis |
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info:eu-repo/semantics/acceptedVersion |
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Text |
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http://purl.org/redcol/resource_type/TM |
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acceptedVersion |
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https://repositorio.unal.edu.co/handle/unal/83915 |
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Universidad Nacional de Colombia |
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Repositorio Institucional Universidad Nacional de Colombia |
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https://repositorio.unal.edu.co/ |
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https://repositorio.unal.edu.co/handle/unal/83915 https://repositorio.unal.edu.co/ |
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Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia |
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spa |
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spa |
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V., Parthiban, R., Mohammad, F., Oh, W. C., & Sagadevan, S. (2020). Evaluation of the photocatalytic efficiency of cobalt oxide nanoparticles towards the degradation of crystal violet and methylene violet dyes. Optik, 207(December 2019), 164428. https://doi.org/10.1016/j.ijleo.2020.164428 Segura Triana, L. E. (2007). Estudio de Antecedentes sobre la contaminación del recurso hidrico en Colombia. In Escuela Superior de Administración Pública (ESAP). Singh, K. P., Gupta, S., Singh, A. K., & Sinha, S. (2011). Optimizing adsorption of crystal violet dye from water by magnetic nanocomposite using response surface modeling approach. Journal of Hazardous Materials, 186(2–3), 1462–1473. https://doi.org/10.1016/j.jhazmat.2010.12.032 Tackling global water pollution | UNEP - UN Environment Programme. (n.d.). Retrieved September 16, 2020, from https://www.unenvironment.org/explore-topics/water/what-we-do/tackling-global-water-pollution Tamburini, D., Shimada, C. M., & McCarthy, B. (2021). The molecular characterization of early synthetic dyes in E. Knecht et al’s textile sample book “A Manual of Dyeing” (1893) by high performance liquid chromatography - Diode array detector - Mass spectrometry (HPLC-DAD-MS). Dyes and Pigments, 190(March), 109286. https://doi.org/10.1016/j.dyepig.2021.109286 Tan, X. fei, Liu, Y. guo, Gu, Y. ling, Liu, S. bo, Zeng, G. ming, Cai, X., Hu, X. jiang, Wang, H., Liu, S. mian, & Jiang, L. hua. (2016). Biochar pyrolyzed from MgAl-layered double hydroxides pre-coated ramie biomass (Boehmeria nivea (L.) Gaud.): Characterization and application for crystal violet removal. Journal of Environmental Management, 184, 85–93. https://doi.org/10.1016/j.jenvman.2016.08.070 Testolin, R. C., Mater, L., Sanches-Simões, E., Dal Conti-Lampert, A., Corrêa, A. X. R., Groth, M. L., Oliveira-Carneiro, M., & Radetski, C. M. (2020). Comparison of the mineralization and biodegradation efficiency of the Fenton reaction and Ozone in the treatment of crude petroleum-contaminated water. Journal of Environmental Chemical Engineering, 8(5), 104265. https://doi.org/10.1016/j.jece.2020.104265 Thiam, A., Salazar, R., Brillas, E., & Sirés, I. (2020). In-situ dosage of Fe2+ catalyst using natural pyrite for thiamphenicol mineralization by photoelectro-Fenton process. Journal of Environmental Management, 270(May). https://doi.org/10.1016/j.jenvman.2020.110835 Thomas, N., Dionysiou, D. D., & Pillai, S. C. (2021). Heterogeneous Fenton catalysts: A review of recent advances. Journal of Hazardous Materials, 404(PB), 124082. https://doi.org/10.1016/j.jhazmat.2020.124082 UNESCO. (2019). Informe Mundial de las Naciones Unidas sobre el Desarrollo de los Recursos Hídricos 2019. No dejar a nadie atrás. In Organización de las Naciones Unidas para la Educación, la Ciencia y la Cultura (p. 215). http://www.unwater.org/publications/world-water-development-report-2019/ Vega Mora, L. (2015). PROGRAMA INTEGRAL DE GESTIÓN AMBIENTAL SECTORIAL-PGAS SUBSECTOR TEXTIL. Villegas- Guzman, P., Giannakis, S., Rtimi, S., Grandjean, D., Bensimon, M., de Alencastro, L. F., Torres-Palma, R., & Pulgarin, C. (2017). A green solar photo-Fenton process for the elimination of bacteria and micropollutants in municipal wastewater treatment using mineral iron and natural organic acids. In Applied Catalysis B: Environmental (Vol. 219, pp. 538–549). https://doi.org/10.1016/j.apcatb.2017.07.066 Wahi, N., Joseph, C., Tawie, R., & Ikau, R. (2016). Critical Review on Construction Waste Control Practices: Legislative and Waste Management Perspective. Procedia - Social and Behavioral Sciences, 224(August 2015), 276–283. https://doi.org/10.1016/j.sbspro.2016.05.460 Wang, A., Wang, Y., Walter, E. D., Kukkadapu, R. 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Catalytic performance and reaction mechanisms of NO removal with NH3 at low and medium temperatures on Mn-W-Sb modified siderite catalysts. Journal of Environmental Sciences (China), 115(x), 126–139. https://doi.org/10.1016/j.jes.2021.06.029 Yin, J., Cai, J., Yin, C., Gao, L., & Zhou, J. (2016). Degradation performance of crystal violet over CuO@AC and CeO2-CuO@AC catalysts using microwave catalytic oxidation degradation method. Journal of Environmental Chemical Engineering, 4(1), 958–964. https://doi.org/10.1016/j.jece.2016.01.001 Yu, J., Zou, J., Xu, P., & He, Q. (2020). Three-dimensional photoelectrocatalytic degradation of the opaque dye acid fuchsin by Pr and Co co-doped TiO2 particle electrodes. In Journal of Cleaner Production (Vol. 251). https://doi.org/10.1016/j.jclepro.2019.119744 Zhang, M., Dong, H., Zhao, L., Wang, D. xi, & Meng, D. (2019). A review on Fenton process for organic wastewater treatment based on optimization perspective. Science of the Total Environment, 670, 110–121. https://doi.org/10.1016/j.scitotenv.2019.03.180 Zhang, Y., Zhang, Z., Yan, Q., & Wang, Q. (2016). Synthesis, characterization, and catalytic activity of alkali metal molybdate/α-MoO3 hybrids as highly efficient catalytic wet air oxidation catalysts. Applied Catalysis A: General, 511, 47–58. https://doi.org/10.1016/j.apcata.2015.11.035 Zhu, Y., Zhu, R., Xi, Y., Zhu, J., Zhu, G., & He, H. (2019). Strategies for enhancing the heterogeneous fenton catalytic reactivity: A review. Applied Catalysis B: Environmental, 255(January). https://doi.org/10.1016/j.apcatb.2019.05.041 Zollinger, H. (2004). Color Chemistry. Synthesis, Properties and Applications of Organic Dyes and Pigments. 3rd revised edition. By Heinrich Zollinger. Angewandte Chemie International Edition, 43(40), 5291–5292. https://doi.org/10.1002/anie.200385122 |
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Universidad Nacional de Colombia |
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Atribución-NoComercial-SinDerivadas 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Hincapie Triviño, Gina Marcela8e0d076fafc1331017e95475e2924210Pérez Flórez, Alejandro882e42a7e5df421016ee67b45b9affcdContreras Patiño, Julián Esteban248ca381869e504d3df8fcd5e5d725f4Estado Sólido y Catálisis Ambiental2023-05-30T18:56:26Z2023-05-30T18:56:26Z2022https://repositorio.unal.edu.co/handle/unal/83915Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustracionesUna de las principales problemáticas de la industria textil, es la alta cantidad de colorantes depositados en los cuerpos de agua, los cuales pueden tener efectos carcinogénicos, causan eutrofización y perturbaciones en la vida acuática. El proceso Fenton, es un proceso avanzado de oxidación que utiliza sales de hierro (Fe2+) solubles como catalizadores en presencia de H2O2 a pH ácido. En la presente investigación, con el objetivo de valorizar un material natural basado en óxidos de hierro proveniente de Acerías de Paz del Río en el departamento de Boyacá, Colombia, se llevó a reacción dicho material como catalizador en el proceso tipo Fenton frente a dos colorantes usados como modelo en reacciones de degradación: Cristal Violeta (CV) y Fucsina Ácida (FA). El material se caracterizó a través de diferentes técnicas, encontrándose una baja área superficial (27 m2/g), diferentes fases de hierro, dentro de las cuales predominan la siderita, goethita y hematita y una composición elemental mayoritaria para hierro y oxígeno. La evaluación de la actividad catalítica mostró que este material es capaz de reducir la cantidad de Cristal Violeta (CV) hasta el 90% y de Fucsina Ácida (FA) hasta un 80% en 8 h, partiendo en ambos casos de una concentración de contaminante de 50 mg/L, así mismo el valor de carbono orgánico total (TOC) se redujo hasta 34% en CV y 36% en FA, y en los ciclos de reúso el TOC se redujo al 46% y 51% luego del primer ciclo para el CV y la FA respectivamente. Se encontró que la cantidad de hierro lixiviado en la solución es de 6 mg/L, lo cual indica que el proceso catalítico es heterogéneo. (Texto tomado de la fuente).One of the main problems of the textile industry is the high number of dyes deposited in water bodies, which can have carcinogenic effects, cause eutrophication, and disturb aquatic life. The Fenton process is an advanced oxidation process that uses soluble iron salts (Fe2+) as catalysts in the presence of H2O2 at acid pH. In this investigation, with the aim of valorize a natural material based on iron oxides, coming from Acerías de Paz del Río in Boyacá, Colombia, this material was used as a catalyst in the Fenton process against two dyes used as a model in degradation reactions: Crystal Violet (CV) and Acid Fuchsin (FA). The material was characterized through different techniques, finding a low specific surface area (27 m2/g), different iron crystalline phases, predominantly siderite, goethite and hematite, and a majority elemental composition for iron and oxygen. The evaluation of the catalytic activity showed that this material can reduce the amount of Crystal Violet (CV) up to 90% and of Acid Fuchsin (AF) up to 80% in 8 h, starting in both cases from a contaminant concentration of 50 mg/L, likewise, the Total Organic Carbon (TOC) value was reduced up to 34% in CV and 36% in AF, and in the reuse cycles, the TOC was reduced to 46% and 51% after the first cycle for CV and AF respectively. The amount of iron leached was found to be 5 mg/L, indicating that the catalytic process is heterogeneous.Incluye anexosMaestríaMagíster en Ciencias - QuímicaCatálisis ambientalxix, 109 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ciencias - Maestría en Ciencias - QuímicaFacultad de CienciasBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá540 - Química y ciencias afines::543 - Química analíticaColoring matterCatalystswater pollutantsColorantesCatalizadoresContaminantes del aguaProceso FentonProcesos Avanzados de Oxidación (AOP´s)Cristal violetaFucsina ácidaMaterial de hierroAdvanced Oxidation Processes (AOP)Crystal violetFenton processAcid fuchsineIron oreDegradación de colorantes presentes en aguas residuales usando un mineral natural basado en óxidos de hierro como catalizadorDegradation of dyes present in wastewater using a natural material based on iron oxides as catalystTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMÁngel, M., José, H., Velasco, A., Rojas, F., Hugo, V., Alicia, M., Víctor, S., Mesoporos, E. 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Angewandte Chemie International Edition, 43(40), 5291–5292. https://doi.org/10.1002/anie.200385122EstudiantesInvestigadoresMaestrosLICENSElicense.txtlicense.txttext/plain; charset=utf-85879https://repositorio.unal.edu.co/bitstream/unal/83915/1/license.txteb34b1cf90b7e1103fc9dfd26be24b4aMD51ORIGINAL1026266515.2023.pdf1026266515.2023.pdfTesis de Maestría en Ciencias - Químicaapplication/pdf4087939https://repositorio.unal.edu.co/bitstream/unal/83915/2/1026266515.2023.pdf86f0e94ae608355e2eb808e61d25a7f2MD52THUMBNAIL1026266515.2023.pdf.jpg1026266515.2023.pdf.jpgGenerated Thumbnailimage/jpeg5083https://repositorio.unal.edu.co/bitstream/unal/83915/3/1026266515.2023.pdf.jpg80ea3b27c83e8ecb239e5d14889d1559MD53unal/83915oai:repositorio.unal.edu.co:unal/839152024-08-09 23:19:49.521Repositorio Institucional Universidad Nacional de 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