Exotic noble gas carbene-like ions
ABSTRACT: Using a combination of theoretical techniques, this work studies the Kr2C2+ species, which has electronic, structural, and some typical chemical characteristics of carbenes, and whose ground state is singlet. Similarly to the case of traditional carbenes, Kr2C2+ is metastable and appears t...
- Autores:
-
Moreno Prieto, Norberto
Restrepo Cossio, Albeiro Alonso
Hadad Arriagada, Cacier Zilahy
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2014
- Institución:
- Universidad de Antioquia
- Repositorio:
- Repositorio UdeA
- Idioma:
- eng
- OAI Identifier:
- oai:bibliotecadigital.udea.edu.co:10495/13362
- Acceso en línea:
- http://hdl.handle.net/10495/13362
- Palabra clave:
- Carbenes
Kr2C2+ is metastable
Theoretical techniques
Vibrational frequencies
- Rights
- openAccess
- License
- Atribución-NoComercial-SinDerivadas 2.5 Colombia
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Exotic noble gas carbene-like ions |
| title |
Exotic noble gas carbene-like ions |
| spellingShingle |
Exotic noble gas carbene-like ions Carbenes Kr2C2+ is metastable Theoretical techniques Vibrational frequencies |
| title_short |
Exotic noble gas carbene-like ions |
| title_full |
Exotic noble gas carbene-like ions |
| title_fullStr |
Exotic noble gas carbene-like ions |
| title_full_unstemmed |
Exotic noble gas carbene-like ions |
| title_sort |
Exotic noble gas carbene-like ions |
| dc.creator.fl_str_mv |
Moreno Prieto, Norberto Restrepo Cossio, Albeiro Alonso Hadad Arriagada, Cacier Zilahy |
| dc.contributor.author.none.fl_str_mv |
Moreno Prieto, Norberto Restrepo Cossio, Albeiro Alonso Hadad Arriagada, Cacier Zilahy |
| dc.subject.none.fl_str_mv |
Carbenes Kr2C2+ is metastable Theoretical techniques Vibrational frequencies |
| topic |
Carbenes Kr2C2+ is metastable Theoretical techniques Vibrational frequencies |
| description |
ABSTRACT: Using a combination of theoretical techniques, this work studies the Kr2C2+ species, which has electronic, structural, and some typical chemical characteristics of carbenes, and whose ground state is singlet. Similarly to the case of traditional carbenes, Kr2C2+ is metastable and appears to be a candidate for a reactive intermediate. |
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2014 |
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2014 |
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2020-01-18T12:32:17Z |
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2020-01-18T12:32:17Z |
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info:eu-repo/semantics/article |
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Artículo de investigación |
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Echeverri Cárdenas, A. S., Moreno Prieto, N., Restrepo A. A., & Hadad Arriagada, C. Z. (2014) Exotic noble gas carbene-like ions.Chemical Physics Letters, 615, 16-20.https://doi.org/10.1016/j.cplett.2014.09.059 |
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0009-2614 |
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http://hdl.handle.net/10495/13362 |
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Echeverri Cárdenas, A. S., Moreno Prieto, N., Restrepo A. A., & Hadad Arriagada, C. Z. (2014) Exotic noble gas carbene-like ions.Chemical Physics Letters, 615, 16-20.https://doi.org/10.1016/j.cplett.2014.09.059 0009-2614 |
| url |
http://hdl.handle.net/10495/13362 |
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eng |
| language |
eng |
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Atribución-NoComercial-SinDerivadas 2.5 Colombia |
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info:eu-repo/semantics/openAccess |
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http://creativecommons.org/licenses/by-nc-nd/2.5/co/ |
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openAccess |
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4 |
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Elsevier |
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Holanda |
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Universidad de Antioquia |
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Moreno Prieto, NorbertoRestrepo Cossio, Albeiro AlonsoHadad Arriagada, Cacier Zilahy2020-01-18T12:32:17Z2020-01-18T12:32:17Z2014Echeverri Cárdenas, A. S., Moreno Prieto, N., Restrepo A. A., & Hadad Arriagada, C. Z. (2014) Exotic noble gas carbene-like ions.Chemical Physics Letters, 615, 16-20.https://doi.org/10.1016/j.cplett.2014.09.0590009-2614http://hdl.handle.net/10495/13362ABSTRACT: Using a combination of theoretical techniques, this work studies the Kr2C2+ species, which has electronic, structural, and some typical chemical characteristics of carbenes, and whose ground state is singlet. Similarly to the case of traditional carbenes, Kr2C2+ is metastable and appears to be a candidate for a reactive intermediate.4application/pdfengElsevierHolandainfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARTArtículo de investigaciónhttp://purl.org/coar/version/c_970fb48d4fbd8a86http://purl.org/coar/version/c_970fb48d4fbd8a85Atribución-NoComercial-SinDerivadas 2.5 Colombiainfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/2.5/co/http://purl.org/coar/access_right/c_abf2https://creativecommons.org/licenses/by-nc-nd/4.0/CarbenesKr2C2+ is metastableTheoretical techniquesVibrational frequenciesExotic noble gas carbene-like ionsChemical Physics Letters1620615CC-LICENSElicense_urllicense_urltext/plain; charset=utf-849http://bibliotecadigital.udea.edu.co/bitstream/10495/13362/2/license_url4afdbb8c545fd630ea7db775da747b2fMD52license_textlicense_texttext/html; charset=utf-80http://bibliotecadigital.udea.edu.co/bitstream/10495/13362/3/license_textd41d8cd98f00b204e9800998ecf8427eMD53license_rdflicense_rdfapplication/rdf+xml; charset=utf-80http://bibliotecadigital.udea.edu.co/bitstream/10495/13362/4/license_rdfd41d8cd98f00b204e9800998ecf8427eMD54LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://bibliotecadigital.udea.edu.co/bitstream/10495/13362/5/license.txt8a4605be74aa9ea9d79846c1fba20a33MD55ORIGINALEcheverri Andrea_2014_Exoticnoblegascarbenelikeions.pdfEcheverri Andrea_2014_Exoticnoblegascarbenelikeions.pdfArtículo de investigaciónapplication/pdf796954http://bibliotecadigital.udea.edu.co/bitstream/10495/13362/1/Echeverri%20Andrea_2014_Exoticnoblegascarbenelikeions.pdf94113261757d85fc3269cd0f046775e3MD5110495/13362oai:bibliotecadigital.udea.edu.co:10495/133622021-06-17 15:32:21.214Repositorio Institucional Universidad de Antioquiaandres.perez@udea.edu.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 |