Desarrollo de materiales carbonosos obtenidos por transformación termoquímica de residuos industriales para la producción de agua dulce a partir de la deshumidificación del aire
ilustraciones, gráficos
- Autores:
-
Galeano Caro, Dahiana
- Tipo de recurso:
- Fecha de publicación:
- 2024
- Institución:
- Universidad Nacional de Colombia
- Repositorio:
- Universidad Nacional de Colombia
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.unal.edu.co:unal/85892
- Palabra clave:
- 620 - Ingeniería y operaciones afines::628 - Ingeniería sanitaria
Agua potable
Residuos industriales
Carbón activado
Adsorción
Procesos de potabilización del agua
Acidificación superficial
Adsorción
Carbones activados
PET
Producción de agua dulce
Activated carbons
Adsorption
Freshwater production
Surface acidification
- Rights
- openAccess
- License
- Atribución-NoComercial-SinDerivadas 4.0 Internacional
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| dc.title.spa.fl_str_mv |
Desarrollo de materiales carbonosos obtenidos por transformación termoquímica de residuos industriales para la producción de agua dulce a partir de la deshumidificación del aire |
| dc.title.translated.eng.fl_str_mv |
Development of carbonaceous materials obtained by thermochemical transformation of industrial waste for freshwater production from air dehumidification |
| title |
Desarrollo de materiales carbonosos obtenidos por transformación termoquímica de residuos industriales para la producción de agua dulce a partir de la deshumidificación del aire |
| spellingShingle |
Desarrollo de materiales carbonosos obtenidos por transformación termoquímica de residuos industriales para la producción de agua dulce a partir de la deshumidificación del aire 620 - Ingeniería y operaciones afines::628 - Ingeniería sanitaria Agua potable Residuos industriales Carbón activado Adsorción Procesos de potabilización del agua Acidificación superficial Adsorción Carbones activados PET Producción de agua dulce Activated carbons Adsorption Freshwater production Surface acidification |
| title_short |
Desarrollo de materiales carbonosos obtenidos por transformación termoquímica de residuos industriales para la producción de agua dulce a partir de la deshumidificación del aire |
| title_full |
Desarrollo de materiales carbonosos obtenidos por transformación termoquímica de residuos industriales para la producción de agua dulce a partir de la deshumidificación del aire |
| title_fullStr |
Desarrollo de materiales carbonosos obtenidos por transformación termoquímica de residuos industriales para la producción de agua dulce a partir de la deshumidificación del aire |
| title_full_unstemmed |
Desarrollo de materiales carbonosos obtenidos por transformación termoquímica de residuos industriales para la producción de agua dulce a partir de la deshumidificación del aire |
| title_sort |
Desarrollo de materiales carbonosos obtenidos por transformación termoquímica de residuos industriales para la producción de agua dulce a partir de la deshumidificación del aire |
| dc.creator.fl_str_mv |
Galeano Caro, Dahiana |
| dc.contributor.advisor.none.fl_str_mv |
Cortés Correa, Farid Bernardo |
| dc.contributor.author.none.fl_str_mv |
Galeano Caro, Dahiana |
| dc.contributor.researchgroup.spa.fl_str_mv |
Fenómenos de Superficie Michael Polanyi |
| dc.contributor.googlescholar.spa.fl_str_mv |
https://scholar.google.com/citations?user=feYIAEsAAAAJ&hl=es&oi=ao |
| dc.subject.ddc.spa.fl_str_mv |
620 - Ingeniería y operaciones afines::628 - Ingeniería sanitaria |
| topic |
620 - Ingeniería y operaciones afines::628 - Ingeniería sanitaria Agua potable Residuos industriales Carbón activado Adsorción Procesos de potabilización del agua Acidificación superficial Adsorción Carbones activados PET Producción de agua dulce Activated carbons Adsorption Freshwater production Surface acidification |
| dc.subject.lemb.none.fl_str_mv |
Agua potable Residuos industriales Carbón activado Adsorción Procesos de potabilización del agua |
| dc.subject.proposal.spa.fl_str_mv |
Acidificación superficial Adsorción Carbones activados PET Producción de agua dulce |
| dc.subject.proposal.eng.fl_str_mv |
Activated carbons Adsorption Freshwater production Surface acidification |
| description |
ilustraciones, gráficos |
| publishDate |
2024 |
| dc.date.accessioned.none.fl_str_mv |
2024-04-10T00:19:13Z |
| dc.date.available.none.fl_str_mv |
2024-04-10T00:19:13Z |
| dc.date.issued.none.fl_str_mv |
2024 |
| dc.type.spa.fl_str_mv |
Trabajo de grado - Maestría |
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info:eu-repo/semantics/masterThesis |
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info:eu-repo/semantics/acceptedVersion |
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DataPaper Image Text Other |
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http://purl.org/redcol/resource_type/TM |
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acceptedVersion |
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https://repositorio.unal.edu.co/handle/unal/85892 |
| dc.identifier.instname.spa.fl_str_mv |
Universidad Nacional de Colombia |
| dc.identifier.reponame.spa.fl_str_mv |
Repositorio Institucional Universidad Nacional de Colombia |
| dc.identifier.repourl.spa.fl_str_mv |
https://repositorio.unal.edu.co/ |
| url |
https://repositorio.unal.edu.co/handle/unal/85892 https://repositorio.unal.edu.co/ |
| identifier_str_mv |
Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia |
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spa |
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spa |
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LaReferencia |
| dc.relation.references.spa.fl_str_mv |
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Linares-Solano, and B. Rand, "Water adsorption on activated carbons: study of water adsorption in micro-and mesopores," The Journal of Physical Chemistry B, vol. 105, pp. 7998-8006, 2001. F. B. Cortes Correa, "Adsorción de agua en materiales compuestos y en zeolita," Facultad de Minas, 2009. M. R. Basila, "Hydrogen bonding interaction between adsorbate molecules and surface hydroxyl groups on silica," The Journal of Chemical Physics, vol. 35, pp. 1151-1158, 1961. W. Hertl and M. Hair, "Adsorption of water on silica," Nature, vol. 223, pp. 1150-1151, 1969. M. D. Donohue and G. L. Aranovich, "Classification of Gibbs adsorption isotherms," Advances in colloid and interface science, vol. 76, pp. 137-152, 1998. H. ShamsiJazeyi and T. Kaghazchi, "Investigation of nitric acid treatment of activated carbon for enhanced aqueous mercury removal," Journal of Industrial and Engineering Chemistry, vol. 16, pp. 852-858, 2010. J. Zawadzki, M. Wiśniewski, and K. Skowrońska, "Heterogeneous reactions of NO2 and NO–O2 on the surface of carbons," Carbon, vol. 41, pp. 235-246, 2003. G. Quezada, J. Saavedraa, and R. R. P. Toledoa, "SIMULACION MOLECULAR DE POLIACRILAMIDA ANIONICA EN PRESENCIA DE SALES." L. E. R. D. Mirón and M. E. L. Magaña, "¿ Qué sabemos del agua?." A. Ramírez, L. G. Navarro, and J. Conde Acevedo, "Degradación química del poli (etilen tereftalato)," Revista Colombiana de Química, vol. 39, pp. 321-331, 2010. R. Agarwal, J. Noh, J. Schwarz, and P. Davini, "Effect of surface acidity of activated carbon on hydrogen storage," Carbon, vol. 25, pp. 219-226, 1987 J. Nishino, "Adsorption of water vapor and carbon dioxide at carboxylic functional groups on the surface of coal," Fuel, vol. 80, pp. 757-764, 2001. T. Ohba, H. Kanoh, and K. Kaneko, "Structures and stability of water nanoclusters in hydrophobic nanospaces," Nano letters, vol. 5, pp. 227-230, 2005. E. W. Bittner, M. R. Smith, and B. C. 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Rodriguez de la Pava, "Moisture adsorption isotherms in yellow pitahaya (Selenicereusmegalanthus)," Dyna, vol. 78, pp. 7-14, 2011. F. B. CORTÉS, A. BETANCOURT, B. ROJANO, V. LÓPEZ, and E. Arenas, "Evaluación de las propiedades termodinámicas de sorción de la uchuva (physalis peruviana l.)," Biotecnología en el Sector Agropecuario y Agroindustrial, vol. 10, pp. 32-41, 2012. D. Shen, M. Bülow, F. Siperstein, M. Engelhard, and A. L. Myers, "Comparison of experimental techniques for measuring isosteric heat of adsorption," Adsorption, vol. 6, pp. 275-286, 2000. D. P. ASCHERI and S. BASTOS, "Propiedades de adsorción de agua de dos genotipos de arroz rojo," Engenharia Agrícola, vol. 35, pp. 134-143, 2015. T. Horikawa, Y. Zeng, D. Do, K.-I. Sotowa, and J. R. A. Avila, "On the isosteric heat of adsorption of non-polar and polar fluids on highly graphitized carbon black," Journal of colloid and interface science, vol. 439, pp. 1-6, 2015. M. Dubinin, "Water vapor adsorption and the microporous structures of carbonaceous adsorbents," Carbon, vol. 18, pp. 355-364, 1980. E. A. Taborda-Acevedo, W. J. Jurado, and F. B. Cortés, "Efecto de la temperatura en el proceso de adsorción de agua en Carbón sub-bituminoso colombiano," Boletín de Ciencias de la Tierra, pp. 57-64, 2016. P. Leuk, M. Schneeberger, U. Hirn, and W. Bauer, "Heat of sorption: a comparison between isotherm models and calorimeter measurements of wood pulp," Drying technology, vol. 34, pp. 563-573, 2016. |
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Atribución-NoComercial-SinDerivadas 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Cortés Correa, Farid Bernardo3b35826f8c2b2379b0289696615550a4Galeano Caro, Dahiana54eee3eda8cc70aae1ca972f020a8cfaFenómenos de Superficie Michael Polanyihttps://scholar.google.com/citations?user=feYIAEsAAAAJ&hl=es&oi=ao2024-04-10T00:19:13Z2024-04-10T00:19:13Z2024https://repositorio.unal.edu.co/handle/unal/85892Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, gráficosEl agua potable es un recurso indispensable para la humanidad. Sin embargo, en zonas de alto estrés hídrico es difícil encontrarlo en condiciones adecuadas para su consumo y uso. Por ello, el principal objetivo de este estudio es la producción de agua dulce a partir de la deshumidificación del aire utilizando carbones activados obtenidos a partir de residuos industriales para hacer frente a esta situación. Se sinterizaron carbones activados a partir de la transformación termoquímica de residuos de tereftalato de polietileno (PET) y su desempeño se comparó con carbones activados comerciales sintetizados a partir de residuos agroindustriales de café y coco. Adicionalmente, los carbones fueron modificados superficialmente con ácido nítrico para mejorar su afinidad por compuestos polares. Los materiales fueron caracterizados profundamente a través de microscopía electrónica de barrido (SEM), espectroscopia de fotoemisión de rayos (XPS), espectroscopia Raman y adsorción de nitrógeno. Los resultados mostraron materiales con área superficial de hasta 1313 m2‧g-1 para aquellos sin acidificación superficial. Mientras que, aquellos modificados superficialmente disminuyeron su área superficial hasta en un 65% para los materiales sintetizados a partir de residuos de café y coco, y del 5% para aquellos sintetizados a partir de residuos PET. La acidificación superficial de los carbones permitió la exhibición de múltiples grupos oxigenados y nitrogenados, lo cual maximizó la interacción con las moléculas de agua a través de la formación de puentes de hidrógeno. Las isotermas de adsorción de agua sobre los carbones activados a 20 °C tuvieron un comportamiento Tipo IV según la clasificación de la Unión Internacional de Química Pura y Aplicada (IUPAC), mientras que, para temperaturas de 30 y 40 °C se obtuvieron isotermas tipo I. La máxima capacidad adsortiva fue de 1.55 g‧g-1 para el material P800N (carbón activado carbonizado hasta una temperatura de 800 °C y modificado superficialmente con ácido nítrico) para una humedad relativa del 84% y una temperatura de 20 °C. El proceso se puede definir como espontáneo y exotérmico según las propiedades termodinámicas de la sorción. Para las pruebas de campo se diseñó un prototipo para evaluación en Medellín, Antioquía, Colombia. Durante la prueba de campo, la sorción/captura de agua se realizó durante la noche, mientras que la liberación y producción de agua se produjo durante el día con uso exclusivo de energía solar. La humedad relativa promedio durante la etapa de adsorción fue de 80%, mientras que la velocidad del viento fue de 2.3 m‧s-1 y la temperatura fue de 20.7 °C. Durante la etapa de desorción la temperatura promedia fue de 26.2°C. La productividad del agua fue igual a 0.9 g de agua condensada por g de material seco. Estos resultados indican que los materiales sintetizados pueden producir agua de manera eficiente en áreas desafiantes en el marco de una economía circular, contribuyendo a la sostenibilidad y el bienestar social en zonas con alta escases hídrica. (Tomado de la fuente)Access to drinking water is a vital necessity for humanity. However, finding water in suitable conditions for consumption and use is challenging, particularly in areas experiencing high-water stress. The primary objective of this study is to address this issue by producing fresh water through air dehumidification using activated carbons derived from industrial waste. Commercial activated carbons, synthesized from agro-industrial coffee and coconut waste, as well as activated carbons synthesized from the thermochemical transformation of polyethylene terephthalate (PET) waste, underwent thorough characterization through techniques such as scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and nitrogen. The results showed materials with a surface area of up to 1313 m2‧g-1 for those without surface acidification. Meanwhile, those superficially modified decreased their surface area by up to 65% for materials synthesized from coffee and coconut waste and 5% for those synthesized from PET waste. The surface acidification of the coals allowed the display of multiple oxygenated and nitrogenous groups, which maximized the interaction with water molecules by forming hydrogen bonds. The water isotherms on the activated carbons at 20 °C had Type IV behavior according to the International Union of Pure and Applied Chemistry (IUPAC) classification. In contrast, type I isotherms were obtained for 30 and 40 °C temperatures. The maximum adsorptive capacity was 1.55 g‧g-1 for the P800N material (activated carbon carbonized up to a temperature of 800 °C and surface modified with nitric acid) with a relative humidity of 84% and a temperature of 20 °C. The process can be defined as spontaneous and exothermic according to the thermodynamic properties of the sorption. For field tests, a prototype was designed for evaluation in Medellín, Antioquia, Colombia. During the field test, water sorption/capture occurred at night, while water release and production occurred during the day with the exclusive use of solar energy. The average relative humidity during the adsorption stage was 80%, while the wind speed was 2.3 m‧s-1, and the temperature was 20.7 °C. During the desorption stage, the average temperature was 26.2°C. The water productivity was equal to 0.9 g of condensed water per g of dry material. These results indicate that the synthesized materials can efficiently produce water in challenging areas within the framework of a circular economy, contributing to sustainability and social well-being in areas with high water scarcity.MaestríaMagíster en Ingeniería - Ingeniería QuímicaAdsorción, nanotecnologíaIngeniería Química E Ingeniería De Petróleos.Sede Medellín59 páginasapplication/pdfspaUniversidad Nacional de ColombiaMedellín - Minas - Maestría en Ingeniería - Ingeniería QuímicaFacultad de MinasMedellín, ColombiaUniversidad Nacional de Colombia - Sede Medellín620 - Ingeniería y operaciones afines::628 - Ingeniería sanitariaAgua potableResiduos industrialesCarbón activadoAdsorciónProcesos de potabilización del aguaAcidificación superficialAdsorciónCarbones activadosPETProducción de agua dulceActivated carbonsAdsorptionFreshwater productionSurface acidificationDesarrollo de materiales carbonosos obtenidos por transformación termoquímica de residuos industriales para la producción de agua dulce a partir de la deshumidificación del aireDevelopment of carbonaceous materials obtained by thermochemical transformation of industrial waste for freshwater production from air dehumidificationTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionDataPaperImageTextOtherhttp://purl.org/redcol/resource_type/TMLaReferenciaW. 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Bauer, "Heat of sorption: a comparison between isotherm models and calorimeter measurements of wood pulp," Drying technology, vol. 34, pp. 563-573, 2016.EstudiantesInvestigadoresMaestrosPúblico generalLICENSElicense.txtlicense.txttext/plain; charset=utf-85879https://repositorio.unal.edu.co/bitstream/unal/85892/3/license.txteb34b1cf90b7e1103fc9dfd26be24b4aMD53ORIGINAL1098779289.2024.pdf1098779289.2024.pdfTesis de maestría en Ingenieríaapplication/pdf2765081https://repositorio.unal.edu.co/bitstream/unal/85892/4/1098779289.2024.pdfe3c9099bcc4fc36eed6623c6faa8434fMD54THUMBNAIL1098779289.2024.pdf.jpg1098779289.2024.pdf.jpgGenerated Thumbnailimage/jpeg8006https://repositorio.unal.edu.co/bitstream/unal/85892/5/1098779289.2024.pdf.jpga672b009c8c10c3b3783a5c7177b8000MD55unal/85892oai:repositorio.unal.edu.co:unal/858922024-04-09 23:05:31.512Repositorio Institucional Universidad Nacional de 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