Desarrollo de herramientas metrológicas para la medición de aniones y cationes en suelos
ilustraciones, diagramas, fotografías, gráficas, tablas
- Autores:
-
Abella Gamba, Johanna Paola
- Tipo de recurso:
- Fecha de publicación:
- 2023
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/85244
- Palabra clave:
- 540 - Química y ciencias afines::543 - Química analítica
Metrología
Cationes
metrology
cations
Suelos
Material de referencia
Comparabilidad
Correlaciones
Elementos disponibles
Soils
Reference material
Comparability
Correlations
Soil available elements
- Rights
- openAccess
- License
- Atribución-NoComercial 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Desarrollo de herramientas metrológicas para la medición de aniones y cationes en suelos |
| dc.title.translated.eng.fl_str_mv |
Development of metrological tools for the measurement of anions and cations in soils |
| title |
Desarrollo de herramientas metrológicas para la medición de aniones y cationes en suelos |
| spellingShingle |
Desarrollo de herramientas metrológicas para la medición de aniones y cationes en suelos 540 - Química y ciencias afines::543 - Química analítica Metrología Cationes metrology cations Suelos Material de referencia Comparabilidad Correlaciones Elementos disponibles Soils Reference material Comparability Correlations Soil available elements |
| title_short |
Desarrollo de herramientas metrológicas para la medición de aniones y cationes en suelos |
| title_full |
Desarrollo de herramientas metrológicas para la medición de aniones y cationes en suelos |
| title_fullStr |
Desarrollo de herramientas metrológicas para la medición de aniones y cationes en suelos |
| title_full_unstemmed |
Desarrollo de herramientas metrológicas para la medición de aniones y cationes en suelos |
| title_sort |
Desarrollo de herramientas metrológicas para la medición de aniones y cationes en suelos |
| dc.creator.fl_str_mv |
Abella Gamba, Johanna Paola |
| dc.contributor.advisor.none.fl_str_mv |
Martínez Cordón, María José |
| dc.contributor.author.none.fl_str_mv |
Abella Gamba, Johanna Paola |
| dc.contributor.researcher.none.fl_str_mv |
Ahumada Forigua, Diego Alejandro |
| dc.contributor.researchgroup.spa.fl_str_mv |
Grupo de Investigación en Metrología Química y Bioanálisis del Instituto Nacional de Metrología de Colombia Residualidad y Destino Ambiental de Plaguicidas en Sistemas Agricolas |
| dc.subject.ddc.spa.fl_str_mv |
540 - Química y ciencias afines::543 - Química analítica |
| topic |
540 - Química y ciencias afines::543 - Química analítica Metrología Cationes metrology cations Suelos Material de referencia Comparabilidad Correlaciones Elementos disponibles Soils Reference material Comparability Correlations Soil available elements |
| dc.subject.agrovoc.spa.fl_str_mv |
Metrología Cationes |
| dc.subject.agrovoc.eng.fl_str_mv |
metrology cations |
| dc.subject.proposal.spa.fl_str_mv |
Suelos Material de referencia Comparabilidad Correlaciones Elementos disponibles |
| dc.subject.proposal.eng.fl_str_mv |
Soils Reference material Comparability Correlations Soil available elements |
| description |
ilustraciones, diagramas, fotografías, gráficas, tablas |
| publishDate |
2023 |
| dc.date.issued.none.fl_str_mv |
2023 |
| dc.date.accessioned.none.fl_str_mv |
2024-01-12T16:25:52Z |
| dc.date.available.none.fl_str_mv |
2024-01-12T16:25:52Z |
| dc.type.spa.fl_str_mv |
Trabajo de grado - Maestría |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/masterThesis |
| dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/acceptedVersion |
| dc.type.content.spa.fl_str_mv |
Text |
| dc.type.redcol.spa.fl_str_mv |
http://purl.org/redcol/resource_type/TM |
| status_str |
acceptedVersion |
| dc.identifier.uri.none.fl_str_mv |
https://repositorio.unal.edu.co/handle/unal/85244 |
| dc.identifier.instname.spa.fl_str_mv |
Universidad Nacional de Colombia |
| dc.identifier.reponame.spa.fl_str_mv |
Repositorio Institucional Universidad Nacional de Colombia |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.unal.edu.co/ |
| url |
https://repositorio.unal.edu.co/handle/unal/85244 https://repositorio.unal.edu.co/ |
| identifier_str_mv |
Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia |
| dc.language.iso.spa.fl_str_mv |
spa |
| language |
spa |
| dc.relation.references.spa.fl_str_mv |
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Atribución-NoComercial 4.0 InternacionalDerechos reservados al autor, 2023http://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Martínez Cordón, María José0f66912da9a6accaef9784be67b513ffAbella Gamba, Johanna Paolaf8588c3590dd213d593e78bf50b55c6bAhumada Forigua, Diego AlejandroGrupo de Investigación en Metrología Química y Bioanálisis del Instituto Nacional de Metrología de ColombiaResidualidad y Destino Ambiental de Plaguicidas en Sistemas Agricolas2024-01-12T16:25:52Z2024-01-12T16:25:52Z2023https://repositorio.unal.edu.co/handle/unal/85244Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, diagramas, fotografías, gráficas, tablasEn el presente documento, se presentan los resultados obtenidos en el desarrollo de dos herramientas metrológicas relacionadas con la medición de hierro, cobre, azufre y fósforo disponible en suelos. La primera herramienta correspondió a un material de referencia, para lo cual inicialmente se desarrollaron y validaron diferentes métodos para la medición de estos mensurandos por ICP-MS, cromatografía iónica y espectrofotometría UV-Vis. Estos métodos demostraron ser adecuados para evaluar la homogeneidad y estabilidad de materiales de referencia. Posteriormente, se presentan los resultados obtenidos en los estudios de preparación, homogeneidad y estabilidad de los materiales de referencia; los cuales permitieron soportar la obtención de materiales de referencia adecuados para su uso. Para el desarrollo de una segunda herramienta metrológica, se llevó a cabo un estudio preliminar del establecimiento de equivalencias entre el uso de diferentes técnicas analíticas para la medición de hierro, cobre, azufre y fósforo disponible en suelos; este estudio mostró que (i) existen diferencias en las mediciones obtenidas por diferentes técnicas analíticas y métodos de cuantificación; (ii) en algunos casos, como hierro, cobre y fósforo, estas diferencias podrían estar asociadas a la influencia de algunas propiedades de los suelos como la conductividad electrolítica, el contenido de manganeso y el pH. Finalmente, se proponen tres modelos multivariados que permiten mejorar la equivalencia entre las técnicas y reducir el error hasta en un 80%. (Texto tomado de la fuente)This document presents the results of the development of two metrological tools for measuring available iron, copper, sulfur, and phosphorus in soils. The first tool is a reference material. For its development, different measurement methods were validated using ICP-MS, ion chromatography, and UV-Vis spectrophotometry. These methods proved to be suitable for evaluating the homogeneity and stability of reference materials. The results obtained in the preparation, homogeneity, and stability studies of the reference materials are presented below, which supported that reference materials were obtained with uncertainties due to homogeneity and stability suitable for their use. For the development of a second metrological tool, a preliminary study was carried out to establish equivalences between different analytical techniques for measuring available iron, copper, sulfur, and phosphorus in soils. This study showed that (i) there are differences in the measurements obtained by different analytical techniques and quantification methods; (ii) in some cases, such as iron, copper, and phosphorus, these differences could be associated with the influence of some soil properties such as electrolytic conductivity, manganese content, and pH. Finally, three multivariate models are proposed that allow improving the equivalence between techniques and reducing error by up to 80%.MaestríaMagíster en Ciencias - QuímicaQuímica analítica / Metrología Química / Química del sueloxxii, 170 páginasapplication/pdfspaUniversidad Nacional de ColombiaBogotá - Ciencias - Maestría en Ciencias - QuímicaFacultad de CienciasBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá540 - Química y ciencias afines::543 - Química analíticaMetrologíaCationesmetrologycationsSuelosMaterial de referenciaComparabilidadCorrelacionesElementos disponiblesSoilsReference materialComparabilityCorrelationsSoil available elementsDesarrollo de herramientas metrológicas para la medición de aniones y cationes en suelosDevelopment of metrological tools for the measurement of anions and cations in soilsTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TM[1] N. 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Available: https://www.bipm.org/documents/20126/28432509/working-document-ID-11268/6eae4b21-bb0a-db3e-372a-86398d0f107a[17] V. J. Barwick, Ed., Eurachem Guide: Terminology in Analytical Measurement - Introduction to VIM 3, Second edition. 2023. [Online]. Available: www.eurachem.org.[18] Eurolab España. and PP Morillas y colaboradores, Eds., Guía Eurachem: La Adecuación al Uso de los Métodos Analíticos - Una guía de laboratorio para la validación de métodos y temes relacionados, Primera edición. 2016. Accessed: Jan. 19, 2023. [Online]. Available: www.eurachem.org[19] Eurachem Method Validation Working Group, The fitness for purpose of analytical methods : a laboratory guide to method validation and related topics. 2014. Accessed: Jul. 19, 2023. [Online]. Available: https://www.eurachem.org/images/stories/Guides/pdf/MV_guide_2nd_ed_EN.pdf[20] D. Ahumada, C. Paredes, J. Abella, and I. González, Validación de Métodos en Análisis Químico Cuantitativo. Instituto Nacional de Metrología, 2023. Accessed: Feb. 21, 2023. [Online]. Available: https://inm.gov.co/web/wp-content/uploads/2023/05/Guia_ValidacionMetodosAnalisisQuimicoCuantitativo-16.pdf[21] JCGM, “International Vocabulary of Metrology Fourth edition,” Joint Committee for Guides in Metrology, no. January, pp. 1–55, 2021.[22] H. Kipphardt, R. Matschat, and U. Panne, “Metrology in chemistry - A rocky road,” Microchimica Acta, vol. 162, no. 1–2, pp. 35–41, 2008, doi: 10.1007/s00604-007-0909-6.[23] G. Dube, “Metrology in chemistry - A public task,” Accreditation and Quality Assurance, vol. 6, no. 1, pp. 3–7, 2001, doi: 10.1007/PL00010431.[24] R. 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