Evaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgas

Múltiples estudios presentan las microalgas como la fuente de biocombustibles más prometedora, debido a que, entre otras características, son 50 veces más eficientes en convertir la luz solar en biomasa y capturan entre 10 y 50 veces más CO2 que las plantas terrestres. Debido a que el contenido de a...

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Autores:: Pasos Panqueva, Johan Andrés

Tipo de recurso:

Fecha de publicación:: 2021

Institución:: Universidad Nacional de Colombia

Repositorio:: Universidad Nacional de Colombia

Idioma:: spa

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repository_id_str
dc.title.spa.fl_str_mv	Evaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgas
dc.title.translated.eng.fl_str_mv	Assessment of the wet peroxide oxidation process as an alternative for the treatment of the aqueous phase resulting from the hydrothermal liquefaction of microalgae
title	Evaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgas
spellingShingle	Evaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgas 620 - Ingeniería y operaciones afines::624 - Ingeniería civil 660 - Ingeniería química Microalga Licuefacción hidrotermal Tratamiento de aguas residuales Procesos avanzados de oxidación Recuperación de nutrientes Oxidación hidrotermal con peroxido Chlorella vulgaris Microalgae Hydrothernal liquefaction Wastewater treatment Wet peroxide oxidation Nutrient recovery Advanced oxidation process
title_short	Evaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgas
title_full	Evaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgas
title_fullStr	Evaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgas
title_full_unstemmed	Evaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgas
title_sort	Evaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgas
dc.creator.fl_str_mv	Pasos Panqueva, Johan Andrés
dc.contributor.advisor.none.fl_str_mv	Godoy Silva, Rubén Darío Rodríguez Varela, Luis Ignacio
dc.contributor.author.none.fl_str_mv	Pasos Panqueva, Johan Andrés
dc.subject.ddc.spa.fl_str_mv	620 - Ingeniería y operaciones afines::624 - Ingeniería civil 660 - Ingeniería química
topic	620 - Ingeniería y operaciones afines::624 - Ingeniería civil 660 - Ingeniería química Microalga Licuefacción hidrotermal Tratamiento de aguas residuales Procesos avanzados de oxidación Recuperación de nutrientes Oxidación hidrotermal con peroxido Chlorella vulgaris Microalgae Hydrothernal liquefaction Wastewater treatment Wet peroxide oxidation Nutrient recovery Advanced oxidation process
dc.subject.proposal.spa.fl_str_mv	Microalga Licuefacción hidrotermal Tratamiento de aguas residuales Procesos avanzados de oxidación Recuperación de nutrientes Oxidación hidrotermal con peroxido
dc.subject.proposal.none.fl_str_mv	Chlorella vulgaris
dc.subject.proposal.eng.fl_str_mv	Microalgae Hydrothernal liquefaction Wastewater treatment Wet peroxide oxidation Nutrient recovery Advanced oxidation process
description	Múltiples estudios presentan las microalgas como la fuente de biocombustibles más prometedora, debido a que, entre otras características, son 50 veces más eficientes en convertir la luz solar en biomasa y capturan entre 10 y 50 veces más CO2 que las plantas terrestres. Debido a que el contenido de agua de estos microorganismos puede alcanzar más del 95% en peso, la licuefacción hidrotermal (LHT), que emplea agua a condiciones supercríticas, se ha perfilado como la mejor manera para convertir la biomasa húmeda de microalga en biocrudo. Sin embargo, el rendimiento del proceso para producir biocrudo no supera el 50%, por lo que la generación de una fase acuosa (subproducto de la LHT) constituye el principal residuo del proceso. El presente trabajo pretende evaluar otro proceso hidrotermal, denominado oxidación hidrotermal con peróxido, como alternativa de tratamiento de la fase acuosa proveniente de la LHT de la microalga Chlorella vulgaris. En primer lugar, se obtuvo la biomasa algal a licuar, se caracterizó bioquímicamente y se realizó la licuefacción hidrotermal, determinando los rendimientos de producción de cada una de las fases a condiciones constantes de reacción (375ºC y 15 minutos de reacción). Posteriormente se caracterizó la fase acuosa obtenida y se diseñó un plan de experimentos que permita establecer las condiciones de reacción adecuadas (tiempo y relación molar de peróxido) que maximicen la producción de fase acuosa tratada. Finalmente, se caracterizó la fase acuosa tratada y se realizaron cultivos comparativos de la microalga en diferentes diluciones de fase acuosa, con el fin de cuantificar el crecimiento algal y evaluar el potencial de recirculación del agua tratada por medio de la oxidación hidrotermal con peróxido. Con el desarrollo de este trabajo se demostró que es viable tratar la fase acuosa de la LHT, para recircular agua y recuperar nutrientes; con lo cual, se mejora la sostenibilidad ambiental y energética de la producción de biocrudo a partir de algas. (Texto tomado de la fuente)
publishDate	2021
dc.date.accessioned.none.fl_str_mv	2021-08-18T15:15:12Z
dc.date.available.none.fl_str_mv	2021-08-18T15:15:12Z
dc.date.issued.none.fl_str_mv	2021-06
dc.type.spa.fl_str_mv	Trabajo de grado - Maestría
dc.type.driver.spa.fl_str_mv	info:eu-repo/semantics/masterThesis
dc.type.version.spa.fl_str_mv	info:eu-repo/semantics/acceptedVersion
dc.type.content.spa.fl_str_mv	DataPaper Text
dc.type.redcol.spa.fl_str_mv	http://purl.org/redcol/resource_type/TM
status_str	acceptedVersion
dc.identifier.uri.none.fl_str_mv	https://repositorio.unal.edu.co/handle/unal/79961
dc.identifier.instname.spa.fl_str_mv	Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv	Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv	https://repositorio.unal.edu.co/
url	https://repositorio.unal.edu.co/handle/unal/79961 https://repositorio.unal.edu.co/
identifier_str_mv	Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv	spa
language	spa
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rights_invalid_str_mv	Atribución-NoComercial-SinDerivadas 4.0 Internacional Derechos reservados al autor, 2021 http://creativecommons.org/licenses/by-nc-nd/4.0/ http://purl.org/coar/access_right/c_abf2
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dc.publisher.spa.fl_str_mv	Universidad Nacional de Colombia
dc.publisher.program.spa.fl_str_mv	Bogotá - Ingeniería - Maestría en Ingeniería - Ingeniería Química
dc.publisher.faculty.spa.fl_str_mv	Facultad de Ingeniería
dc.publisher.place.spa.fl_str_mv	Bogotá - Colombia
dc.publisher.branch.spa.fl_str_mv	Universidad Nacional de Colombia - Sede Bogotá
institution	Universidad Nacional de Colombia
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spelling	Atribución-NoComercial-SinDerivadas 4.0 InternacionalDerechos reservados al autor, 2021http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Godoy Silva, Rubén Darío019810b6b9f5c2a275ca1c832cf9cda7Rodríguez Varela, Luis Ignaciocbbd6a87ab310fe6ca4325ebe6c3cff6Pasos Panqueva, Johan Andrés13dd44532bed0a88c6b70cc9ca9c14ba2021-08-18T15:15:12Z2021-08-18T15:15:12Z2021-06https://repositorio.unal.edu.co/handle/unal/79961Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/Múltiples estudios presentan las microalgas como la fuente de biocombustibles más prometedora, debido a que, entre otras características, son 50 veces más eficientes en convertir la luz solar en biomasa y capturan entre 10 y 50 veces más CO2 que las plantas terrestres. Debido a que el contenido de agua de estos microorganismos puede alcanzar más del 95% en peso, la licuefacción hidrotermal (LHT), que emplea agua a condiciones supercríticas, se ha perfilado como la mejor manera para convertir la biomasa húmeda de microalga en biocrudo. Sin embargo, el rendimiento del proceso para producir biocrudo no supera el 50%, por lo que la generación de una fase acuosa (subproducto de la LHT) constituye el principal residuo del proceso. El presente trabajo pretende evaluar otro proceso hidrotermal, denominado oxidación hidrotermal con peróxido, como alternativa de tratamiento de la fase acuosa proveniente de la LHT de la microalga Chlorella vulgaris. En primer lugar, se obtuvo la biomasa algal a licuar, se caracterizó bioquímicamente y se realizó la licuefacción hidrotermal, determinando los rendimientos de producción de cada una de las fases a condiciones constantes de reacción (375ºC y 15 minutos de reacción). Posteriormente se caracterizó la fase acuosa obtenida y se diseñó un plan de experimentos que permita establecer las condiciones de reacción adecuadas (tiempo y relación molar de peróxido) que maximicen la producción de fase acuosa tratada. Finalmente, se caracterizó la fase acuosa tratada y se realizaron cultivos comparativos de la microalga en diferentes diluciones de fase acuosa, con el fin de cuantificar el crecimiento algal y evaluar el potencial de recirculación del agua tratada por medio de la oxidación hidrotermal con peróxido. Con el desarrollo de este trabajo se demostró que es viable tratar la fase acuosa de la LHT, para recircular agua y recuperar nutrientes; con lo cual, se mejora la sostenibilidad ambiental y energética de la producción de biocrudo a partir de algas. (Texto tomado de la fuente)Multiple studies present microalgae as the most promising source of biofuels, due to the fact that, among other characteristics, they are 50 times more efficient in converting sunlight into biomass and capture between 10 and 50 times more CO2 than terrestrial plants. Because the water content of these microorganisms can reach more than 95% by weight, hydrothermal liquefaction (LHT), which uses water at supercritical conditions, has emerged as the best way to convert wet microalgae biomass to biocrude. However, the yield of the process to produce biocrude does not exceed 50%, so the generation of an aqueous phase (by-product of the LHT) constitutes the main waste of the process. The present work aims to evaluate another hydrothermal process, called hydrothermal oxidation with peroxide, as an alternative for treating the aqueous phase from the LHT of the microalgae Chlorella vulgaris. First, the algal biomass to be liquefied was obtained, it was biochemically characterized and hydrothermal liquefaction was carried out, determining the production yields of each of the phases at constant reaction conditions (375ºC and 15 minutes of reaction). Subsequently, the aqueous phase obtained was characterized and an experiment plan was designed to establish the appropriate reaction conditions (time and molar ratio of peroxide) that maximize the production of the treated aqueous phase. Finally, the treated aqueous phase was characterized and comparative cultures of the microalgae were carried out in different dilutions of the aqueous phase, in order to quantify the algal growth and evaluate the recirculation potential of the treated water by means of hydrothermal oxidation with peroxide. With the development of this work it was demonstrated that it is feasible to treat the aqueous phase of the LHT, to recirculate water and recover nutrients; with which, the environmental and energy sustainability of the production of biocrude from algae is improved.(Text taken from the source)MaestríaMagister en Ingeniería QuímicaBioprocesosProcesos termoquímicos190 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ingeniería - Maestría en Ingeniería - Ingeniería QuímicaFacultad de IngenieríaBogotá - ColombiaUniversidad Nacional de Colombia - Sede Bogotá620 - Ingeniería y operaciones afines::624 - Ingeniería civil660 - Ingeniería químicaMicroalgaLicuefacción hidrotermalTratamiento de aguas residualesProcesos avanzados de oxidaciónRecuperación de nutrientesOxidación hidrotermal con peroxidoChlorella vulgarisMicroalgaeHydrothernal liquefactionWastewater treatmentWet peroxide oxidationNutrient recoveryAdvanced oxidation processEvaluación del proceso de oxidación hidrotermal con peróxido como alternativa de tratamiento de la fase acuosa resultante de la licuefacción hidrotermal de microalgasAssessment of the wet peroxide oxidation process as an alternative for the treatment of the aqueous phase resulting from the hydrothermal liquefaction of microalgaeTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionDataPaperTexthttp://purl.org/redcol/resource_type/TMAbreu, A. 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Thermochemical catalytic liquefaction of the marine microalgae dunaliella tertiolecta and characterization of bio-oils. Energy and Fuels, 23(7), 3753–3758. https://doi.org/10.1021/ef9000105EspecializadaUniversidad Nacional de ColombiaLICENSElicense.txtlicense.txttext/plain; charset=utf-83964https://repositorio.unal.edu.co/bitstream/unal/79961/1/license.txtcccfe52f796b7c63423298c2d3365fc6MD51ORIGINAL1032454795.2021.pdf1032454795.2021.pdfTesis de Maestría en Ingeniería Químicaapplication/pdf4305690https://repositorio.unal.edu.co/bitstream/unal/79961/3/1032454795.2021.pdf8969c5992c13f21f8236286d943d8c63MD53THUMBNAIL1032454795.2021.pdf.jpg1032454795.2021.pdf.jpgGenerated Thumbnailimage/jpeg5433https://repositorio.unal.edu.co/bitstream/unal/79961/4/1032454795.2021.pdf.jpg4fa22dff3e49f0f98eae0129b0c58824MD54unal/79961oai:repositorio.unal.edu.co:unal/799612024-07-27 00:13:39.918Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.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