Chemical modeling of methanol as an extragalactic shock tracer

ilustraciones, diagramas

Autores:: Méndez Robayo, Eva Juliana

Tipo de recurso:

Fecha de publicación:: 2024

Institución:: Universidad Nacional de Colombia

Repositorio:: Universidad Nacional de Colombia

Idioma:: eng

id	UNACIONAL2_1bba2b51b1879d48aa0a7a8f494bea29
oai_identifier_str	oai:repositorio.unal.edu.co:unal/85957
network_acronym_str	UNACIONAL2
network_name_str	Universidad Nacional de Colombia
repository_id_str
dc.title.eng.fl_str_mv	Chemical modeling of methanol as an extragalactic shock tracer
dc.title.translated.spa.fl_str_mv	Modelamiento químico del metanol como trazador de choques extragalácticos
title	Chemical modeling of methanol as an extragalactic shock tracer
spellingShingle	Chemical modeling of methanol as an extragalactic shock tracer 520 - Astronomía y ciencias afines::522 - Técnicas, procedimientos, aparatos, equipos, materiales Astrochemistry Molecules Shock waves Active Galactic Nuclei Quantum tunneling Astroquímica Moléculas Túnelamiento cuántico Ondas de choque Núcleo activo de galaxia Astrofísica Química experimental Modelo de simulación Astrophysics Experimental chemistry Simulation models
title_short	Chemical modeling of methanol as an extragalactic shock tracer
title_full	Chemical modeling of methanol as an extragalactic shock tracer
title_fullStr	Chemical modeling of methanol as an extragalactic shock tracer
title_full_unstemmed	Chemical modeling of methanol as an extragalactic shock tracer
title_sort	Chemical modeling of methanol as an extragalactic shock tracer
dc.creator.fl_str_mv	Méndez Robayo, Eva Juliana
dc.contributor.advisor.spa.fl_str_mv	Higuera Garzón, Mario Armando Huang, Ko-Yun
dc.contributor.author.spa.fl_str_mv	Méndez Robayo, Eva Juliana
dc.contributor.researcher.spa.fl_str_mv	Viti, Serena
dc.contributor.researchgroup.spa.fl_str_mv	Molecular Astrophysics Group - Universiteit Leiden and University College London Grupo SAGAN - Universidad Nacional de Colombia
dc.contributor.orcid.spa.fl_str_mv	Higuera Garzón, Mario Armando [0000-0001-6617-1046] Viti, Serena [0000-0001-8504-8844] Huang, Ko-Yun [0000-0002-1227-8435]
dc.subject.ddc.spa.fl_str_mv	520 - Astronomía y ciencias afines::522 - Técnicas, procedimientos, aparatos, equipos, materiales
topic	520 - Astronomía y ciencias afines::522 - Técnicas, procedimientos, aparatos, equipos, materiales Astrochemistry Molecules Shock waves Active Galactic Nuclei Quantum tunneling Astroquímica Moléculas Túnelamiento cuántico Ondas de choque Núcleo activo de galaxia Astrofísica Química experimental Modelo de simulación Astrophysics Experimental chemistry Simulation models
dc.subject.proposal.eng.fl_str_mv	Astrochemistry Molecules Shock waves Active Galactic Nuclei Quantum tunneling
dc.subject.proposal.spa.fl_str_mv	Astroquímica Moléculas Túnelamiento cuántico Ondas de choque Núcleo activo de galaxia
dc.subject.unesco.spa.fl_str_mv	Astrofísica Química experimental Modelo de simulación
dc.subject.unesco.eng.fl_str_mv	Astrophysics Experimental chemistry Simulation models
description	ilustraciones, diagramas
publishDate	2024
dc.date.accessioned.none.fl_str_mv	2024-04-23T01:54:39Z
dc.date.available.none.fl_str_mv	2024-04-23T01:54:39Z
dc.date.issued.none.fl_str_mv	2024
dc.type.spa.fl_str_mv	Trabajo de grado - Maestría
dc.type.driver.spa.fl_str_mv	info:eu-repo/semantics/masterThesis
dc.type.version.spa.fl_str_mv	info:eu-repo/semantics/acceptedVersion
dc.type.content.spa.fl_str_mv	Text
dc.type.redcol.spa.fl_str_mv	http://purl.org/redcol/resource_type/TM
status_str	acceptedVersion
dc.identifier.uri.none.fl_str_mv	https://repositorio.unal.edu.co/handle/unal/85957
dc.identifier.instname.spa.fl_str_mv	Universidad Nacional de Colombia
dc.identifier.reponame.spa.fl_str_mv	Repositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourl.spa.fl_str_mv	https://repositorio.unal.edu.co/
url	https://repositorio.unal.edu.co/handle/unal/85957 https://repositorio.unal.edu.co/
identifier_str_mv	Universidad Nacional de Colombia Repositorio Institucional Universidad Nacional de Colombia
dc.language.iso.spa.fl_str_mv	eng
language	eng
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dc.format.extent.spa.fl_str_mv	82 páginas
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dc.publisher.spa.fl_str_mv	Universidad Nacional de Colombia
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institution	Universidad Nacional de Colombia
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spelling	Atribución-NoComercial 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Higuera Garzón, Mario Armandoa12f46c538561a02747286f0cf279f63Huang, Ko-Yun622b2be00feeb1cddc304256f6d7a7f5600Méndez Robayo, Eva Juliana02aa73d1f78af57b3e825af4f278c703Viti, SerenaMolecular Astrophysics Group - Universiteit Leiden and University College LondonGrupo SAGAN - Universidad Nacional de ColombiaHiguera Garzón, Mario Armando [0000-0001-6617-1046]Viti, Serena [0000-0001-8504-8844]Huang, Ko-Yun [0000-0002-1227-8435]2024-04-23T01:54:39Z2024-04-23T01:54:39Z2024https://repositorio.unal.edu.co/handle/unal/85957Universidad Nacional de ColombiaRepositorio Institucional Universidad Nacional de Colombiahttps://repositorio.unal.edu.co/ilustraciones, diagramasThe behavior of methanol (CH3OH) in the composite galaxy NGC 1068 was analyzed to investigate its effectiveness as an extragalactic shock tracer and to study the effect of shock velocity and formation routes on the predicted interstellar abundance of CH3OH. With a parameterized C-shock physical model, C-shock chemistry was investigated with UCLCHEM to study the chemical abundance of CH3OH as a function of time in different locations of the Circumnuclear Disc (CND) near the Active Galactic Nuclei (AGN) and the Starburst (SB) ring of NGC 1068. It is concluded that gas-phase methanol can trace C-type shocks as its abundance increases significantly due to ice-dust grain sputtering or sublimation during shock propagation. This increase in the abundance of gaseous methanol is comparable from both low- (∼10 km/s) and high- (∼50 km/s) velocity shocks. Comparing our models with the multi-line molecular observations and analysis performed by Huang et al. (submitted), we concluded that the observed CH3OH abundance may result from C-shock influence or from thermal sublimation of ice due to protostellar core heating, as both models can account for the observed CH3OH in the gas phase. This work also demonstrated for the first time that the primary reaction leading to the formation of methanol in interstellar ice-dust grains is the radical-molecule H-atom abstraction route under shocked-influenced environments, such as the CND of NGC 1068, from the modeling point of view. This finding is consistent with the results of Simons et al. (2020) and Santos et al. (2022) in dark molecular clouds. However, its dominance is dependent on the gas kinetic temperature (Tk), gas volume density (nH2 ), velocity of the C-shock wave (vshock), and cosmic ray ionisation rate (ζ).Se analizó el comportamiento del metanol (CH3OH) en la galaxia compuesta NGC 1068 para investigar su eficacia como trazador de choques extragalácticos y estudiar el efecto de la velocidad del choque y las rutas de formación sobre la abundancia interestelar prevista de CH3OH. Con un modelo físico parametrizado de choque tipo C, se investigó la química del choque con UCLCHEM para estudiar la abundancia química de CH3OH en función del tiempo en diferentes localizaciones del Disco Circumnuclear (CND) cerca del Núcleo Activo de Galaxia (AGN) y del anillo Starburst (SB) de NGC 1068. Se concluye que el metanol en fase gaseosa puede rastrear choques de tipo C, ya que su abundancia aumenta significati- vamente debido a la pulverización o sublimación de granos helados durante la propagación del choque. Este aumento en la abundancia de metanol gaseoso es comparable para choques de baja (∼10 km/s) y alta velocidad (∼50 km/s). Comparando nuestros modelos con las observaciones moleculares multilíneares y los análisis realizados por Huang et al. (remetido), llegamos a la conclusión de que la abundancia observada de CH3OH puede deberse a la influencia del choque tipo C o a la sublimación térmica del hielo debido al calentamiento del núcleo protoestelar, ya que ambos modelos pueden explicar la abundancia observada de CH3OH en fase gaseosa. Este trabajo también mostró por primera vez que la reacción primaria que conduce a la formación de metanol en los granos de polvo interestelar es la vía de abstracción de átomos de H en entornos influenciados por choques, como el CND de NGC 1068, desde el punto de vista del modelamiento. Este hallazgo concuerda con los re- sultados de Simons et al. (2020) y Santos et al. (2022) en nubes moleculares oscuras. Sin embargo, su predominio depende de la temperatura cinética del gas (Tk), la densidad volumétrica del gas (nH2), la velocidad de la onda de choque (vshock) y la tasa de ionización de rayos cósmicos (ζ). (Texto tomado de la fuente).MaestríaMagíster en Ciencias - AstronomíaAstrochemistry and Active Galactic Nuclei82 páginasapplication/pdfengUniversidad Nacional de ColombiaBogotá - Ciencias - Maestría en Ciencias - AstronomíaFacultad de CienciasBogotá, ColombiaUniversidad Nacional de Colombia - Sede Bogotá520 - Astronomía y ciencias afines::522 - Técnicas, procedimientos, aparatos, equipos, materialesAstrochemistryMoleculesShock wavesActive Galactic NucleiQuantum tunnelingAstroquímicaMoléculasTúnelamiento cuánticoOndas de choqueNúcleo activo de galaxiaAstrofísicaQuímica experimentalModelo de simulaciónAstrophysicsExperimental chemistrySimulation modelsChemical modeling of methanol as an extragalactic shock tracerModelamiento químico del metanol como trazador de choques extragalácticosTrabajo de grado - Maestríainfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/acceptedVersionTexthttp://purl.org/redcol/resource_type/TMAikawa, Yuri ; Herbst, Eric ; Roberts, Helen ; Caselli, Paola: Molecular Evolution in Collapsing Prestellar Cores. 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Chemical modeling of methanol as an extragalactic shock tracer

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