Compuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacteriana

Ilustraciones

Autores:: Múnera Gómez, Luisa Fernanda

Tipo de recurso:

Fecha de publicación:: 2023

Institución:: Universidad Nacional de Colombia

Repositorio:: Universidad Nacional de Colombia

Idioma:: spa

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network_acronym_str	UNACIONAL2
network_name_str	Universidad Nacional de Colombia
repository_id_str
dc.title.spa.fl_str_mv	Compuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacteriana
dc.title.translated.eng.fl_str_mv	Coordination compounds of divalent metals with amino acids and dicarboxylic acids: potential antibacterial activity
title	Compuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacteriana
spellingShingle	Compuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacteriana 540 - Química y ciencias afines::546 - Química inorgánica 540 - Química y ciencias afines::547 - Química orgánica Aminoácidos Compuestos de coordinación Compuestos de coordinación Actividad antibacteriana Aminoácidos Glicina Alanina Metáles divalentes Ácidos dicarboxílicos Concentración mínima inhibitoria Coordination compounds Antibacterial activity Amino acids Glycine Alanine Divalent metals Dicarboxylic acids Minimum inhibitory concentration Glicina Alanina
title_short	Compuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacteriana
title_full	Compuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacteriana
title_fullStr	Compuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacteriana
title_full_unstemmed	Compuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacteriana
title_sort	Compuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacteriana
dc.creator.fl_str_mv	Múnera Gómez, Luisa Fernanda
dc.contributor.advisor.none.fl_str_mv	Pabón Gelves, Elizabeth Muñoz Acevedo, Juan Carlos
dc.contributor.author.none.fl_str_mv	Múnera Gómez, Luisa Fernanda
dc.contributor.researchgroup.spa.fl_str_mv	Ciencia de Materiales Avanzados
dc.contributor.orcid.spa.fl_str_mv	Múnera Gómez, Luisa [0009-0006-3097-2849]
dc.contributor.cvlac.spa.fl_str_mv	Múnera Gómez, Luisa Fernanda [0001949499]
dc.subject.ddc.spa.fl_str_mv	540 - Química y ciencias afines::546 - Química inorgánica 540 - Química y ciencias afines::547 - Química orgánica
topic	540 - Química y ciencias afines::546 - Química inorgánica 540 - Química y ciencias afines::547 - Química orgánica Aminoácidos Compuestos de coordinación Compuestos de coordinación Actividad antibacteriana Aminoácidos Glicina Alanina Metáles divalentes Ácidos dicarboxílicos Concentración mínima inhibitoria Coordination compounds Antibacterial activity Amino acids Glycine Alanine Divalent metals Dicarboxylic acids Minimum inhibitory concentration Glicina Alanina
dc.subject.lemb.none.fl_str_mv	Aminoácidos Compuestos de coordinación
dc.subject.proposal.spa.fl_str_mv	Compuestos de coordinación Actividad antibacteriana Aminoácidos Glicina Alanina Metáles divalentes Ácidos dicarboxílicos Concentración mínima inhibitoria
dc.subject.proposal.eng.fl_str_mv	Coordination compounds Antibacterial activity Amino acids Glycine Alanine Divalent metals Dicarboxylic acids Minimum inhibitory concentration
dc.subject.wikidata.none.fl_str_mv	Glicina Alanina
description	Ilustraciones
publishDate	2023
dc.date.issued.none.fl_str_mv	2023-12
dc.date.accessioned.none.fl_str_mv	2024-01-30T16:50:48Z
dc.date.available.none.fl_str_mv	2024-01-30T16:50:48Z
dc.type.spa.fl_str_mv	Trabajo de grado - Maestría
dc.type.driver.spa.fl_str_mv	info:eu-repo/semantics/masterThesis
dc.type.version.spa.fl_str_mv	info:eu-repo/semantics/acceptedVersion
dc.type.content.spa.fl_str_mv	Text
dc.type.redcol.spa.fl_str_mv	http://purl.org/redcol/resource_type/TM
status_str	acceptedVersion
dc.identifier.uri.none.fl_str_mv	https://repositorio.unal.edu.co/handle/unal/85529
dc.identifier.instname.spa.fl_str_mv	Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv	Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv	https://repositorio.unal.edu.co/
url	https://repositorio.unal.edu.co/handle/unal/85529 https://repositorio.unal.edu.co/
identifier_str_mv	Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv	spa
language	spa
dc.relation.indexed.spa.fl_str_mv	LaReferencia
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dc.publisher.spa.fl_str_mv	Universidad Nacional de Colombia
dc.publisher.program.spa.fl_str_mv	Medellín - Ciencias - Maestría en Ciencias - Química
dc.publisher.faculty.spa.fl_str_mv	Facultad de Ciencias
dc.publisher.place.spa.fl_str_mv	Medellín, Colombia
dc.publisher.branch.spa.fl_str_mv	Universidad Nacional de Colombia - Sede Medellín
institution	Universidad Nacional de Colombia
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spelling	Atribución-NoComercial-SinDerivadas 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Pabón Gelves, Elizabeth29dab4728be81c8d9276a582c19c9b32Muñoz Acevedo, Juan Carlos9febf6fa56a6f9b8cf7adb1c171a1540Múnera Gómez, Luisa Fernanda7aa0ca975a5f1e24170e43474b8ea2daCiencia de Materiales AvanzadosMúnera Gómez, Luisa [0009-0006-3097-2849]Múnera Gómez, Luisa Fernanda [0001949499]2024-01-30T16:50:48Z2024-01-30T16:50:48Z2023-12https://repositorio.unal.edu.co/handle/unal/85529Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/IlustracionesLos compuestos de coordinación con ligandos orgánicos de interés biológico han demostrado tener actividad antibacteriana ante una gran variedad de géneros entre los que se incluyen algunas bacterias resistentes a los tratamientos convencionales. Los aminoácidos son un grupo de moléculas muy versátiles con dos grupos funcionales (amino y carboxilo), esto favorece la interacción con el metal permitiendo sintetizar compuestos con alto potencial antibacteriano. En esta tesis se sintetizaron por métodos convencionales compuestos de coordinación con los metales divalente cobre y níquel, y se usaron como ligandos los aminoácidos glicina, alanina y los ácidos dicarboxílicos itacónico y oxálico. La caracterización de los compuestos sintetizados se realizó por análisis termogravimétrico (TGA), espectroscopia infrarroja por transformada de Fourier (FTIR), espectroscopia ultravioleta - visible (UV-vis) y difracción de rayos X (DRX), mostrando que los compuestos son octaédricos, cristalinos y estables a temperaturas entre los 250 a 300°C. Además, estos compuestos mostraron buena actividad antibacteriana principalmente contra cepas gram-positivas, esto se comprobó por el método del halo de inhibición y mediante la determinación de la concentración mínima inhibitoria la cual fue de 20 ppm para los compuestos con cobre y para los compuestos con níquel estuvo entre 10 y 5 ppm. (texto tomado de la fuente)Coordination compounds with organic ligands of biological interest have shown to have antibacterial activity against a wide variety of genera, including some bacteria resistant to conventional treatments. Amino acids are a group of very versatile molecules with two functional groups (amino and carboxyl), this favors the interaction with the metal, allowing the synthesis of compounds with high antibacterial potential. In this thesis, coordination compounds with the divalent metals copper and nickel were synthesized by conventional methods, and the amino acids glycine, alanine, and the dicarboxylic acids itaconic and oxalic acids were used as ligands. The characterization of the synthesized compounds was carried out by thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), ultraviolet - visible spectroscopy (UV-vis) and X-ray diffraction (XRD), showing that the compounds are octahedral, crystalline and stable at temperatures between 250 to 300°C. In addition, these compounds showed good antibacterial activity mainly against gram-positive strains, this was verified by the inhibition zone method and by determining the minimum inhibitory concentration which was 20 ppm for the compounds with copper and for the compounds with Nickel was between 10 and 5 ppm.MaestríaMagíster en Ciencias - QuímicaÁrea Curricular en Ciencias Naturales100 páginasapplication/pdfspaUniversidad Nacional de ColombiaMedellín - Ciencias - Maestría en Ciencias - QuímicaFacultad de CienciasMedellín, ColombiaUniversidad Nacional de Colombia - Sede Medellín540 - Química y ciencias afines::546 - Química inorgánica540 - Química y ciencias afines::547 - Química orgánicaAminoácidosCompuestos de coordinaciónCompuestos de coordinaciónActividad antibacterianaAminoácidosGlicinaAlaninaMetáles divalentesÁcidos dicarboxílicosConcentración mínima inhibitoriaCoordination compoundsAntibacterial activityAmino acidsGlycineAlanineDivalent metalsDicarboxylic acidsMinimum inhibitory concentrationGlicinaAlaninaCompuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacterianaCoordination compounds of divalent metals with amino acids and dicarboxylic acids: potential antibacterial activityTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMLaReferenciaT. 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