Formation of homogeneous nanotubes on titanium c.p. by anodizing technique for biomedical applications

ABSTRACT: The nanostructures and within them, the titanium dioxide nanostructures have had an investigative awakening because they have a large surface area, allowing ion exchange processes and possible photocatalytic activity. One of the structures that have attracted more the attention of research...

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Autores:
Aguirre Ocampo, Robinson
Tipo de recurso:
Doctoral thesis
Fecha de publicación:
2020
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/17867
Acceso en línea:
http://hdl.handle.net/10495/17867
Palabra clave:
Ionization
Ionización
Radiation
Radiación
Water pollution
Contaminación del agua
Corrosion
Corrosión
Titanio
Biomedicina
http://vocabularies.unesco.org/thesaurus/concept12916
http://vocabularies.unesco.org/thesaurus/concept1237
http://vocabularies.unesco.org/thesaurus/concept2632
http://vocabularies.unesco.org/thesaurus/concept5010
Rights
embargoedAccess
License
Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)
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network_name_str Repositorio UdeA
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dc.title.spa.fl_str_mv Formation of homogeneous nanotubes on titanium c.p. by anodizing technique for biomedical applications
title Formation of homogeneous nanotubes on titanium c.p. by anodizing technique for biomedical applications
spellingShingle Formation of homogeneous nanotubes on titanium c.p. by anodizing technique for biomedical applications
Ionization
Ionización
Radiation
Radiación
Water pollution
Contaminación del agua
Corrosion
Corrosión
Titanio
Biomedicina
http://vocabularies.unesco.org/thesaurus/concept12916
http://vocabularies.unesco.org/thesaurus/concept1237
http://vocabularies.unesco.org/thesaurus/concept2632
http://vocabularies.unesco.org/thesaurus/concept5010
title_short Formation of homogeneous nanotubes on titanium c.p. by anodizing technique for biomedical applications
title_full Formation of homogeneous nanotubes on titanium c.p. by anodizing technique for biomedical applications
title_fullStr Formation of homogeneous nanotubes on titanium c.p. by anodizing technique for biomedical applications
title_full_unstemmed Formation of homogeneous nanotubes on titanium c.p. by anodizing technique for biomedical applications
title_sort Formation of homogeneous nanotubes on titanium c.p. by anodizing technique for biomedical applications
dc.creator.fl_str_mv Aguirre Ocampo, Robinson
dc.contributor.advisor.none.fl_str_mv Echeverría Echeverría, Félix
dc.contributor.author.none.fl_str_mv Aguirre Ocampo, Robinson
dc.subject.unesco.none.fl_str_mv Ionization
Ionización
Radiation
Radiación
Water pollution
Contaminación del agua
Corrosion
Corrosión
topic Ionization
Ionización
Radiation
Radiación
Water pollution
Contaminación del agua
Corrosion
Corrosión
Titanio
Biomedicina
http://vocabularies.unesco.org/thesaurus/concept12916
http://vocabularies.unesco.org/thesaurus/concept1237
http://vocabularies.unesco.org/thesaurus/concept2632
http://vocabularies.unesco.org/thesaurus/concept5010
dc.subject.ocde.none.fl_str_mv Titanio
Biomedicina
dc.subject.unescouri.none.fl_str_mv http://vocabularies.unesco.org/thesaurus/concept12916
http://vocabularies.unesco.org/thesaurus/concept1237
http://vocabularies.unesco.org/thesaurus/concept2632
http://vocabularies.unesco.org/thesaurus/concept5010
description ABSTRACT: The nanostructures and within them, the titanium dioxide nanostructures have had an investigative awakening because they have a large surface area, allowing ion exchange processes and possible photocatalytic activity. One of the structures that have attracted more the attention of researchers is nanotubular because it presents unique geometric properties that allow it to be applied as a catalyst in reactions that employ radiation for removing water contaminants, like the sensor of chemical compounds present in the air, and in medicine as a biomedical device. Although there are several methods of producing titanium dioxide nanotubes, one that has gained strength because of its easy implementation and simplicity is the anodizing process. Titanium is a material used in many engineering fields due to its high mechanical and corrosion resistance properties, but to further enhance the above features, anodizing is presented as a viable option for surface improvement, because it can produce nanotubes with higher organization and orientation that with other techniques could not be obtained. This project aim was obtained homogeneous TiO2 nanotubes on c.p Ti using aqueous electrolytes. For that purpose, an anodizing protocol was established to get geometrically homogeneous nanotubes by modifying different parameters of the anodizing process. Then the best coatings were selected and were characterized by SEM, TEM, AFM, XRD, and micro-Raman, correlating the obtained with the nano-tubular coating characteristics, after that, it was analyzed the effect of the above on biocompatibility and antibacterial capacity of coatings by bioassays.
publishDate 2020
dc.date.issued.none.fl_str_mv 2020
dc.date.accessioned.none.fl_str_mv 2021-01-18T15:14:25Z
dc.date.available.none.fl_str_mv 2021-01-18T15:14:25Z
dc.type.spa.fl_str_mv info:eu-repo/semantics/doctoralThesis
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dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/10495/17867
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dc.language.iso.spa.fl_str_mv eng
language eng
dc.rights.*.fl_str_mv Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)
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rights_invalid_str_mv Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)
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dc.format.extent.spa.fl_str_mv 158
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dc.publisher.group.spa.fl_str_mv Centro de Investigación, Innovación y Desarrollo de Materiales (CIDEMAT)
dc.publisher.place.spa.fl_str_mv Medellín, Colombia
institution Universidad de Antioquia
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spelling Echeverría Echeverría, FélixAguirre Ocampo, Robinson2021-01-18T15:14:25Z2021-01-18T15:14:25Z2020http://hdl.handle.net/10495/17867ABSTRACT: The nanostructures and within them, the titanium dioxide nanostructures have had an investigative awakening because they have a large surface area, allowing ion exchange processes and possible photocatalytic activity. One of the structures that have attracted more the attention of researchers is nanotubular because it presents unique geometric properties that allow it to be applied as a catalyst in reactions that employ radiation for removing water contaminants, like the sensor of chemical compounds present in the air, and in medicine as a biomedical device. Although there are several methods of producing titanium dioxide nanotubes, one that has gained strength because of its easy implementation and simplicity is the anodizing process. Titanium is a material used in many engineering fields due to its high mechanical and corrosion resistance properties, but to further enhance the above features, anodizing is presented as a viable option for surface improvement, because it can produce nanotubes with higher organization and orientation that with other techniques could not be obtained. This project aim was obtained homogeneous TiO2 nanotubes on c.p Ti using aqueous electrolytes. For that purpose, an anodizing protocol was established to get geometrically homogeneous nanotubes by modifying different parameters of the anodizing process. Then the best coatings were selected and were characterized by SEM, TEM, AFM, XRD, and micro-Raman, correlating the obtained with the nano-tubular coating characteristics, after that, it was analyzed the effect of the above on biocompatibility and antibacterial capacity of coatings by bioassays.158application/pdfenginfo:eu-repo/semantics/draftinfo:eu-repo/semantics/doctoralThesishttp://purl.org/coar/resource_type/c_db06https://purl.org/redcol/resource_type/TDTesis/Trabajo de grado - Monografía - Doctoradohttp://purl.org/coar/version/c_b1a7d7d4d402bcceAtribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)info:eu-repo/semantics/embargoedAccesshttp://creativecommons.org/licenses/by-nc-nd/2.5/co/http://purl.org/coar/access_right/c_f1cfhttps://creativecommons.org/licenses/by-nc-nd/4.0/Formation of homogeneous nanotubes on titanium c.p. by anodizing technique for biomedical applicationsCentro de Investigación, Innovación y Desarrollo de Materiales (CIDEMAT)Medellín, ColombiaIonizationIonizaciónRadiationRadiaciónWater pollutionContaminación del aguaCorrosionCorrosiónTitanioBiomedicinahttp://vocabularies.unesco.org/thesaurus/concept12916http://vocabularies.unesco.org/thesaurus/concept1237http://vocabularies.unesco.org/thesaurus/concept2632http://vocabularies.unesco.org/thesaurus/concept5010Doctor en Ingeniería de MaterialesDoctoradoFacultad de Ingeniería. Doctorado en Ingeniería de MaterialesUniversidad de AntioquiaCC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8823http://bibliotecadigital.udea.edu.co/bitstream/10495/17867/4/license_rdfb88b088d9957e670ce3b3fbe2eedbc13MD54LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://bibliotecadigital.udea.edu.co/bitstream/10495/17867/5/license.txt8a4605be74aa9ea9d79846c1fba20a33MD55ORIGINALAguirreRobinson_2020_FormationNanotubesTitanium.pdfAguirreRobinson_2020_FormationNanotubesTitanium.pdfTesis doctoralapplication/pdf22378242http://bibliotecadigital.udea.edu.co/bitstream/10495/17867/2/AguirreRobinson_2020_FormationNanotubesTitanium.pdf323bccade345de9f927f0dea2a5919ceMD5210495/17867oai:bibliotecadigital.udea.edu.co:10495/178672021-05-21 11:44:51.739Repositorio Institucional Universidad de Antioquiaandres.perez@udea.edu.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