Cobalt supported on Zirconia. Selective catalytic reduction of NO using propane as reducing agent

ABSTRACT: The catalytic behavior of a series of cobalt catalysts supported on zirconia in the selective catalytic reduction (SCR) of NO has been studied using propane as reducing agent. The catalysts were characterized by Raman Spectroscopy, Temperature Programmed Reduction (TPR), Diffuse Reflectanc...

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Autores:
Villa Holguín, Aída Luz
Lick, Ileana Daniela
Gazzoli, Delia
Botto, Irma Lia
Soria, Delia Beatriz
Gonzalez, Maria Gloria
Ponzi, Esther Natalia
Tipo de recurso:
Article of investigation
Fecha de publicación:
2014
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/36310
Acceso en línea:
https://hdl.handle.net/10495/36310
Palabra clave:
Catalizadores metálicos
Metal catalysts
Cobalto
Cobalt
Environmental impact analysis
Evaluación del impacto ambiental
Combustión
Combustion
Óxido nítrico
Nitric oxide
Rights
openAccess
License
http://creativecommons.org/licenses/by-nc-sa/2.5/co/
id UDEA2_c45e14c793b6186c336431972e440866
oai_identifier_str oai:bibliotecadigital.udea.edu.co:10495/36310
network_acronym_str UDEA2
network_name_str Repositorio UdeA
repository_id_str
dc.title.spa.fl_str_mv Cobalt supported on Zirconia. Selective catalytic reduction of NO using propane as reducing agent
title Cobalt supported on Zirconia. Selective catalytic reduction of NO using propane as reducing agent
spellingShingle Cobalt supported on Zirconia. Selective catalytic reduction of NO using propane as reducing agent
Catalizadores metálicos
Metal catalysts
Cobalto
Cobalt
Environmental impact analysis
Evaluación del impacto ambiental
Combustión
Combustion
Óxido nítrico
Nitric oxide
title_short Cobalt supported on Zirconia. Selective catalytic reduction of NO using propane as reducing agent
title_full Cobalt supported on Zirconia. Selective catalytic reduction of NO using propane as reducing agent
title_fullStr Cobalt supported on Zirconia. Selective catalytic reduction of NO using propane as reducing agent
title_full_unstemmed Cobalt supported on Zirconia. Selective catalytic reduction of NO using propane as reducing agent
title_sort Cobalt supported on Zirconia. Selective catalytic reduction of NO using propane as reducing agent
dc.creator.fl_str_mv Villa Holguín, Aída Luz
Lick, Ileana Daniela
Gazzoli, Delia
Botto, Irma Lia
Soria, Delia Beatriz
Gonzalez, Maria Gloria
Ponzi, Esther Natalia
dc.contributor.author.none.fl_str_mv Villa Holguín, Aída Luz
Lick, Ileana Daniela
Gazzoli, Delia
Botto, Irma Lia
Soria, Delia Beatriz
Gonzalez, Maria Gloria
Ponzi, Esther Natalia
dc.contributor.researchgroup.spa.fl_str_mv Catálisis Ambiental
dc.subject.lemb.none.fl_str_mv Catalizadores metálicos
Metal catalysts
Cobalto
Cobalt
Environmental impact analysis
Evaluación del impacto ambiental
Combustión
Combustion
Óxido nítrico
Nitric oxide
topic Catalizadores metálicos
Metal catalysts
Cobalto
Cobalt
Environmental impact analysis
Evaluación del impacto ambiental
Combustión
Combustion
Óxido nítrico
Nitric oxide
description ABSTRACT: The catalytic behavior of a series of cobalt catalysts supported on zirconia in the selective catalytic reduction (SCR) of NO has been studied using propane as reducing agent. The catalysts were characterized by Raman Spectroscopy, Temperature Programmed Reduction (TPR), Diffuse Reflectance Spectroscopy UV-Vis (DRS) and X-ray Photoelectron Spectroscopy (XPS) to assess the physicochemical properties of cobalt species. Results for SCR of NO indicate that the activity is substantially related to the cobalt concentration and consequent nature of supported cobalt species. The formation of segregated oxidic phases on the catalytic surface produces an activity decrease. The most active catalyst contains Co(II) ions, interacting with the support, in tetrahedral coordination
publishDate 2014
dc.date.issued.none.fl_str_mv 2014
dc.date.accessioned.none.fl_str_mv 2023-08-22T19:04:15Z
dc.date.available.none.fl_str_mv 2023-08-22T19:04:15Z
dc.type.spa.fl_str_mv Artículo de investigación
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
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dc.identifier.citation.spa.fl_str_mv Lick, Ileana Daniela; Gazzoli, Delia; Botto, Irma Lia; Soria, Delia Beatriz; Villa, Aida Luz; et al.; Cobalt Supported on Zirconia: Selective Catalytic Reduction of NO Using Propane as Reducing Agent; Bentham Science Publishers; Current Catalysis; 3; 2; 11-2014; 179-186
dc.identifier.issn.none.fl_str_mv 2211-5447
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/10495/36310
dc.identifier.eissn.none.fl_str_mv 2211-5455
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identifier_str_mv Lick, Ileana Daniela; Gazzoli, Delia; Botto, Irma Lia; Soria, Delia Beatriz; Villa, Aida Luz; et al.; Cobalt Supported on Zirconia: Selective Catalytic Reduction of NO Using Propane as Reducing Agent; Bentham Science Publishers; Current Catalysis; 3; 2; 11-2014; 179-186
2211-5447
2211-5455
URL:https://www.ingentaconnect.com/content/ben/ccat/2014/00000003/00000002/art00011;
url https://hdl.handle.net/10495/36310
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.citationendpage.spa.fl_str_mv 186
dc.relation.citationstartpage.spa.fl_str_mv 179
dc.relation.citationvolume.spa.fl_str_mv 3
dc.relation.ispartofjournal.spa.fl_str_mv Current Catalysis
dc.rights.uri.*.fl_str_mv http://creativecommons.org/licenses/by-nc-sa/2.5/co/
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dc.publisher.spa.fl_str_mv Bentham Science Publishers
dc.publisher.place.spa.fl_str_mv Países Bajos
institution Universidad de Antioquia
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spelling Villa Holguín, Aída LuzLick, Ileana DanielaGazzoli, DeliaBotto, Irma LiaSoria, Delia BeatrizGonzalez, Maria GloriaPonzi, Esther NataliaCatálisis Ambiental2023-08-22T19:04:15Z2023-08-22T19:04:15Z2014Lick, Ileana Daniela; Gazzoli, Delia; Botto, Irma Lia; Soria, Delia Beatriz; Villa, Aida Luz; et al.; Cobalt Supported on Zirconia: Selective Catalytic Reduction of NO Using Propane as Reducing Agent; Bentham Science Publishers; Current Catalysis; 3; 2; 11-2014; 179-1862211-5447https://hdl.handle.net/10495/363102211-5455URL:https://www.ingentaconnect.com/content/ben/ccat/2014/00000003/00000002/art00011;ABSTRACT: The catalytic behavior of a series of cobalt catalysts supported on zirconia in the selective catalytic reduction (SCR) of NO has been studied using propane as reducing agent. The catalysts were characterized by Raman Spectroscopy, Temperature Programmed Reduction (TPR), Diffuse Reflectance Spectroscopy UV-Vis (DRS) and X-ray Photoelectron Spectroscopy (XPS) to assess the physicochemical properties of cobalt species. Results for SCR of NO indicate that the activity is substantially related to the cobalt concentration and consequent nature of supported cobalt species. The formation of segregated oxidic phases on the catalytic surface produces an activity decrease. The most active catalyst contains Co(II) ions, interacting with the support, in tetrahedral coordinationCOL00019418application/pdfengBentham Science PublishersPaíses Bajoshttp://creativecommons.org/licenses/by-nc-sa/2.5/co/https://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Cobalt supported on Zirconia. 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