Use of mesoporous silica as a reinforcing agent in rubber compounds
ABSTRACT: esoporous silica is used as filler for styrene-butadiene rubber (SBR); filler-polymer interactions are compared with those exhibited when Ultrasil silica (VN3) is used. A silane coupling agent is added to improve filler dispersion and its influence on the bound-rubber formation is also inv...
- Autores:
-
López Osorio, Betty Lucy
Pérez Pérez, León Dario
Mesa Cadavid, Mónica
Sierra García, Ligia
Devaux, Eric
Camargo, Mauricio
Campagne, Christine
Giraud, Stéphane
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2005
- Institución:
- Universidad de Antioquia
- Repositorio:
- Repositorio UdeA
- Idioma:
- eng
- OAI Identifier:
- oai:bibliotecadigital.udea.edu.co:10495/30852
- Acceso en línea:
- https://hdl.handle.net/10495/30852
- Palabra clave:
- Sílice
Silica
Caucho
Rubber
Polímeros
Polymers
- Rights
- openAccess
- License
- http://creativecommons.org/licenses/by/2.5/co/
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| dc.title.spa.fl_str_mv |
Use of mesoporous silica as a reinforcing agent in rubber compounds |
| title |
Use of mesoporous silica as a reinforcing agent in rubber compounds |
| spellingShingle |
Use of mesoporous silica as a reinforcing agent in rubber compounds Sílice Silica Caucho Rubber Polímeros Polymers |
| title_short |
Use of mesoporous silica as a reinforcing agent in rubber compounds |
| title_full |
Use of mesoporous silica as a reinforcing agent in rubber compounds |
| title_fullStr |
Use of mesoporous silica as a reinforcing agent in rubber compounds |
| title_full_unstemmed |
Use of mesoporous silica as a reinforcing agent in rubber compounds |
| title_sort |
Use of mesoporous silica as a reinforcing agent in rubber compounds |
| dc.creator.fl_str_mv |
López Osorio, Betty Lucy Pérez Pérez, León Dario Mesa Cadavid, Mónica Sierra García, Ligia Devaux, Eric Camargo, Mauricio Campagne, Christine Giraud, Stéphane |
| dc.contributor.author.none.fl_str_mv |
López Osorio, Betty Lucy Pérez Pérez, León Dario Mesa Cadavid, Mónica Sierra García, Ligia Devaux, Eric Camargo, Mauricio Campagne, Christine Giraud, Stéphane |
| dc.subject.lemb.none.fl_str_mv |
Sílice Silica Caucho Rubber Polímeros Polymers |
| topic |
Sílice Silica Caucho Rubber Polímeros Polymers |
| description |
ABSTRACT: esoporous silica is used as filler for styrene-butadiene rubber (SBR); filler-polymer interactions are compared with those exhibited when Ultrasil silica (VN3) is used. A silane coupling agent is added to improve filler dispersion and its influence on the bound-rubber formation is also investigated. The bound-rubber content is higher for the mesoporous silica and increases further for the sample containing silane. The increase is explained by chemical interactions between filler and rubber and penetration of the rubber chains into the mesopores. This is confirmed by 13C solid-state NMR, IR spectroscopy and differential scanning calorimetry. Dynamic mechanical thermal analysis shows higher storage modulus for the rubber filled with mesoporous silica. |
| publishDate |
2005 |
| dc.date.issued.none.fl_str_mv |
2005 |
| dc.date.accessioned.none.fl_str_mv |
2022-09-25T12:58:53Z |
| dc.date.available.none.fl_str_mv |
2022-09-25T12:58:53Z |
| dc.type.spa.fl_str_mv |
info:eu-repo/semantics/article |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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Artículo de investigación |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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publishedVersion |
| dc.identifier.citation.spa.fl_str_mv |
López, B., Pérez, L., Mesa, M., Sierra, L., Devaux, E., Camargo, M., Campagne, C. & Giraud, S. (2005). Use of mesoporous silica as a reinforcing agent in rubber compounds. e-Polymers, 5(1), 018. https://doi.org/10.1515/epoly.2005.5.1.182 |
| dc.identifier.issn.none.fl_str_mv |
1618-7229 |
| dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/10495/30852 |
| dc.identifier.doi.none.fl_str_mv |
10.1515/epoly.2005.5.1.182 |
| identifier_str_mv |
López, B., Pérez, L., Mesa, M., Sierra, L., Devaux, E., Camargo, M., Campagne, C. & Giraud, S. (2005). Use of mesoporous silica as a reinforcing agent in rubber compounds. e-Polymers, 5(1), 018. https://doi.org/10.1515/epoly.2005.5.1.182 1618-7229 10.1515/epoly.2005.5.1.182 |
| url |
https://hdl.handle.net/10495/30852 |
| dc.language.iso.spa.fl_str_mv |
eng |
| language |
eng |
| dc.rights.spa.fl_str_mv |
info:eu-repo/semantics/openAccess |
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http://creativecommons.org/licenses/by/2.5/co/ |
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http://purl.org/coar/access_right/c_abf2 |
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https://creativecommons.org/licenses/by/4.0/ |
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openAccess |
| rights_invalid_str_mv |
http://creativecommons.org/licenses/by/2.5/co/ http://purl.org/coar/access_right/c_abf2 https://creativecommons.org/licenses/by/4.0/ |
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13 |
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application/pdf |
| dc.publisher.spa.fl_str_mv |
De Gruyter Open |
| dc.publisher.group.spa.fl_str_mv |
Ciencia de los Materiales |
| dc.publisher.place.spa.fl_str_mv |
Francia |
| institution |
Universidad de Antioquia |
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https://bibliotecadigital.udea.edu.co/bitstream/10495/30852/1/LopezBetty_2005_UseMesoporousSilica.pdf https://bibliotecadigital.udea.edu.co/bitstream/10495/30852/2/license_rdf https://bibliotecadigital.udea.edu.co/bitstream/10495/30852/3/license.txt |
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López Osorio, Betty LucyPérez Pérez, León DarioMesa Cadavid, MónicaSierra García, LigiaDevaux, EricCamargo, MauricioCampagne, ChristineGiraud, Stéphane2022-09-25T12:58:53Z2022-09-25T12:58:53Z2005López, B., Pérez, L., Mesa, M., Sierra, L., Devaux, E., Camargo, M., Campagne, C. & Giraud, S. (2005). Use of mesoporous silica as a reinforcing agent in rubber compounds. e-Polymers, 5(1), 018. https://doi.org/10.1515/epoly.2005.5.1.1821618-7229https://hdl.handle.net/10495/3085210.1515/epoly.2005.5.1.182ABSTRACT: esoporous silica is used as filler for styrene-butadiene rubber (SBR); filler-polymer interactions are compared with those exhibited when Ultrasil silica (VN3) is used. A silane coupling agent is added to improve filler dispersion and its influence on the bound-rubber formation is also investigated. The bound-rubber content is higher for the mesoporous silica and increases further for the sample containing silane. The increase is explained by chemical interactions between filler and rubber and penetration of the rubber chains into the mesopores. This is confirmed by 13C solid-state NMR, IR spectroscopy and differential scanning calorimetry. Dynamic mechanical thermal analysis shows higher storage modulus for the rubber filled with mesoporous silica.COL000240113application/pdfengDe Gruyter OpenCiencia de los MaterialesFranciainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARTArtículo de investigaciónhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/co/http://purl.org/coar/access_right/c_abf2https://creativecommons.org/licenses/by/4.0/Use of mesoporous silica as a reinforcing agent in rubber compoundsSíliceSilicaCauchoRubberPolímerosPolymersE-Polymers11318ORIGINALLopezBetty_2005_UseMesoporousSilica.pdfLopezBetty_2005_UseMesoporousSilica.pdfArtículo de investigaciónapplication/pdf737327https://bibliotecadigital.udea.edu.co/bitstream/10495/30852/1/LopezBetty_2005_UseMesoporousSilica.pdf681db63f4f23e0e72139cc6d77e79ad0MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8927https://bibliotecadigital.udea.edu.co/bitstream/10495/30852/2/license_rdf1646d1f6b96dbbbc38035efc9239ac9cMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://bibliotecadigital.udea.edu.co/bitstream/10495/30852/3/license.txt8a4605be74aa9ea9d79846c1fba20a33MD5310495/30852oai:bibliotecadigital.udea.edu.co:10495/308522022-09-25 07:58:53.462Repositorio Institucional Universidad de Antioquiaandres.perez@udea.edu.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 |