Volumetric properties of (peg 400 + water) and (peg 400 + ethanol) mixtures at several temperatures and correlation with the jouyban-acree model

Molar volumes and excess molar volumes were investigated from density values for (PEG 400 + water) and (PEG 400 + ethanol) binary mixtures at temperatures from 283.15 K to 313.15 K. Both systems exhibit negative excess volumes probably due to increased interactions like hydrogen bonding and/or large...

Full description

Autores:
Rodríguez, Gerson A.
Holguín, Andrés R.
Martínez, Fleming
Khoubnasabjafari, Maryam
Jouyban, Abolghasem
Tipo de recurso:
Article of journal
Fecha de publicación:
2012
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/49313
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/49313
http://bdigital.unal.edu.co/42770/
http://bdigital.unal.edu.co/42770/2/
Palabra clave:
PEG 400
etanol
agua
mezclas líquidas binarias
densidad
volumen de exceso
modelo de Jouyban-Acree
PEG 400
ethanol
water
binary liquid mixtures
density
excess volume
Jouyban-Acree model
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional
Description
Summary:Molar volumes and excess molar volumes were investigated from density values for (PEG 400 + water) and (PEG 400 + ethanol) binary mixtures at temperatures from 283.15 K to 313.15 K. Both systems exhibit negative excess volumes probably due to increased interactions like hydrogen bonding and/or large differences in molar volumes of components. Volume thermal expansion coefficients were also calculated for binary mixtures and pure solvents. The Jouyban-Acree model was used for density and molar volume correlations of the studied mixtures at different temperatures. The mean relative deviations between experimental and calculated density data were 0.1 and 0.5 %, for aqueous and ethanolic mixtures, respectively; whereas, in molar volume data the values were 18.0 and 6.9 %, for aqueous and ethanolic mixtures, respectively. The trained versions of the model for PEG 400 binary solvents could be used to predict the density values of other PEGs with reasonable prediction error employing the density of mono-solvents.