Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicides

Four methodologies were evaluated for the determination of ethylenethiourea and propylenethiourea in fruits and vegetables. An extraction method using a mixture of methanol:water 3:1 and subsequent clean up with liquid-liquid partition supported on extrelut was selected and optimized. Identification...

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Autores:
Guerrero, Jairo A.
Velandia, Yohanna
Tipo de recurso:
Article of journal
Fecha de publicación:
2013
Institución:
Universidad Nacional de Colombia
Repositorio:
Universidad Nacional de Colombia
Idioma:
spa
OAI Identifier:
oai:repositorio.unal.edu.co:unal/50219
Acceso en línea:
https://repositorio.unal.edu.co/handle/unal/50219
http://bdigital.unal.edu.co/44196/
Palabra clave:
Etilentiourea
propilentiourea
validación
HPLC
frutas y hortalizas
Ethylenethiourea
propylenethiourea
validation
HPLC
fruits and vegetables
Rights
openAccess
License
Atribución-NoComercial 4.0 Internacional
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oai_identifier_str oai:repositorio.unal.edu.co:unal/50219
network_acronym_str UNACIONAL2
network_name_str Universidad Nacional de Colombia
repository_id_str
spelling Atribución-NoComercial 4.0 InternacionalDerechos reservados - Universidad Nacional de Colombiahttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Guerrero, Jairo A.03bee73a-61ca-491c-b144-43fd5bd34765300Velandia, Yohanna1cc579c9-b2a6-42a1-8e03-43f68bc4c2b63002019-06-29T09:55:35Z2019-06-29T09:55:35Z2013https://repositorio.unal.edu.co/handle/unal/50219http://bdigital.unal.edu.co/44196/Four methodologies were evaluated for the determination of ethylenethiourea and propylenethiourea in fruits and vegetables. An extraction method using a mixture of methanol:water 3:1 and subsequent clean up with liquid-liquid partition supported on extrelut was selected and optimized. Identification and quantification was carried out using high-efficiency liquid chromatography with diode array detection. The validated methodology is specific and selective, with recoveries between 77,82% and 83,57% with coefficients of variation below 20% and detection limits between 0,003 and 0,006 mg.kg-1. Linearity parameters showed adequate results in the concentration range. The method is robust for the evaluated factors and matrix effect was not observed to any analyte in the whole concentration range tested. It was found traces of ethylenethiourea in one sample of tomato and propylenethiourea in one sample of potato.Se evaluaron cuatro metodologías para la determinación de etilentiourea y propilentiourea en frutas y hortalizas; se seleccionó y optimizó un método de extracción utilizando una mezcla metanol:agua 3:1 y posterior limpieza con partición liquido-líquido soportada sobre extrelut. La determinación y cuantificación se llevó a cabo utilizando cromatografía liquida de alta eficiencia con detección de arreglo de diodos. La metodología validada es específica y selectiva, con porcentajes de recuperación entre 77,82% y 83,57%, coeficientes de variación menores al 20% y límites de detección entre 0,003 y 0,006 mg.kg-1. Los parámetros estadísticos de linealidad mostraron resultados adecuados en los rangos de concentración evaluados. La metodología es robusta para las variables evaluadas y no se observó efecto matriz. Se encontraron trazas de etilentiourea y propilentiourea en una muestra de tomate y una muestra de papa, respectivamente.application/pdfspaUniversidad Nacional de Colombiahttp://revistas.unal.edu.co/index.php/rcolquim/article/view/45911Universidad Nacional de Colombia Revistas electrónicas UN Revista Colombiana de QuímicaRevista Colombiana de QuímicaRevista Colombiana de Química; Vol. 42, núm. 3 (2013): Versión preliminar; 344-364 2357-3791 0120-2804Guerrero, Jairo A. and Velandia, Yohanna (2013) Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicides. Revista Colombiana de Química; Vol. 42, núm. 3 (2013): Versión preliminar; 344-364 2357-3791 0120-2804 .Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicidesArtículo de revistainfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Texthttp://purl.org/redcol/resource_type/ARTEtilentioureapropilentioureavalidaciónHPLCfrutas y hortalizasEthylenethioureapropylenethioureavalidationHPLCfruits and vegetablesORIGINAL45911-222621-1-SM.pdfapplication/pdf319753https://repositorio.unal.edu.co/bitstream/unal/50219/1/45911-222621-1-SM.pdf8de7d7c845b555ceeaae6b071989ac48MD51THUMBNAIL45911-222621-1-SM.pdf.jpg45911-222621-1-SM.pdf.jpgGenerated Thumbnailimage/jpeg7999https://repositorio.unal.edu.co/bitstream/unal/50219/2/45911-222621-1-SM.pdf.jpg6f674e21fa94e056a941d9b42edf6073MD52unal/50219oai:repositorio.unal.edu.co:unal/502192023-12-14 23:05:48.781Repositorio Institucional Universidad Nacional de Colombiarepositorio_nal@unal.edu.co
dc.title.spa.fl_str_mv Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicides
title Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicides
spellingShingle Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicides
Etilentiourea
propilentiourea
validación
HPLC
frutas y hortalizas
Ethylenethiourea
propylenethiourea
validation
HPLC
fruits and vegetables
title_short Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicides
title_full Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicides
title_fullStr Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicides
title_full_unstemmed Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicides
title_sort Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicides
dc.creator.fl_str_mv Guerrero, Jairo A.
Velandia, Yohanna
dc.contributor.author.spa.fl_str_mv Guerrero, Jairo A.
Velandia, Yohanna
dc.subject.proposal.spa.fl_str_mv Etilentiourea
propilentiourea
validación
HPLC
frutas y hortalizas
Ethylenethiourea
propylenethiourea
validation
HPLC
fruits and vegetables
topic Etilentiourea
propilentiourea
validación
HPLC
frutas y hortalizas
Ethylenethiourea
propylenethiourea
validation
HPLC
fruits and vegetables
description Four methodologies were evaluated for the determination of ethylenethiourea and propylenethiourea in fruits and vegetables. An extraction method using a mixture of methanol:water 3:1 and subsequent clean up with liquid-liquid partition supported on extrelut was selected and optimized. Identification and quantification was carried out using high-efficiency liquid chromatography with diode array detection. The validated methodology is specific and selective, with recoveries between 77,82% and 83,57% with coefficients of variation below 20% and detection limits between 0,003 and 0,006 mg.kg-1. Linearity parameters showed adequate results in the concentration range. The method is robust for the evaluated factors and matrix effect was not observed to any analyte in the whole concentration range tested. It was found traces of ethylenethiourea in one sample of tomato and propylenethiourea in one sample of potato.
publishDate 2013
dc.date.issued.spa.fl_str_mv 2013
dc.date.accessioned.spa.fl_str_mv 2019-06-29T09:55:35Z
dc.date.available.spa.fl_str_mv 2019-06-29T09:55:35Z
dc.type.spa.fl_str_mv Artículo de revista
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dc.type.content.spa.fl_str_mv Text
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format http://purl.org/coar/resource_type/c_6501
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dc.identifier.uri.none.fl_str_mv https://repositorio.unal.edu.co/handle/unal/50219
dc.identifier.eprints.spa.fl_str_mv http://bdigital.unal.edu.co/44196/
url https://repositorio.unal.edu.co/handle/unal/50219
http://bdigital.unal.edu.co/44196/
dc.language.iso.spa.fl_str_mv spa
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dc.relation.spa.fl_str_mv http://revistas.unal.edu.co/index.php/rcolquim/article/view/45911
dc.relation.ispartof.spa.fl_str_mv Universidad Nacional de Colombia Revistas electrónicas UN Revista Colombiana de Química
Revista Colombiana de Química
dc.relation.ispartofseries.none.fl_str_mv Revista Colombiana de Química; Vol. 42, núm. 3 (2013): Versión preliminar; 344-364 2357-3791 0120-2804
dc.relation.references.spa.fl_str_mv Guerrero, Jairo A. and Velandia, Yohanna (2013) Evaluation of methodologies for the analysis of toxic degradation products of dithiocarbamates fungicides. Revista Colombiana de Química; Vol. 42, núm. 3 (2013): Versión preliminar; 344-364 2357-3791 0120-2804 .
dc.rights.spa.fl_str_mv Derechos reservados - Universidad Nacional de Colombia
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.rights.license.spa.fl_str_mv Atribución-NoComercial 4.0 Internacional
dc.rights.uri.spa.fl_str_mv http://creativecommons.org/licenses/by-nc/4.0/
dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv Atribución-NoComercial 4.0 Internacional
Derechos reservados - Universidad Nacional de Colombia
http://creativecommons.org/licenses/by-nc/4.0/
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
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dc.publisher.spa.fl_str_mv Universidad Nacional de Colombia
institution Universidad Nacional de Colombia
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