Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water
RESUMEN: Degradation of triclosan, benzophenone 1, and benzophenone 3 by multifrequency ultrasound was studied at high frequencies. Frequency effect on initial degradation rates was analyzed and an optimum frequency was found. Power density effect was also analyzed. A reaction mechanism was proposed...
- Autores:
-
Vega Garzón, Lina Patricia
- Tipo de recurso:
- Doctoral thesis
- Fecha de publicación:
- 2018
- Institución:
- Universidad de Antioquia
- Repositorio:
- Repositorio UdeA
- Idioma:
- spa
- OAI Identifier:
- oai:bibliotecadigital.udea.edu.co:10495/12232
- Acceso en línea:
- http://hdl.handle.net/10495/12232
- Palabra clave:
- Triclosan
Triclosán
Toxicity
Toxicidad
Benzophenone
Sonochemical degradation
http://aims.fao.org/aos/agrovoc/c_7826
- Rights
- openAccess
- License
- Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)
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| dc.title.spa.fl_str_mv |
Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water |
| title |
Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water |
| spellingShingle |
Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water Triclosan Triclosán Toxicity Toxicidad Benzophenone Sonochemical degradation http://aims.fao.org/aos/agrovoc/c_7826 |
| title_short |
Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water |
| title_full |
Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water |
| title_fullStr |
Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water |
| title_full_unstemmed |
Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water |
| title_sort |
Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water |
| dc.creator.fl_str_mv |
Vega Garzón, Lina Patricia |
| dc.contributor.advisor.none.fl_str_mv |
Peñuela, Gustavo |
| dc.contributor.author.none.fl_str_mv |
Vega Garzón, Lina Patricia |
| dc.subject.decs.none.fl_str_mv |
Triclosan Triclosán |
| topic |
Triclosan Triclosán Toxicity Toxicidad Benzophenone Sonochemical degradation http://aims.fao.org/aos/agrovoc/c_7826 |
| dc.subject.agrovoc.none.fl_str_mv |
Toxicity Toxicidad |
| dc.subject.proposal.spa.fl_str_mv |
Benzophenone Sonochemical degradation |
| dc.subject.agrovocuri.none.fl_str_mv |
http://aims.fao.org/aos/agrovoc/c_7826 |
| description |
RESUMEN: Degradation of triclosan, benzophenone 1, and benzophenone 3 by multifrequency ultrasound was studied at high frequencies. Frequency effect on initial degradation rates was analyzed and an optimum frequency was found. Power density effect was also analyzed. A reaction mechanism was proposed and reaction kinetics were found. Pulsed US mode effect was analyzed too. Simultaneous analysis of the effect of power, frequency, pulse time, and silent time was made and optimization by response surface methodology was made for benzophenone 3 degradation. Analysis of this and radical scavengers, let conclude if degradation of molecules was taking place in the bubble/liquid interface, bubble, or bulk liquid. Toxicity tests were conducted by Microtox®. Degradation byproducts and degradation pathways were proposed. |
| publishDate |
2018 |
| dc.date.issued.none.fl_str_mv |
2018 |
| dc.date.accessioned.none.fl_str_mv |
2019-10-29T19:12:55Z |
| dc.date.available.none.fl_str_mv |
2019-10-29T19:12:55Z |
| dc.type.spa.fl_str_mv |
info:eu-repo/semantics/doctoralThesis |
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http://purl.org/coar/version/c_b1a7d7d4d402bcce |
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info:eu-repo/semantics/draft |
| dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_db06 |
| dc.type.redcol.spa.fl_str_mv |
https://purl.org/redcol/resource_type/TD |
| dc.type.local.spa.fl_str_mv |
Tesis/Trabajo de grado - Monografía - Doctorado |
| format |
http://purl.org/coar/resource_type/c_db06 |
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draft |
| dc.identifier.citation.spa.fl_str_mv |
L. P. Vega, "Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water", Tesis doctoral, Fac. Ingeniería, Univ. de Ant., Medellín, Col., 2018. |
| dc.identifier.uri.none.fl_str_mv |
http://hdl.handle.net/10495/12232 |
| identifier_str_mv |
L. P. Vega, "Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water", Tesis doctoral, Fac. Ingeniería, Univ. de Ant., Medellín, Col., 2018. |
| url |
http://hdl.handle.net/10495/12232 |
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spa |
| language |
spa |
| dc.rights.*.fl_str_mv |
Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO) |
| dc.rights.spa.fl_str_mv |
info:eu-repo/semantics/openAccess |
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http://creativecommons.org/licenses/by-nc-nd/2.5/co/ |
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http://purl.org/coar/access_right/c_abf2 |
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https://creativecommons.org/licenses/by-nc-nd/4.0/ |
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Atribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO) http://creativecommons.org/licenses/by-nc-nd/2.5/co/ http://purl.org/coar/access_right/c_abf2 https://creativecommons.org/licenses/by-nc-nd/4.0/ |
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openAccess |
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190 |
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application/pdf |
| dc.publisher.group.spa.fl_str_mv |
Diagnóstico y Control de la Contaminación |
| dc.publisher.place.spa.fl_str_mv |
Medellín, Colombia |
| institution |
Universidad de Antioquia |
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Peñuela, GustavoVega Garzón, Lina Patricia2019-10-29T19:12:55Z2019-10-29T19:12:55Z2018L. P. Vega, "Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in Water", Tesis doctoral, Fac. Ingeniería, Univ. de Ant., Medellín, Col., 2018.http://hdl.handle.net/10495/12232RESUMEN: Degradation of triclosan, benzophenone 1, and benzophenone 3 by multifrequency ultrasound was studied at high frequencies. Frequency effect on initial degradation rates was analyzed and an optimum frequency was found. Power density effect was also analyzed. A reaction mechanism was proposed and reaction kinetics were found. Pulsed US mode effect was analyzed too. Simultaneous analysis of the effect of power, frequency, pulse time, and silent time was made and optimization by response surface methodology was made for benzophenone 3 degradation. Analysis of this and radical scavengers, let conclude if degradation of molecules was taking place in the bubble/liquid interface, bubble, or bulk liquid. Toxicity tests were conducted by Microtox®. Degradation byproducts and degradation pathways were proposed.190application/pdfspainfo:eu-repo/semantics/draftinfo:eu-repo/semantics/doctoralThesishttp://purl.org/coar/resource_type/c_db06https://purl.org/redcol/resource_type/TDTesis/Trabajo de grado - Monografía - Doctoradohttp://purl.org/coar/version/c_b1a7d7d4d402bcceAtribución-NoComercial-SinDerivadas 2.5 Colombia (CC BY-NC-ND 2.5 CO)info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/2.5/co/http://purl.org/coar/access_right/c_abf2https://creativecommons.org/licenses/by-nc-nd/4.0/Sonochemical degradation of triclosan, benzophenone-1 and benzophenone -3 in WaterDiagnóstico y Control de la ContaminaciónMedellín, ColombiaTriclosanTriclosánToxicityToxicidadBenzophenoneSonochemical degradationhttp://aims.fao.org/aos/agrovoc/c_7826Doctor en IngenieríaDoctoradoFacultad de Ingeniería. Doctorado en IngenieríaUniversidad de AntioquiaORIGINALVegaLina_2018_SonochemicalDegradationTriclosan.pdfVegaLina_2018_SonochemicalDegradationTriclosan.pdfTesis doctoralapplication/pdf5348144http://bibliotecadigital.udea.edu.co/bitstream/10495/12232/1/VegaLina_2018_SonochemicalDegradationTriclosan.pdf2c915b69d2cc57ec9ffe35a696876febMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://bibliotecadigital.udea.edu.co/bitstream/10495/12232/5/license.txt8a4605be74aa9ea9d79846c1fba20a33MD55CC-LICENSElicense_urllicense_urltext/plain; charset=utf-849http://bibliotecadigital.udea.edu.co/bitstream/10495/12232/2/license_url4afdbb8c545fd630ea7db775da747b2fMD52license_textlicense_texttext/html; charset=utf-80http://bibliotecadigital.udea.edu.co/bitstream/10495/12232/3/license_textd41d8cd98f00b204e9800998ecf8427eMD53license_rdflicense_rdfLicenciaapplication/rdf+xml; charset=utf-80http://bibliotecadigital.udea.edu.co/bitstream/10495/12232/4/license_rdfd41d8cd98f00b204e9800998ecf8427eMD5410495/12232oai:bibliotecadigital.udea.edu.co:10495/122322021-05-24 11:18:38.576Repositorio Institucional Universidad de Antioquiaandres.perez@udea.edu.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 |