Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures

Global energy policies are undergoing a profound reorientation to provide a more secure, sustainable, and affordable system, moving towards net-zero emissions by 2050. Although investment in clean fuels is set to increase significantly in the coming years, parts of the fossil fuel system remain crit...

Full description

Autores:
Contreras Mateus, María Daniela
Tipo de recurso:
Doctoral thesis
Fecha de publicación:
2023
Institución:
Universidad Industrial de Santander
Repositorio:
Repositorio UIS
Idioma:
eng
OAI Identifier:
oai:noesis.uis.edu.co:20.500.14071/15521
Acceso en línea:
https://noesis.uis.edu.co/handle/20.500.14071/15521
https://noesis.uis.edu.co
Palabra clave:
Reología
Magnetoreología
Crudos pesados
Aseguramiento de flujo
Ferrofluidos
Rheology
Magnetorheology
Heavy Crude Oils
Flow Assurance
Ferrofluids
Rights
openAccess
License
Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)
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dc.title.none.fl_str_mv Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures
dc.title.english.none.fl_str_mv Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures
title Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures
spellingShingle Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures
Reología
Magnetoreología
Crudos pesados
Aseguramiento de flujo
Ferrofluidos
Rheology
Magnetorheology
Heavy Crude Oils
Flow Assurance
Ferrofluids
title_short Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures
title_full Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures
title_fullStr Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures
title_full_unstemmed Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures
title_sort Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures
dc.creator.fl_str_mv Contreras Mateus, María Daniela
dc.contributor.advisor.none.fl_str_mv Chaves Guerrero, Arlex
Sánchez, Francisco Homero
dc.contributor.author.none.fl_str_mv Contreras Mateus, María Daniela
dc.contributor.evaluator.none.fl_str_mv Torres Díaz, Isaac
Muraca, Diego
Mejía Ospino, Enrique
Molina Velasco, Daniel Ricardo
Sánchez Torres, Viviana
dc.subject.none.fl_str_mv Reología
Magnetoreología
Crudos pesados
Aseguramiento de flujo
Ferrofluidos
topic Reología
Magnetoreología
Crudos pesados
Aseguramiento de flujo
Ferrofluidos
Rheology
Magnetorheology
Heavy Crude Oils
Flow Assurance
Ferrofluids
dc.subject.keyword.none.fl_str_mv Rheology
Magnetorheology
Heavy Crude Oils
Flow Assurance
Ferrofluids
description Global energy policies are undergoing a profound reorientation to provide a more secure, sustainable, and affordable system, moving towards net-zero emissions by 2050. Although investment in clean fuels is set to increase significantly in the coming years, parts of the fossil fuel system remain critical to energy security, such as refineries to supply residual users of transportation fuels. In this context, unconventional hydrocarbons have been a major candidate for current and future oil production, since they exist in abundant quantity on Earth’s crust, representing nearly 70% of proven reserves. Accordingly, great attention has been fundamentally directed towards exploring the promising and growing nanotechnology modern era. Against this background, this thesis is framed in the theoretical and experimental study of the inclusion of ferrofluids in the matrix of heavy crude oils with the aim of proving the induction of magnetorheological effects, primarily focused on improving the flow properties of these complex fluids in pipeline transportation applications. Therefore, it has been demonstrated that the integration of nanoparticles plays a fundamental role as adsorbent and smart magnetically controllable agent, effectively modifying the rheological properties of heavy crude oils. Likewise, surface modification of nanoparticles by adsorption of asphaltenes supported the role of this fraction as facilitator in promoting the spontaneous formation of aggregates. The orientation of these aggregates could be manipulated using external magnetic fields to stimulate more favorable flow properties in heavy crude oils. These findings serve as a fundamental theoretical basis for the development of an innovative technological approach aimed at flow assurance of heavy crude oils.
publishDate 2023
dc.date.accessioned.none.fl_str_mv 2023-11-23T14:25:04Z
dc.date.available.none.fl_str_mv 2023-11-23T14:25:04Z
dc.date.created.none.fl_str_mv 2023-11-14
dc.date.issued.none.fl_str_mv 2023-11-14
dc.type.local.none.fl_str_mv Tesis/Trabajo de grado - Monografía - Doctorado
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dc.identifier.uri.none.fl_str_mv https://noesis.uis.edu.co/handle/20.500.14071/15521
dc.identifier.instname.none.fl_str_mv Universidad Industrial de Santander
dc.identifier.reponame.none.fl_str_mv Universidad Industrial de Santander
dc.identifier.repourl.none.fl_str_mv https://noesis.uis.edu.co
url https://noesis.uis.edu.co/handle/20.500.14071/15521
https://noesis.uis.edu.co
identifier_str_mv Universidad Industrial de Santander
dc.language.iso.none.fl_str_mv eng
language eng
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.license.none.fl_str_mv Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)
dc.rights.uri.none.fl_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
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dc.rights.accessrights.none.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.creativecommons.none.fl_str_mv Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
rights_invalid_str_mv Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)
http://creativecommons.org/licenses/by-nc-nd/4.0/
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Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
eu_rights_str_mv openAccess
dc.format.mimetype.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidad Industrial de Santander
dc.publisher.faculty.none.fl_str_mv Facultad de Ingeníerias Fisicoquímicas
dc.publisher.program.none.fl_str_mv Doctorado en Ingeniería Química
dc.publisher.school.none.fl_str_mv Escuela de Ingeniería Química
publisher.none.fl_str_mv Universidad Industrial de Santander
institution Universidad Industrial de Santander
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spelling Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/http://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)Chaves Guerrero, ArlexSánchez, Francisco HomeroContreras Mateus, María DanielaTorres Díaz, IsaacMuraca, DiegoMejía Ospino, EnriqueMolina Velasco, Daniel RicardoSánchez Torres, Viviana2023-11-23T14:25:04Z2023-11-23T14:25:04Z2023-11-142023-11-14https://noesis.uis.edu.co/handle/20.500.14071/15521Universidad Industrial de SantanderUniversidad Industrial de Santanderhttps://noesis.uis.edu.coGlobal energy policies are undergoing a profound reorientation to provide a more secure, sustainable, and affordable system, moving towards net-zero emissions by 2050. Although investment in clean fuels is set to increase significantly in the coming years, parts of the fossil fuel system remain critical to energy security, such as refineries to supply residual users of transportation fuels. In this context, unconventional hydrocarbons have been a major candidate for current and future oil production, since they exist in abundant quantity on Earth’s crust, representing nearly 70% of proven reserves. Accordingly, great attention has been fundamentally directed towards exploring the promising and growing nanotechnology modern era. Against this background, this thesis is framed in the theoretical and experimental study of the inclusion of ferrofluids in the matrix of heavy crude oils with the aim of proving the induction of magnetorheological effects, primarily focused on improving the flow properties of these complex fluids in pipeline transportation applications. Therefore, it has been demonstrated that the integration of nanoparticles plays a fundamental role as adsorbent and smart magnetically controllable agent, effectively modifying the rheological properties of heavy crude oils. Likewise, surface modification of nanoparticles by adsorption of asphaltenes supported the role of this fraction as facilitator in promoting the spontaneous formation of aggregates. The orientation of these aggregates could be manipulated using external magnetic fields to stimulate more favorable flow properties in heavy crude oils. These findings serve as a fundamental theoretical basis for the development of an innovative technological approach aimed at flow assurance of heavy crude oils.DoctoradoDoctor en Ingeniería QuímicaGlobal energy policies are undergoing a profound reorientation to provide a more secure, sustainable, and affordable system, moving towards net-zero emissions by 2050. Although investment in clean fuels is set to increase significantly in the coming years, parts of the fossil fuel system remain critical to energy security, such as refineries to supply residual users of transportation fuels. In this context, unconventional hydrocarbons have been a major candidate for current and future oil production, since they exist in abundant quantity on Earth’s crust, representing nearly 70% of proven reserves. Accordingly, great attention has been fundamentally directed towards exploring the promising and growing nanotechnology modern era. Against this background, this thesis is framed in the theoretical and experimental study of the inclusion of ferrofluids in the matrix of heavy crude oils with the aim of proving the induction of magnetorheological effects, primarily focused on improving the flow properties of these complex fluids in pipeline transportation applications. Therefore, it has been demonstrated that the integration of nanoparticles plays a fundamental role as adsorbent and smart magnetically controllable agent, effectively modifying the rheological properties of heavy crude oils. Likewise, surface modification of nanoparticles by adsorption of asphaltenes supported the role of this fraction as facilitator in promoting the spontaneous formation of aggregates. The orientation of these aggregates could be manipulated using external magnetic fields to stimulate more favorable flow properties in heavy crude oils. These findings serve as a fundamental theoretical basis for the development of an innovative technological approach aimed at flow assurance of heavy crude oils.https://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0001634796https://orcid.org/0000-0002-6798-5719application/pdfengUniversidad Industrial de SantanderFacultad de Ingeníerias FisicoquímicasDoctorado en Ingeniería QuímicaEscuela de Ingeniería QuímicaReologíaMagnetoreologíaCrudos pesadosAseguramiento de flujoFerrofluidosRheologyMagnetorheologyHeavy Crude OilsFlow AssuranceFerrofluidsStudy of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids MixturesStudy of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids MixturesTesis/Trabajo de grado - Monografía - Doctoradohttp://purl.org/coar/version/c_b1a7d7d4d402bccehttp://purl.org/coar/resource_type/c_db06ORIGINALDocumento.pdfDocumento.pdfapplication/pdf7400067https://noesis.uis.edu.co/bitstreams/adf94ee1-dfdc-4505-8398-f9bae760c164/download6ae41ca33ef5f7cca2f368bd154f6126MD51Nota de proyecto.pdfNota de proyecto.pdfapplication/pdf114703https://noesis.uis.edu.co/bitstreams/ea990e7f-4f99-4701-8f65-445e5c32a345/downloaddbb2471cc5c8dace92b2393b39e81821MD52Carta de autorización.pdfCarta de autorización.pdfapplication/pdf121735https://noesis.uis.edu.co/bitstreams/74f8b660-9309-4d5f-b7ef-bf461898b529/download6e74be92256bfb973449c687edc607e0MD54LICENSElicense.txtlicense.txttext/plain; charset=utf-82237https://noesis.uis.edu.co/bitstreams/4e457c31-9e59-45db-a399-9d7e838197bf/downloadd6298274a8378d319ac744759540b71bMD5320.500.14071/15521oai:noesis.uis.edu.co:20.500.14071/155212023-11-23 09:25:06.914http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessopen.accesshttps://noesis.uis.edu.coDSpace at UISnoesis@uis.edu.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