Modeling and simulation of a batch distillation column for recovering limonene epoxide

ABSTRACT: Aspen Plus and MATLAB software simulation tools were employed for modeling, simulation and optimization of a distillation process to recover limonene epoxide from a liquid mixture containing limonene + acetonitrile + water + limonene epoxide. This mixture is obtained from limonene epoxidat...

Full description

Autores:
Barrera Zapata, Rolando
Villa Holguín, Aída Luz
Montes de Correa, Consuelo
Tipo de recurso:
Article of investigation
Fecha de publicación:
2012
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/26826
Acceso en línea:
http://hdl.handle.net/10495/26826
https://revistas.eia.edu.co/index.php/reveia/article/view/265
Palabra clave:
Destilación
Distillation
Modelado
Modeling
Epóxido de limoneno
Simulación de procesos
Rights
openAccess
License
Atribución-NoComercial-SinDerivadas 2.5 Colombia
id UDEA2_abc6bd1e8103d5e7b328c4ce55bfa729
oai_identifier_str oai:bibliotecadigital.udea.edu.co:10495/26826
network_acronym_str UDEA2
network_name_str Repositorio UdeA
repository_id_str
dc.title.spa.fl_str_mv Modeling and simulation of a batch distillation column for recovering limonene epoxide
dc.title.alternative.spa.fl_str_mv Modelado y simulación de una columna de destilación por lotes para recuperar epóxido de limoneno
title Modeling and simulation of a batch distillation column for recovering limonene epoxide
spellingShingle Modeling and simulation of a batch distillation column for recovering limonene epoxide
Destilación
Distillation
Modelado
Modeling
Epóxido de limoneno
Simulación de procesos
title_short Modeling and simulation of a batch distillation column for recovering limonene epoxide
title_full Modeling and simulation of a batch distillation column for recovering limonene epoxide
title_fullStr Modeling and simulation of a batch distillation column for recovering limonene epoxide
title_full_unstemmed Modeling and simulation of a batch distillation column for recovering limonene epoxide
title_sort Modeling and simulation of a batch distillation column for recovering limonene epoxide
dc.creator.fl_str_mv Barrera Zapata, Rolando
Villa Holguín, Aída Luz
Montes de Correa, Consuelo
dc.contributor.author.none.fl_str_mv Barrera Zapata, Rolando
Villa Holguín, Aída Luz
Montes de Correa, Consuelo
dc.subject.lemb.none.fl_str_mv Destilación
Distillation
Modelado
Modeling
topic Destilación
Distillation
Modelado
Modeling
Epóxido de limoneno
Simulación de procesos
dc.subject.proposal.spa.fl_str_mv Epóxido de limoneno
Simulación de procesos
description ABSTRACT: Aspen Plus and MATLAB software simulation tools were employed for modeling, simulation and optimization of a distillation process to recover limonene epoxide from a liquid mixture containing limonene + acetonitrile + water + limonene epoxide. This mixture is obtained from limonene epoxidation over PW-Amberlite using aqueous hydrogen peroxide as oxidant and acetonitrile as solvent. Analyses of residue curve maps indicate that batch distillation columns of inverse configuration are adequate to separate limonene epoxide. The model parameters, i.e., the number of stages (8) and the reflux ratio (3,1) were determined by steady state simulations with short-cut models and rigorous models from Aspen Plus. Aspen Plus simulation of the batch distillation operation showed that it is possible to recover up to 95 % limonene epoxide with a molar fraction of 0,97 after 7,5 h. For comparison purposes, the batch distillation operation was also simulated with a semi-rigorous MATLAB model and similar results were obtained.
publishDate 2012
dc.date.issued.none.fl_str_mv 2012
dc.date.accessioned.none.fl_str_mv 2022-03-23T22:01:12Z
dc.date.available.none.fl_str_mv 2022-03-23T22:01:12Z
dc.type.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.coarversion.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.hasversion.spa.fl_str_mv info:eu-repo/semantics/publishedVersion
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dc.type.redcol.spa.fl_str_mv https://purl.org/redcol/resource_type/ART
dc.type.local.spa.fl_str_mv Artículo de investigación
format http://purl.org/coar/resource_type/c_2df8fbb1
status_str publishedVersion
dc.identifier.issn.none.fl_str_mv 1794-1237
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/10495/26826
dc.identifier.eissn.none.fl_str_mv 2463-0950
dc.identifier.url.spa.fl_str_mv https://revistas.eia.edu.co/index.php/reveia/article/view/265
identifier_str_mv 1794-1237
2463-0950
url http://hdl.handle.net/10495/26826
https://revistas.eia.edu.co/index.php/reveia/article/view/265
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartofjournalabbrev.spa.fl_str_mv Revista EIA
dc.rights.spa.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.*.fl_str_mv Atribución-NoComercial-SinDerivadas 2.5 Colombia
dc.rights.uri.*.fl_str_mv http://creativecommons.org/licenses/by-nc-nd/2.5/co/
dc.rights.accessrights.spa.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.rights.creativecommons.spa.fl_str_mv https://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv Atribución-NoComercial-SinDerivadas 2.5 Colombia
http://creativecommons.org/licenses/by-nc-nd/2.5/co/
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.format.extent.spa.fl_str_mv 11
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Escuela de Ingeniería de Antioquia
dc.publisher.group.spa.fl_str_mv Catálisis Ambiental
dc.publisher.place.spa.fl_str_mv Envigado, Colombia
institution Universidad de Antioquia
bitstream.url.fl_str_mv http://bibliotecadigital.udea.edu.co/bitstream/10495/26826/1/MontesConsuelo_2012_ModelingBatchDistillation.pdf
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spelling Barrera Zapata, RolandoVilla Holguín, Aída LuzMontes de Correa, Consuelo2022-03-23T22:01:12Z2022-03-23T22:01:12Z20121794-1237http://hdl.handle.net/10495/268262463-0950https://revistas.eia.edu.co/index.php/reveia/article/view/265ABSTRACT: Aspen Plus and MATLAB software simulation tools were employed for modeling, simulation and optimization of a distillation process to recover limonene epoxide from a liquid mixture containing limonene + acetonitrile + water + limonene epoxide. This mixture is obtained from limonene epoxidation over PW-Amberlite using aqueous hydrogen peroxide as oxidant and acetonitrile as solvent. Analyses of residue curve maps indicate that batch distillation columns of inverse configuration are adequate to separate limonene epoxide. The model parameters, i.e., the number of stages (8) and the reflux ratio (3,1) were determined by steady state simulations with short-cut models and rigorous models from Aspen Plus. Aspen Plus simulation of the batch distillation operation showed that it is possible to recover up to 95 % limonene epoxide with a molar fraction of 0,97 after 7,5 h. For comparison purposes, the batch distillation operation was also simulated with a semi-rigorous MATLAB model and similar results were obtained.RESUMEN: Se emplearon herramientas de software de simulación como Aspen Plus y MATLAB para el modelado, simulación y optimización de un proceso de destilación para recuperar epóxido de limoneno a partir de una mezcla líquida que contiene limoneno + acetonitrilo + agua + epóxido de limoneno. Esta mezcla se obtiene de la epoxidación de limoneno sobre PW-Amberlita utilizando peróxido de hidrógeno acuoso como oxidante y acetonitrilo como disolvente. Los análisis de curvas de composición residual indicaron que las columnas de destilación por lotes de configuración inversa son adecuadas para separar el epóxido de limoneno. Los parámetros del modelo, como el número de etapas (8) y la relación de reflujo (3,1) se determinaron mediante simulaciones de estado estacionario con modelos cortos y rigurosos de Aspen Plus. La simulación del equipo por lotes en Aspen Plus mostró que es posible recuperar hasta el 95 % del epóxido de limoneno con una fracción molar de 0,97 después de 7,5 h. Con fines comparativos, la destilación por lotes también se simuló con un modelo semirriguroso construido en MATLAB, con el cual se lograron resultados similares.COL000194111application/pdfengEscuela de Ingeniería de AntioquiaCatálisis AmbientalEnvigado, Colombiainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARTArtículo de investigaciónhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/openAccessAtribución-NoComercial-SinDerivadas 2.5 Colombiahttp://creativecommons.org/licenses/by-nc-nd/2.5/co/http://purl.org/coar/access_right/c_abf2https://creativecommons.org/licenses/by-nc-nd/4.0/Modeling and simulation of a batch distillation column for recovering limonene epoxideModelado y simulación de una columna de destilación por lotes para recuperar epóxido de limonenoDestilaciónDistillationModeladoModelingEpóxido de limonenoSimulación de procesosRevista EIARevista EIA131141918ORIGINALMontesConsuelo_2012_ModelingBatchDistillation.pdfMontesConsuelo_2012_ModelingBatchDistillation.pdfArtículo de investigaciónapplication/pdf487922http://bibliotecadigital.udea.edu.co/bitstream/10495/26826/1/MontesConsuelo_2012_ModelingBatchDistillation.pdf5dd814b18c7a830579607b0ec2843e3aMD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8823http://bibliotecadigital.udea.edu.co/bitstream/10495/26826/2/license_rdfb88b088d9957e670ce3b3fbe2eedbc13MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://bibliotecadigital.udea.edu.co/bitstream/10495/26826/3/license.txt8a4605be74aa9ea9d79846c1fba20a33MD5310495/26826oai:bibliotecadigital.udea.edu.co:10495/268262022-03-26 12:39:46.521Repositorio Institucional Universidad de Antioquiaandres.perez@udea.edu.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