Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixture
An accurate gas chromatography coupled to a flame ionization detector (GC-FID) method was validated for the simultaneous analysis of light hydrocarbons (C2-C4) in their gas mixture. The validation parameters were evaluated based on the ISO/IEC 17025 definition including method selectivity, repeatabi...
- Autores:
-
Zuas, Oman
Budiman, Harry
Mulyana, Muhammad Rizky
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2016
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/66278
- Acceso en línea:
- https://repositorio.unal.edu.co/handle/unal/66278
http://bdigital.unal.edu.co/67302/
- Palabra clave:
- 54 Química y ciencias afines / Chemistry
method validation
hydrocarbons
GC-FID
ISO/IEC 17025
validación de método analítico
hidrocarburos
GC-FID
ISO/IEC 17025
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixture |
| title |
Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixture |
| spellingShingle |
Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixture 54 Química y ciencias afines / Chemistry method validation hydrocarbons GC-FID ISO/IEC 17025 validación de método analítico hidrocarburos GC-FID ISO/IEC 17025 |
| title_short |
Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixture |
| title_full |
Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixture |
| title_fullStr |
Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixture |
| title_full_unstemmed |
Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixture |
| title_sort |
Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixture |
| dc.creator.fl_str_mv |
Zuas, Oman Budiman, Harry Mulyana, Muhammad Rizky |
| dc.contributor.author.spa.fl_str_mv |
Zuas, Oman Budiman, Harry Mulyana, Muhammad Rizky |
| dc.subject.ddc.spa.fl_str_mv |
54 Química y ciencias afines / Chemistry |
| topic |
54 Química y ciencias afines / Chemistry method validation hydrocarbons GC-FID ISO/IEC 17025 validación de método analítico hidrocarburos GC-FID ISO/IEC 17025 |
| dc.subject.proposal.spa.fl_str_mv |
method validation hydrocarbons GC-FID ISO/IEC 17025 validación de método analítico hidrocarburos GC-FID ISO/IEC 17025 |
| description |
An accurate gas chromatography coupled to a flame ionization detector (GC-FID) method was validated for the simultaneous analysis of light hydrocarbons (C2-C4) in their gas mixture. The validation parameters were evaluated based on the ISO/IEC 17025 definition including method selectivity, repeatability, accuracy, linearity, limit of detection (LOD), limit of quantitation (LOQ), and ruggedness. Under the optimum analytical conditions, the analysis of gas mixture revealed that each target component was well-separated with high selectivity property. The method was also found to be precise and accurate. The method linearity was found to be high with good correlation coefficient values (R2 ≥ 0.999) for all target components. It can be concluded that the GC-FID developed method is reliable and suitable for determination of light C2-C4 hydrocarbons (including ethylene, propane, propylene, isobutane, and n-butane) in their gas mixture. The validated method has successfully been applied to the estimation of hydrocarbons light C2-C4 hydrocarbons in natural gas samples, showing high performance repeatability with relative standard deviation (RSD) less than 1.0% and good selectivity with no interference from other possible components could be observed. |
| publishDate |
2016 |
| dc.date.issued.spa.fl_str_mv |
2016-09-01 |
| dc.date.accessioned.spa.fl_str_mv |
2019-07-03T01:49:24Z |
| dc.date.available.spa.fl_str_mv |
2019-07-03T01:49:24Z |
| dc.type.spa.fl_str_mv |
Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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info:eu-repo/semantics/article |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_6501 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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Text |
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http://purl.org/redcol/resource_type/ART |
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publishedVersion |
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ISSN: 2357-3791 |
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https://repositorio.unal.edu.co/handle/unal/66278 |
| dc.identifier.eprints.spa.fl_str_mv |
http://bdigital.unal.edu.co/67302/ |
| identifier_str_mv |
ISSN: 2357-3791 |
| url |
https://repositorio.unal.edu.co/handle/unal/66278 http://bdigital.unal.edu.co/67302/ |
| dc.language.iso.spa.fl_str_mv |
spa |
| language |
spa |
| dc.relation.spa.fl_str_mv |
https://revistas.unal.edu.co/index.php/rcolquim/article/view/58085 |
| dc.relation.ispartof.spa.fl_str_mv |
Universidad Nacional de Colombia Revistas electrónicas UN Revista Colombiana de Química Revista Colombiana de Química |
| dc.relation.references.spa.fl_str_mv |
Zuas, Oman and Budiman, Harry and Mulyana, Muhammad Rizky (2016) Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixture. Revista Colombiana de Química, 45 (3). pp. 22-27. ISSN 2357-3791 |
| dc.rights.spa.fl_str_mv |
Derechos reservados - Universidad Nacional de Colombia |
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http://purl.org/coar/access_right/c_abf2 |
| dc.rights.license.spa.fl_str_mv |
Atribución-NoComercial 4.0 Internacional |
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http://creativecommons.org/licenses/by-nc/4.0/ |
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info:eu-repo/semantics/openAccess |
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Atribución-NoComercial 4.0 Internacional Derechos reservados - Universidad Nacional de Colombia http://creativecommons.org/licenses/by-nc/4.0/ http://purl.org/coar/access_right/c_abf2 |
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openAccess |
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application/pdf |
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Universidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Química |
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Universidad Nacional de Colombia |
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Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Zuas, Oman9a6b5abe-8393-4d19-981b-c2fdecc26052300Budiman, Harryf8da76fb-be1c-430a-af3b-efe58436e1df300Mulyana, Muhammad Rizky2df0d614-2e77-4a02-858e-b858d0a340713002019-07-03T01:49:24Z2019-07-03T01:49:24Z2016-09-01ISSN: 2357-3791https://repositorio.unal.edu.co/handle/unal/66278http://bdigital.unal.edu.co/67302/An accurate gas chromatography coupled to a flame ionization detector (GC-FID) method was validated for the simultaneous analysis of light hydrocarbons (C2-C4) in their gas mixture. The validation parameters were evaluated based on the ISO/IEC 17025 definition including method selectivity, repeatability, accuracy, linearity, limit of detection (LOD), limit of quantitation (LOQ), and ruggedness. Under the optimum analytical conditions, the analysis of gas mixture revealed that each target component was well-separated with high selectivity property. The method was also found to be precise and accurate. The method linearity was found to be high with good correlation coefficient values (R2 ≥ 0.999) for all target components. It can be concluded that the GC-FID developed method is reliable and suitable for determination of light C2-C4 hydrocarbons (including ethylene, propane, propylene, isobutane, and n-butane) in their gas mixture. The validated method has successfully been applied to the estimation of hydrocarbons light C2-C4 hydrocarbons in natural gas samples, showing high performance repeatability with relative standard deviation (RSD) less than 1.0% and good selectivity with no interference from other possible components could be observed.Se validó una cromatrografía de gases precisa, equipada con un detector de ionización de llama (GC-FID) para el análisis simultáneo de hidrocarburos ligeros (C2-C4) en su mezcla gaseosa. Los parámetros de validación se evaluaron con base en la definición de la ISO/IEC 17025, que incluye selectividad del método, precisión y repetibilidad, exactitud, linealidad, límite de detección (LOD), límite de cuantificación (LOQ) y robustez. Bajo las condiciones analíticas óptimas, el análisis de la mezcla gaseosa mostró que cada analito de interés fue separado adecuadamente con alta selectividad. Se encontró también que el método era preciso y exacto; la linealidad fue alta y con buen coeficiente de correlación lineal (R2 ≥ 0.999) para todos los analitos. Se puede concluir que el método GC-FID es confiable y apropiado para la determinación de hidrocarburos ligeros C2-C4 (incluyendo etileno, propano, propileno, isobutano y n-butano) en una mezcla gaseosa. El método validado ha sido exitosamente aplicado a la valoración de hidrocarburos ligeros C2-C4 en muestras de gas natural, mostrando alta repetibilidad con desviación estándar relativa (RDS) menor al 1% y buena selectividad sin interferencias de otros posibles componentes.application/pdfspaUniversidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Químicahttps://revistas.unal.edu.co/index.php/rcolquim/article/view/58085Universidad Nacional de Colombia Revistas electrónicas UN Revista Colombiana de QuímicaRevista Colombiana de QuímicaZuas, Oman and Budiman, Harry and Mulyana, Muhammad Rizky (2016) Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixture. Revista Colombiana de Química, 45 (3). pp. 22-27. ISSN 2357-379154 Química y ciencias afines / Chemistrymethod validationhydrocarbonsGC-FIDISO/IEC 17025validación de método analíticohidrocarburosGC-FIDISO/IEC 17025Analytical method validation of GC-FID for the simultaneous measurement of hydrocarbons (C2-C4) in their gas mixtureArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTORIGINAL58085-318166-1-PB.pdfapplication/pdf899924https://repositorio.unal.edu.co/bitstream/unal/66278/1/58085-318166-1-PB.pdf1a77391785ad41026cc729fa082265ebMD51THUMBNAIL58085-318166-1-PB.pdf.jpg58085-318166-1-PB.pdf.jpgGenerated Thumbnailimage/jpeg9634https://repositorio.unal.edu.co/bitstream/unal/66278/2/58085-318166-1-PB.pdf.jpg906fab484e85d897a00f15a358ed8295MD52unal/66278oai:repositorio.unal.edu.co:unal/662782023-05-24 23:02:59.463Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co |