Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process

ilustraciones, diagramas

Autores:: Manrique Waldo, Raiza Johanna

Tipo de recurso:: Doctoral thesis

Fecha de publicación:: 2023

Institución:: Universidad Nacional de Colombia

Repositorio:: Universidad Nacional de Colombia

Idioma:: eng

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dc.title.eng.fl_str_mv	Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process
dc.title.translated.spa.fl_str_mv	Estudio de la interacción entre los oligómeros de la fracción pesada del bioaceite de pirólisis rápida y un catalizador en el proceso de hidrotratamiento
title	Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process
spellingShingle	Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process 660 - Ingeniería química::661 - Tecnología de químicos industriales 660 - Ingeniería química::662 - Tecnología de explosivos, combustibles, productos relacionados Pirólisis Hidrogenación Hydrogenation Pyrolysis Pyrolysis bio-oil Pyrolytic lignin Oligomers Structures Fractionation Bio-oil upgrading Bioaceite de pirólisis Lignina pirolítica Oligómeros Estructuras Fraccionamiento Mejoramiento del bioaceite
title_short	Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process
title_full	Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process
title_fullStr	Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process
title_full_unstemmed	Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process
title_sort	Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process
dc.creator.fl_str_mv	Manrique Waldo, Raiza Johanna
dc.contributor.advisor.none.fl_str_mv	Chejne, Farid García Pérez, Manuel
dc.contributor.author.none.fl_str_mv	Manrique Waldo, Raiza Johanna
dc.contributor.researchgroup.spa.fl_str_mv	Termodinámica Aplicada y Energías Alternativas
dc.contributor.orcid.none.fl_str_mv	Chejne, Farid [0000-0003-0445-7609] Manrique Waldo, Raiza Johanna [0000-0002-6702-5419]
dc.contributor.cvlac.spa.fl_str_mv	Raiza Manrique Waldo
dc.contributor.scopus.spa.fl_str_mv	https://www.scopus.com/authid/detail.uri?authorId=57195741838
dc.contributor.researchgate.spa.fl_str_mv	https://www.researchgate.net/profile/Raiza-Manrique
dc.contributor.googlescholar.spa.fl_str_mv	https://scholar.google.com/citations?user=vWdtrjUAAAAJ&hl=es&oi=ao
dc.subject.ddc.spa.fl_str_mv	660 - Ingeniería química::661 - Tecnología de químicos industriales 660 - Ingeniería química::662 - Tecnología de explosivos, combustibles, productos relacionados
topic	660 - Ingeniería química::661 - Tecnología de químicos industriales 660 - Ingeniería química::662 - Tecnología de explosivos, combustibles, productos relacionados Pirólisis Hidrogenación Hydrogenation Pyrolysis Pyrolysis bio-oil Pyrolytic lignin Oligomers Structures Fractionation Bio-oil upgrading Bioaceite de pirólisis Lignina pirolítica Oligómeros Estructuras Fraccionamiento Mejoramiento del bioaceite
dc.subject.lemb.spa.fl_str_mv	Pirólisis Hidrogenación
dc.subject.lemb.eng.fl_str_mv	Hydrogenation Pyrolysis
dc.subject.proposal.eng.fl_str_mv	Pyrolysis bio-oil Pyrolytic lignin Oligomers Structures Fractionation Bio-oil upgrading
dc.subject.proposal.spa.fl_str_mv	Bioaceite de pirólisis Lignina pirolítica Oligómeros Estructuras Fraccionamiento Mejoramiento del bioaceite
description	ilustraciones, diagramas
publishDate	2023
dc.date.accessioned.none.fl_str_mv	2023-06-02T15:17:24Z
dc.date.available.none.fl_str_mv	2023-06-02T15:17:24Z
dc.date.issued.none.fl_str_mv	2023-06-01
dc.type.spa.fl_str_mv	Trabajo de grado - Doctorado
dc.type.driver.spa.fl_str_mv	info:eu-repo/semantics/doctoralThesis
dc.type.version.spa.fl_str_mv	info:eu-repo/semantics/acceptedVersion
dc.type.coar.spa.fl_str_mv	http://purl.org/coar/resource_type/c_db06
dc.type.content.spa.fl_str_mv	DataPaper
dc.type.redcol.spa.fl_str_mv	http://purl.org/redcol/resource_type/TD
format	http://purl.org/coar/resource_type/c_db06
status_str	acceptedVersion
dc.identifier.uri.none.fl_str_mv	https://repositorio.unal.edu.co/handle/unal/83957
dc.identifier.instname.spa.fl_str_mv	Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv	Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv	https://repositorio.unal.edu.co/
url	https://repositorio.unal.edu.co/handle/unal/83957 https://repositorio.unal.edu.co/
identifier_str_mv	Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv	eng
language	eng
dc.relation.indexed.spa.fl_str_mv	RedCol LaReferencia
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repository.mail.fl_str_mv	repositorio_nal@unal.edu.co
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spelling	Reconocimiento 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Chejne, Farid5f55a1a2aa209c6410295ac96392e6b6García Pérez, Manuela1b55cd912e5792e06790c630c03544bManrique Waldo, Raiza Johanna52ea2c1b51a419be9cdf11b07e1c49f5Termodinámica Aplicada y Energías AlternativasChejne, Farid [0000-0003-0445-7609]Manrique Waldo, Raiza Johanna [0000-0002-6702-5419]Raiza Manrique Waldohttps://www.scopus.com/authid/detail.uri?authorId=57195741838https://www.researchgate.net/profile/Raiza-Manriquehttps://scholar.google.com/citations?user=vWdtrjUAAAAJ&hl=es&oi=ao2023-06-02T15:17:24Z2023-06-02T15:17:24Z2023-06-01https://repositorio.unal.edu.co/handle/unal/83957Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, diagramasBiomass fast pyrolysis bio-oil is a promising alternative to be used as a source of fuels and chemicals. It hosts a wide variety of compounds and comes from renewable sources. Pyrolysis oil is formed by water, light organics (GC/MS detectable compounds), Oligomeric fractions derived from lignin and holocellulose. This dissertation focusses on the identification of oligomeric molecules in the pyrolytic lignin fraction and its catalytic hydrodeoxygenation. This fraction can potentially be used to produce fuels and chemicals via hydrodeoxygenation. The chemical structure of pyrolytic lignin oligomeric molecules is poorly known. In this study, quantum mechanical simulation was used to propose the structures based on calculations of the electronic structure. The DFT calculations were used to identify the thermodynamically most probable chemical structures of pyrolytic lignin molecules resulting from lignin pyrolysis followed by demethylation. The structure of new molecules of dimer, trimer and tetramer oligomers from pyrolytic lignin were proposed. The pyrolytic lignin fraction was further fractionated by solid-liquid extraction and the resulting subfraction thoroughly characterized using FTIR, UV-fluorescence and HSQC-NMR. Ethyl acetate subfractions was characterized by phenolic compounds with methoxyl substituents while acetone and isopropanol subfractions showed more aliphatic characteristics. Pyrolytic lignin fraction from BTG was hydrotreated with a sulfided NiMo/Al2O3 catalyst. Hydrotreating experiments were carried out with mixtures of pyrolytic lignin and yellow grease to obtain liquid fuels. All blends induced coke formation values between 0.7 and 2.5 wt. %, indicating that pyrolytic lignin has potential to reduce coke formation during the process. The results obtained in this thesis will allow the definition of strategies for the design of biorefineries including pyrolytic lignin to obtain products.El bioaceite de pirólisis rápida de biomasa es una alternativa prometedora para ser utilizada como fuente de combustibles y productos químicos. Alberga una amplia variedad de compuestos y proviene de fuentes renovables. El aceite de pirólisis está formado por agua, compuestos orgánicos ligeros (compuestos detectables por GC/MS), fracciones oligoméricas derivadas de la lignina y holocelulosa. Esta tesis se centra en la identificación de moléculas oligoméricas en la fracción pirolítica de lignina y su hidrodesoxigenación catalítica. Esta fracción se puede utilizar potencialmente para la producción de combustibles y productos químicos a través de la hidrodesoxigenación. La estructura química de las moléculas oligoméricas de lignina pirolítica es poco conocida. En este estudio, se utilizó simulación mecánica cuántica para proponer las estructuras basadas en cálculos de la estructura electrónica. Los cálculos DFT se utilizaron para identificar las estructuras químicas termodinámicamente más probables de las moléculas de lignina pirolítica resultantes de la pirólisis de lignina seguida de desmetilación. Se propuso la estructura de nuevas moléculas de oligómeros dímeros, trímeros y tetrámeros a partir de lignina pirolítica. La fracción de lignina pirolítica se fraccionó adicionalmente mediante extracción sólido-líquido y la subfracción resultante se caracterizó minuciosamente usando FTIR, UV-fluorescencia, HSQC-NMR. Las subfracciones de acetato de etilo se caracterizaron por compuestos fenólicos con sustituyentes metoxilo, mientras que la subfracción de acetona e isopropanol mostró características más alifáticas. Se realizó el hidrotratmiento de la fracción de lignina pirolítica de BTG con un catalizador de NiMo/Al2O3 sulfurado. Se realizaron experimentos de hidrotratamiento con mezclas de lignina pirolítica y grasa amarilla para obtener combustibles líquidos. Todas las mezclas obtuvieron valores de formación de coque entre 0,7 y 2,5 en peso. %, lo que indica que la lignina pirolítica tiene potencial para reducir la formación de coque durante el proceso. Los resultados obtenidos en esta tesis permitirán definir estrategias para el diseño de biorrefinerías que incluyan lignina pirolítica para la obtención de productos. (Texto tomado de la fuente)World BankDoctoradoDoctor en IngenieríaValorization of the pyrolytic ligninValorización de la lignina pirolíticaÁrea curricular de Ingeniería Química e Ingeniería de Petróleosxviii, 96 páginas + 1 Anexoapplication/pdfengUniversidad Nacional de ColombiaMedellín - Minas - Doctorado en Ingeniería - Sistemas EnergéticosFacultad de MinasMedellín, ColombiaUniversidad Nacional de Colombia - Sede Medellín660 - Ingeniería química::661 - Tecnología de químicos industriales660 - Ingeniería química::662 - Tecnología de explosivos, combustibles, productos relacionadosPirólisisHidrogenaciónHydrogenationPyrolysisPyrolysis bio-oilPyrolytic ligninOligomersStructuresFractionationBio-oil upgradingBioaceite de pirólisisLignina pirolíticaOligómerosEstructurasFraccionamientoMejoramiento del bioaceiteStudy of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment processEstudio de la interacción entre los oligómeros de la fracción pesada del bioaceite de pirólisis rápida y un catalizador en el proceso de hidrotratamientoTrabajo de grado - Doctoradoinfo:eu-repo/semantics/doctoralThesisinfo:eu-repo/semantics/acceptedVersionhttp://purl.org/coar/resource_type/c_db06DataPaperhttp://purl.org/redcol/resource_type/TDRedColLaReferencia[1] L. 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West, “Analysis of polar species in jet fuel and determination of their role in autoxidative deposit formation,” Energy and Fuels, vol. 20, no. 6, pp. 2564–2571, Nov. 2006, doi: 10.1021/ef060275l.Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process - Contract number FP44842-210-2018Call 788 of Minciencias Scientific EcosystemPúblico generalLICENSElicense.txtlicense.txttext/plain; charset=utf-85879https://repositorio.unal.edu.co/bitstream/unal/83957/1/license.txteb34b1cf90b7e1103fc9dfd26be24b4aMD51ORIGINAL1152186564.2023.pdf1152186564.2023.pdfTesis de Doctorado en Ingeniería - Sistemas Energéticosapplication/pdf3870487https://repositorio.unal.edu.co/bitstream/unal/83957/2/1152186564.2023.pdf974c9a89697c8ad36216669f554f3a49MD521152186564.2023.SupplementaryMaterial.pdf1152186564.2023.SupplementaryMaterial.pdfANEXO Tesis de Doctorado en Ingeniería - Sistemas 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Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process

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