Characterization by temperature programmed techniques of spent and acid treated vanadium catalysts

RESUMEN: Muestras de V2O5/SiO2-γAl2O3 desactivado durante la producción de ácido sulfúrico se trataron con ácido con el fin de recuperar el vanadio. Los materiales se caracterizaron mediante técnicas de temperatura programada: TPR-H2, TPO-O2, TPD-NH3, y TGA-DTA con el fin de determinar el efecto de...

Full description

Autores:
González Rodríguez, Lina María
Montes de Correa, Consuelo
Tipo de recurso:
Article of investigation
Fecha de publicación:
2011
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/5404
Acceso en línea:
http://hdl.handle.net/10495/5404
Palabra clave:
Catalizadores
Vanadio
Rights
openAccess
License
Atribución-NoComercial-CompartirIgual 2.5 Colombia (CC BY-NC-SA 2.5 CO)
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oai_identifier_str oai:bibliotecadigital.udea.edu.co:10495/5404
network_acronym_str UDEA2
network_name_str Repositorio UdeA
repository_id_str
dc.title.spa.fl_str_mv Characterization by temperature programmed techniques of spent and acid treated vanadium catalysts
dc.title.alternative.spa.fl_str_mv Caracterización por técnicas de la temperatura programada de catalizadores de vanadio desactivados y tratados con ácido
title Characterization by temperature programmed techniques of spent and acid treated vanadium catalysts
spellingShingle Characterization by temperature programmed techniques of spent and acid treated vanadium catalysts
Catalizadores
Vanadio
title_short Characterization by temperature programmed techniques of spent and acid treated vanadium catalysts
title_full Characterization by temperature programmed techniques of spent and acid treated vanadium catalysts
title_fullStr Characterization by temperature programmed techniques of spent and acid treated vanadium catalysts
title_full_unstemmed Characterization by temperature programmed techniques of spent and acid treated vanadium catalysts
title_sort Characterization by temperature programmed techniques of spent and acid treated vanadium catalysts
dc.creator.fl_str_mv González Rodríguez, Lina María
Montes de Correa, Consuelo
dc.contributor.author.none.fl_str_mv González Rodríguez, Lina María
Montes de Correa, Consuelo
dc.subject.none.fl_str_mv Catalizadores
Vanadio
topic Catalizadores
Vanadio
description RESUMEN: Muestras de V2O5/SiO2-γAl2O3 desactivado durante la producción de ácido sulfúrico se trataron con ácido con el fin de recuperar el vanadio. Los materiales se caracterizaron mediante técnicas de temperatura programada: TPR-H2, TPO-O2, TPD-NH3, y TGA-DTA con el fin de determinar el efecto de las especies responsables de la desactivación en la recuperación del metal. Análisis por DRX y UV-Vis se utilizaron para confirmar algunas señales obtenidas en los perfiles de temperatura programada. Los resultados sugieren que la presencia de sulfovanadatos y óxidos de vanadio en las muestras tratadas hacen difícil recuperar más del 86% del vanadio presente en las muestras de catalizador.
publishDate 2011
dc.date.issued.none.fl_str_mv 2011
dc.date.accessioned.none.fl_str_mv 2016-11-18T01:26:53Z
dc.date.available.none.fl_str_mv 2016-11-18T01:26:53Z
dc.type.spa.fl_str_mv info:eu-repo/semantics/article
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dc.type.local.spa.fl_str_mv Artículo de investigación
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dc.identifier.citation.spa.fl_str_mv I. D. Charry, L. M. González and C. Montes, "haracterization by temperature programmed techniques of spent and acid treated vanadium catalysts", Rev. Fac. Ing. Univ. Antioquia, no. 57, pp. 31-37, 2011.
dc.identifier.issn.none.fl_str_mv 0120-6230
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/10495/5404
dc.identifier.eissn.none.fl_str_mv 2422-2844
identifier_str_mv I. D. Charry, L. M. González and C. Montes, "haracterization by temperature programmed techniques of spent and acid treated vanadium catalysts", Rev. Fac. Ing. Univ. Antioquia, no. 57, pp. 31-37, 2011.
0120-6230
2422-2844
url http://hdl.handle.net/10495/5404
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartofjournalabbrev.spa.fl_str_mv Rev. Fac. Ing. Univ. Antioquia
dc.rights.*.fl_str_mv Atribución-NoComercial-CompartirIgual 2.5 Colombia (CC BY-NC-SA 2.5 CO)
dc.rights.spa.fl_str_mv info:eu-repo/semantics/openAccess
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rights_invalid_str_mv Atribución-NoComercial-CompartirIgual 2.5 Colombia (CC BY-NC-SA 2.5 CO)
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dc.format.extent.spa.fl_str_mv 6
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dc.publisher.spa.fl_str_mv Universidad de Antioquia, Facultad de Ingeniería
dc.publisher.group.spa.fl_str_mv Catálisis Ambiental
dc.publisher.place.spa.fl_str_mv Medellín, Colombia
institution Universidad de Antioquia
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spelling González Rodríguez, Lina MaríaMontes de Correa, Consuelo2016-11-18T01:26:53Z2016-11-18T01:26:53Z2011I. D. Charry, L. M. González and C. Montes, "haracterization by temperature programmed techniques of spent and acid treated vanadium catalysts", Rev. Fac. Ing. Univ. Antioquia, no. 57, pp. 31-37, 2011.0120-6230http://hdl.handle.net/10495/54042422-2844RESUMEN: Muestras de V2O5/SiO2-γAl2O3 desactivado durante la producción de ácido sulfúrico se trataron con ácido con el fin de recuperar el vanadio. Los materiales se caracterizaron mediante técnicas de temperatura programada: TPR-H2, TPO-O2, TPD-NH3, y TGA-DTA con el fin de determinar el efecto de las especies responsables de la desactivación en la recuperación del metal. Análisis por DRX y UV-Vis se utilizaron para confirmar algunas señales obtenidas en los perfiles de temperatura programada. Los resultados sugieren que la presencia de sulfovanadatos y óxidos de vanadio en las muestras tratadas hacen difícil recuperar más del 86% del vanadio presente en las muestras de catalizador.ABSTRACT: Spent samples of V2O5/SiO2-γAl2O3 catalyst used for H2SO4 production were acid treated to recover vanadium. Fresh, spent, and acid treated samples were characterized by temperature-programmed techniques: TPR-H2, TPO-O2, TPD-NH3 and, TGA-DTA in order to determine the effect of deactivating species on vanadium recovery. DRX and UV-Vis techniques were used to confirm several signals from the temperature-programmed profiles. The results suggest that vanadium sulfovanadates and oxides in treated samples strongly interact with the support making it difficult to get more than 86% vanadium recovery.6application/pdfengUniversidad de Antioquia, Facultad de IngenieríaCatálisis AmbientalMedellín, Colombiainfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARTArtículo de investigaciónhttp://purl.org/coar/version/c_970fb48d4fbd8a86Atribución-NoComercial-CompartirIgual 2.5 Colombia (CC BY-NC-SA 2.5 CO)info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/co/http://purl.org/coar/access_right/c_abf2https://creativecommons.org/licenses/by-nc-sa/4.0/CatalizadoresVanadioCharacterization by temperature programmed techniques of spent and acid treated vanadium catalystsCaracterización por técnicas de la temperatura programada de catalizadores de vanadio desactivados y tratados con ácidoRev. Fac. Ing. Univ. AntioquiaRevista Facultad de Ingeniería Universidad de Antioquia313757ORIGINALCharryIran_2011_CharacterizationTemperatureProgrammed.pdfCharryIran_2011_CharacterizationTemperatureProgrammed.pdfArtículo de investigaciónapplication/pdf1938854http://bibliotecadigital.udea.edu.co/bitstream/10495/5404/1/CharryIran_2011_CharacterizationTemperatureProgrammed.pdfc264f3d58a7baf87821a981164e55e5eMD51CC-LICENSElicense_urllicense_urltext/plain; charset=utf-849http://bibliotecadigital.udea.edu.co/bitstream/10495/5404/2/license_url4afdbb8c545fd630ea7db775da747b2fMD52license_textlicense_texttext/html; charset=utf-80http://bibliotecadigital.udea.edu.co/bitstream/10495/5404/3/license_textd41d8cd98f00b204e9800998ecf8427eMD53license_rdflicense_rdfapplication/rdf+xml; charset=utf-80http://bibliotecadigital.udea.edu.co/bitstream/10495/5404/4/license_rdfd41d8cd98f00b204e9800998ecf8427eMD54LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://bibliotecadigital.udea.edu.co/bitstream/10495/5404/5/license.txt8a4605be74aa9ea9d79846c1fba20a33MD5510495/5404oai:bibliotecadigital.udea.edu.co:10495/54042021-04-23 15:23:47.834Repositorio Institucional Universidad de Antioquiaandres.perez@udea.edu.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