Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures
Global energy policies are undergoing a profound reorientation to provide a more secure, sustainable, and affordable system, moving towards net-zero emissions by 2050. Although investment in clean fuels is set to increase significantly in the coming years, parts of the fossil fuel system remain crit...
- Autores:
-
Contreras Mateus, María Daniela
- Tipo de recurso:
- Doctoral thesis
- Fecha de publicación:
- 2023
- Institución:
- Universidad Industrial de Santander
- Repositorio:
- Repositorio UIS
- Idioma:
- eng
- OAI Identifier:
- oai:noesis.uis.edu.co:20.500.14071/15521
- Palabra clave:
- Reología
Magnetoreología
Crudos pesados
Aseguramiento de flujo
Ferrofluidos
Rheology
Magnetorheology
Heavy Crude Oils
Flow Assurance
Ferrofluids
- Rights
- openAccess
- License
- Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)
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dc.title.none.fl_str_mv |
Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures |
dc.title.english.none.fl_str_mv |
Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures |
title |
Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures |
spellingShingle |
Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures Reología Magnetoreología Crudos pesados Aseguramiento de flujo Ferrofluidos Rheology Magnetorheology Heavy Crude Oils Flow Assurance Ferrofluids |
title_short |
Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures |
title_full |
Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures |
title_fullStr |
Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures |
title_full_unstemmed |
Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures |
title_sort |
Study of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids Mixtures |
dc.creator.fl_str_mv |
Contreras Mateus, María Daniela |
dc.contributor.advisor.none.fl_str_mv |
Chaves Guerrero, Arlex Sánchez, Francisco Homero |
dc.contributor.author.none.fl_str_mv |
Contreras Mateus, María Daniela |
dc.contributor.evaluator.none.fl_str_mv |
Torres Díaz, Isaac Muraca, Diego Mejía Ospino, Enrique Molina Velasco, Daniel Ricardo Sánchez Torres, Viviana |
dc.subject.none.fl_str_mv |
Reología Magnetoreología Crudos pesados Aseguramiento de flujo Ferrofluidos |
topic |
Reología Magnetoreología Crudos pesados Aseguramiento de flujo Ferrofluidos Rheology Magnetorheology Heavy Crude Oils Flow Assurance Ferrofluids |
dc.subject.keyword.none.fl_str_mv |
Rheology Magnetorheology Heavy Crude Oils Flow Assurance Ferrofluids |
description |
Global energy policies are undergoing a profound reorientation to provide a more secure, sustainable, and affordable system, moving towards net-zero emissions by 2050. Although investment in clean fuels is set to increase significantly in the coming years, parts of the fossil fuel system remain critical to energy security, such as refineries to supply residual users of transportation fuels. In this context, unconventional hydrocarbons have been a major candidate for current and future oil production, since they exist in abundant quantity on Earth’s crust, representing nearly 70% of proven reserves. Accordingly, great attention has been fundamentally directed towards exploring the promising and growing nanotechnology modern era. Against this background, this thesis is framed in the theoretical and experimental study of the inclusion of ferrofluids in the matrix of heavy crude oils with the aim of proving the induction of magnetorheological effects, primarily focused on improving the flow properties of these complex fluids in pipeline transportation applications. Therefore, it has been demonstrated that the integration of nanoparticles plays a fundamental role as adsorbent and smart magnetically controllable agent, effectively modifying the rheological properties of heavy crude oils. Likewise, surface modification of nanoparticles by adsorption of asphaltenes supported the role of this fraction as facilitator in promoting the spontaneous formation of aggregates. The orientation of these aggregates could be manipulated using external magnetic fields to stimulate more favorable flow properties in heavy crude oils. These findings serve as a fundamental theoretical basis for the development of an innovative technological approach aimed at flow assurance of heavy crude oils. |
publishDate |
2023 |
dc.date.accessioned.none.fl_str_mv |
2023-11-23T14:25:04Z |
dc.date.available.none.fl_str_mv |
2023-11-23T14:25:04Z |
dc.date.created.none.fl_str_mv |
2023-11-14 |
dc.date.issued.none.fl_str_mv |
2023-11-14 |
dc.type.local.none.fl_str_mv |
Tesis/Trabajo de grado - Monografía - Doctorado |
dc.type.hasversion.none.fl_str_mv |
http://purl.org/coar/version/c_b1a7d7d4d402bcce |
dc.type.coar.none.fl_str_mv |
http://purl.org/coar/resource_type/c_db06 |
format |
http://purl.org/coar/resource_type/c_db06 |
dc.identifier.uri.none.fl_str_mv |
https://noesis.uis.edu.co/handle/20.500.14071/15521 |
dc.identifier.instname.none.fl_str_mv |
Universidad Industrial de Santander |
dc.identifier.reponame.none.fl_str_mv |
Universidad Industrial de Santander |
dc.identifier.repourl.none.fl_str_mv |
https://noesis.uis.edu.co |
url |
https://noesis.uis.edu.co/handle/20.500.14071/15521 https://noesis.uis.edu.co |
identifier_str_mv |
Universidad Industrial de Santander |
dc.language.iso.none.fl_str_mv |
eng |
language |
eng |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
dc.rights.license.none.fl_str_mv |
Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO) |
dc.rights.uri.none.fl_str_mv |
http://creativecommons.org/licenses/by-nc-nd/4.0/ |
dc.rights.coar.none.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
dc.rights.accessrights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
dc.rights.creativecommons.none.fl_str_mv |
Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0) |
rights_invalid_str_mv |
Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO) http://creativecommons.org/licenses/by-nc-nd/4.0/ http://purl.org/coar/access_right/c_abf2 Atribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0) |
eu_rights_str_mv |
openAccess |
dc.format.mimetype.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidad Industrial de Santander |
dc.publisher.faculty.none.fl_str_mv |
Facultad de Ingeníerias Fisicoquímicas |
dc.publisher.program.none.fl_str_mv |
Doctorado en Ingeniería Química |
dc.publisher.school.none.fl_str_mv |
Escuela de Ingeniería Química |
publisher.none.fl_str_mv |
Universidad Industrial de Santander |
institution |
Universidad Industrial de Santander |
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spelling |
Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/http://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)Chaves Guerrero, ArlexSánchez, Francisco HomeroContreras Mateus, María DanielaTorres Díaz, IsaacMuraca, DiegoMejía Ospino, EnriqueMolina Velasco, Daniel RicardoSánchez Torres, Viviana2023-11-23T14:25:04Z2023-11-23T14:25:04Z2023-11-142023-11-14https://noesis.uis.edu.co/handle/20.500.14071/15521Universidad Industrial de SantanderUniversidad Industrial de Santanderhttps://noesis.uis.edu.coGlobal energy policies are undergoing a profound reorientation to provide a more secure, sustainable, and affordable system, moving towards net-zero emissions by 2050. Although investment in clean fuels is set to increase significantly in the coming years, parts of the fossil fuel system remain critical to energy security, such as refineries to supply residual users of transportation fuels. In this context, unconventional hydrocarbons have been a major candidate for current and future oil production, since they exist in abundant quantity on Earth’s crust, representing nearly 70% of proven reserves. Accordingly, great attention has been fundamentally directed towards exploring the promising and growing nanotechnology modern era. Against this background, this thesis is framed in the theoretical and experimental study of the inclusion of ferrofluids in the matrix of heavy crude oils with the aim of proving the induction of magnetorheological effects, primarily focused on improving the flow properties of these complex fluids in pipeline transportation applications. Therefore, it has been demonstrated that the integration of nanoparticles plays a fundamental role as adsorbent and smart magnetically controllable agent, effectively modifying the rheological properties of heavy crude oils. Likewise, surface modification of nanoparticles by adsorption of asphaltenes supported the role of this fraction as facilitator in promoting the spontaneous formation of aggregates. The orientation of these aggregates could be manipulated using external magnetic fields to stimulate more favorable flow properties in heavy crude oils. These findings serve as a fundamental theoretical basis for the development of an innovative technological approach aimed at flow assurance of heavy crude oils.DoctoradoDoctor en Ingeniería QuímicaGlobal energy policies are undergoing a profound reorientation to provide a more secure, sustainable, and affordable system, moving towards net-zero emissions by 2050. Although investment in clean fuels is set to increase significantly in the coming years, parts of the fossil fuel system remain critical to energy security, such as refineries to supply residual users of transportation fuels. In this context, unconventional hydrocarbons have been a major candidate for current and future oil production, since they exist in abundant quantity on Earth’s crust, representing nearly 70% of proven reserves. Accordingly, great attention has been fundamentally directed towards exploring the promising and growing nanotechnology modern era. Against this background, this thesis is framed in the theoretical and experimental study of the inclusion of ferrofluids in the matrix of heavy crude oils with the aim of proving the induction of magnetorheological effects, primarily focused on improving the flow properties of these complex fluids in pipeline transportation applications. Therefore, it has been demonstrated that the integration of nanoparticles plays a fundamental role as adsorbent and smart magnetically controllable agent, effectively modifying the rheological properties of heavy crude oils. Likewise, surface modification of nanoparticles by adsorption of asphaltenes supported the role of this fraction as facilitator in promoting the spontaneous formation of aggregates. The orientation of these aggregates could be manipulated using external magnetic fields to stimulate more favorable flow properties in heavy crude oils. These findings serve as a fundamental theoretical basis for the development of an innovative technological approach aimed at flow assurance of heavy crude oils.https://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0001634796https://orcid.org/0000-0002-6798-5719application/pdfengUniversidad Industrial de SantanderFacultad de Ingeníerias FisicoquímicasDoctorado en Ingeniería QuímicaEscuela de Ingeniería QuímicaReologíaMagnetoreologíaCrudos pesadosAseguramiento de flujoFerrofluidosRheologyMagnetorheologyHeavy Crude OilsFlow AssuranceFerrofluidsStudy of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids MixturesStudy of the Magnetorheological Behavior and Magnetic-Induced Microstructure of Heavy Crude Oils and Ferrofluids MixturesTesis/Trabajo de grado - Monografía - Doctoradohttp://purl.org/coar/version/c_b1a7d7d4d402bccehttp://purl.org/coar/resource_type/c_db06ORIGINALDocumento.pdfDocumento.pdfapplication/pdf7400067https://noesis.uis.edu.co/bitstreams/adf94ee1-dfdc-4505-8398-f9bae760c164/download6ae41ca33ef5f7cca2f368bd154f6126MD51Nota de proyecto.pdfNota de proyecto.pdfapplication/pdf114703https://noesis.uis.edu.co/bitstreams/ea990e7f-4f99-4701-8f65-445e5c32a345/downloaddbb2471cc5c8dace92b2393b39e81821MD52Carta de autorización.pdfCarta de autorización.pdfapplication/pdf121735https://noesis.uis.edu.co/bitstreams/74f8b660-9309-4d5f-b7ef-bf461898b529/download6e74be92256bfb973449c687edc607e0MD54LICENSElicense.txtlicense.txttext/plain; charset=utf-82237https://noesis.uis.edu.co/bitstreams/4e457c31-9e59-45db-a399-9d7e838197bf/downloadd6298274a8378d319ac744759540b71bMD5320.500.14071/15521oai:noesis.uis.edu.co:20.500.14071/155212023-11-23 09:25:06.914http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessopen.accesshttps://noesis.uis.edu.coDSpace at UISnoesis@uis.edu.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 |