Corrosion of non-noble metal-based catalysts during oxygen evolution reaction under on/off operation

ABSTRACT: Green-hydrogen generation has become a focus for research due to its promising future as an energy vector. In this regard, one topic that has not been explored in depth, is the corrosion of catalytic layers under on/off operation in alkaline media during oxygen evolution reaction (OER) on...

Full description

Autores:
Cartagena Ocampo, Santiago
Calderón Guitiérrez, Jorge Andrés
Tipo de recurso:
Article of investigation
Fecha de publicación:
2022
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/29887
Acceso en línea:
https://hdl.handle.net/10495/29887
Palabra clave:
Reacciones químicas
Chemical reactions
Corrosión del níquel
Nickel - corrosion
Catalizadores metálicos
Metal catalysts
Electrólisis del agua
Water - electrolysis
Rights
openAccess
License
Atribución-NoComercial-SinDerivadas 2.5 Colombia
Description
Summary:ABSTRACT: Green-hydrogen generation has become a focus for research due to its promising future as an energy vector. In this regard, one topic that has not been explored in depth, is the corrosion of catalytic layers under on/off operation in alkaline media during oxygen evolution reaction (OER) on the anode. Here, we studied the corrosion of, and changes to, the catalytic layer on stainless steel (SS) electrodes under different surface treatments. The results showed that there was formation of a passive and catalytic layer of NiOOH during the anodic polarization concomitantly with iron dissolution.