Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation

ABSTRACT: Green-hydrogen generation has become a focus for research due to its promising future as an energy vector. In this regard, one topic that has not been explored in depth, is the corrosion of catalytic layers under on/off operation in alkaline media during oxygen evolution reaction (OER) on...

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Autores:
Cartagena Ocampo, Santiago
Calderón Guitiérrez, Jorge Andrés
Tipo de recurso:
Article of investigation
Fecha de publicación:
2022
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/29887
Acceso en línea:
https://hdl.handle.net/10495/29887
Palabra clave:
Reacciones químicas
Chemical reactions
Corrosión del níquel
Nickel - corrosion
Catalizadores metálicos
Metal catalysts
Electrólisis del agua
Water - electrolysis
Rights
openAccess
License
Atribución-NoComercial-SinDerivadas 2.5 Colombia
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oai_identifier_str oai:bibliotecadigital.udea.edu.co:10495/29887
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network_name_str Repositorio UdeA
repository_id_str
dc.title.spa.fl_str_mv Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation
title Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation
spellingShingle Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation
Reacciones químicas
Chemical reactions
Corrosión del níquel
Nickel - corrosion
Catalizadores metálicos
Metal catalysts
Electrólisis del agua
Water - electrolysis
title_short Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation
title_full Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation
title_fullStr Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation
title_full_unstemmed Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation
title_sort Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation
dc.creator.fl_str_mv Cartagena Ocampo, Santiago
Calderón Guitiérrez, Jorge Andrés
dc.contributor.author.none.fl_str_mv Cartagena Ocampo, Santiago
Calderón Guitiérrez, Jorge Andrés
dc.subject.lemb.none.fl_str_mv Reacciones químicas
Chemical reactions
Corrosión del níquel
Nickel - corrosion
Catalizadores metálicos
Metal catalysts
Electrólisis del agua
Water - electrolysis
topic Reacciones químicas
Chemical reactions
Corrosión del níquel
Nickel - corrosion
Catalizadores metálicos
Metal catalysts
Electrólisis del agua
Water - electrolysis
description ABSTRACT: Green-hydrogen generation has become a focus for research due to its promising future as an energy vector. In this regard, one topic that has not been explored in depth, is the corrosion of catalytic layers under on/off operation in alkaline media during oxygen evolution reaction (OER) on the anode. Here, we studied the corrosion of, and changes to, the catalytic layer on stainless steel (SS) electrodes under different surface treatments. The results showed that there was formation of a passive and catalytic layer of NiOOH during the anodic polarization concomitantly with iron dissolution.
publishDate 2022
dc.date.accessioned.none.fl_str_mv 2022-07-28T17:03:07Z
dc.date.available.none.fl_str_mv 2022-07-28T17:03:07Z
dc.date.issued.none.fl_str_mv 2022
dc.type.spa.fl_str_mv info:eu-repo/semantics/article
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dc.identifier.citation.spa.fl_str_mv S. Cartagena y J. A. Calderón, «Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation», Corros. Sci., vol. 205, p. 110437, 2022, doi: https://doi.org/10.1016/j.corsci.2022.110437.
dc.identifier.issn.none.fl_str_mv 0010-938X
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/10495/29887
dc.identifier.doi.none.fl_str_mv 10.1016/j.corsci.2022.110437
dc.identifier.eissn.none.fl_str_mv 1879-0496
identifier_str_mv S. Cartagena y J. A. Calderón, «Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation», Corros. Sci., vol. 205, p. 110437, 2022, doi: https://doi.org/10.1016/j.corsci.2022.110437.
0010-938X
10.1016/j.corsci.2022.110437
1879-0496
url https://hdl.handle.net/10495/29887
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartofjournalabbrev.spa.fl_str_mv Corros. Sci.
dc.rights.spa.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.*.fl_str_mv Atribución-NoComercial-SinDerivadas 2.5 Colombia
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dc.publisher.spa.fl_str_mv Elsevier
dc.publisher.group.spa.fl_str_mv Centro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT)
dc.publisher.place.spa.fl_str_mv Reino Unido
institution Universidad de Antioquia
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spelling Cartagena Ocampo, SantiagoCalderón Guitiérrez, Jorge Andrés2022-07-28T17:03:07Z2022-07-28T17:03:07Z2022S. Cartagena y J. A. Calderón, «Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation», Corros. Sci., vol. 205, p. 110437, 2022, doi: https://doi.org/10.1016/j.corsci.2022.110437.0010-938Xhttps://hdl.handle.net/10495/2988710.1016/j.corsci.2022.1104371879-0496ABSTRACT: Green-hydrogen generation has become a focus for research due to its promising future as an energy vector. In this regard, one topic that has not been explored in depth, is the corrosion of catalytic layers under on/off operation in alkaline media during oxygen evolution reaction (OER) on the anode. Here, we studied the corrosion of, and changes to, the catalytic layer on stainless steel (SS) electrodes under different surface treatments. The results showed that there was formation of a passive and catalytic layer of NiOOH during the anodic polarization concomitantly with iron dissolution.COL000792712application/pdfengElsevierCentro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT)Reino Unidoinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARTArtículo de investigaciónhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/openAccessAtribución-NoComercial-SinDerivadas 2.5 Colombiahttp://creativecommons.org/licenses/by-nc-nd/2.5/co/http://purl.org/coar/access_right/c_abf2https://creativecommons.org/licenses/by-nc-nd/4.0/Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operationReacciones químicasChemical reactionsCorrosión del níquelNickel - corrosionCatalizadores metálicosMetal catalystsElectrólisis del aguaWater - electrolysisCorros. Sci.Corrosion Science112205ORIGINALCalderonJorge_2022_Corrosion-non-noble-metal-based-catalysts.pdfCalderonJorge_2022_Corrosion-non-noble-metal-based-catalysts.pdfArtículo de investigaciónapplication/pdf7111740https://bibliotecadigital.udea.edu.co/bitstream/10495/29887/1/CalderonJorge_2022_Corrosion-non-noble-metal-based-catalysts.pdf76343c87f20b4da43c6678eea7cf52d8MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8823https://bibliotecadigital.udea.edu.co/bitstream/10495/29887/2/license_rdfb88b088d9957e670ce3b3fbe2eedbc13MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://bibliotecadigital.udea.edu.co/bitstream/10495/29887/3/license.txt8a4605be74aa9ea9d79846c1fba20a33MD5310495/29887oai:bibliotecadigital.udea.edu.co:10495/298872022-07-28 12:03:07.793Repositorio Institucional Universidad de Antioquiaandres.perez@udea.edu.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