Simulation of a long term atmospheric corrosion process on plain and weathering steels

ABSTRACT: Information on weathering steel behaviour and its rust products characteristics after decades of atmospheric exposure are scarce. On the other side, generally accepted laboratory tests for the assessment of its corrosion resistance have not been developed yet. Consequently, simulating corr...

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Autores:
Bolívar Osorio, Francisco Javier
Morales Aramburo, Álvaro Luis
Arroyave Posada, Carlos Enrique
Tipo de recurso:
Article of investigation
Fecha de publicación:
2003
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/27151
Acceso en línea:
http://hdl.handle.net/10495/27151
Palabra clave:
Corrosión del acero
Steel - Corrosion
Corrosión del hierro
Iron - corrosion
Espectroscopia de Mossbauer
Mossbauer spectroscopy
Ensayo de materiales
Materials - Testing
Rights
openAccess
License
http://creativecommons.org/licenses/by/2.5/co/
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oai_identifier_str oai:bibliotecadigital.udea.edu.co:10495/27151
network_acronym_str UDEA2
network_name_str Repositorio UdeA
repository_id_str
dc.title.spa.fl_str_mv Simulation of a long term atmospheric corrosion process on plain and weathering steels
dc.title.alternative.spa.fl_str_mv Simulación de los procesos de corrosión atmosférica durante largos períodos de tiempo de un acero autoprotector y ordinario
title Simulation of a long term atmospheric corrosion process on plain and weathering steels
spellingShingle Simulation of a long term atmospheric corrosion process on plain and weathering steels
Corrosión del acero
Steel - Corrosion
Corrosión del hierro
Iron - corrosion
Espectroscopia de Mossbauer
Mossbauer spectroscopy
Ensayo de materiales
Materials - Testing
title_short Simulation of a long term atmospheric corrosion process on plain and weathering steels
title_full Simulation of a long term atmospheric corrosion process on plain and weathering steels
title_fullStr Simulation of a long term atmospheric corrosion process on plain and weathering steels
title_full_unstemmed Simulation of a long term atmospheric corrosion process on plain and weathering steels
title_sort Simulation of a long term atmospheric corrosion process on plain and weathering steels
dc.creator.fl_str_mv Bolívar Osorio, Francisco Javier
Morales Aramburo, Álvaro Luis
Arroyave Posada, Carlos Enrique
dc.contributor.author.none.fl_str_mv Bolívar Osorio, Francisco Javier
Morales Aramburo, Álvaro Luis
Arroyave Posada, Carlos Enrique
dc.subject.lemb.none.fl_str_mv Corrosión del acero
Steel - Corrosion
Corrosión del hierro
Iron - corrosion
Espectroscopia de Mossbauer
Mossbauer spectroscopy
Ensayo de materiales
Materials - Testing
topic Corrosión del acero
Steel - Corrosion
Corrosión del hierro
Iron - corrosion
Espectroscopia de Mossbauer
Mossbauer spectroscopy
Ensayo de materiales
Materials - Testing
description ABSTRACT: Information on weathering steel behaviour and its rust products characteristics after decades of atmospheric exposure are scarce. On the other side, generally accepted laboratory tests for the assessment of its corrosion resistance have not been developed yet. Consequently, simulating corrosion in the laboratory during long periods of time are attractive for the interesting and complete information obtainable from them. In the present work, AISI-SAE 1008 and ASTM'588 B steel samples have been exposed for two years to a immersion-emersion CEBELCOR type test in the laboratory, simulating a moderate urban atmosphere. Two groups of six samples each were tested. After the first year, three samples of each batch were retired for analysis and the rest was kept until they reached two years of exposure. The half cell electrode potentials were measured daily. The rust was characterized by metallographic techniques, Mossbauer spectroscopy (MS), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). Comparison was done with field exposure experiments reported in the literature, and conclusions on the behaviour of tested samples were drawn looking for differences and similarities with samples and structures under actual atmospheric conditions.
publishDate 2003
dc.date.issued.none.fl_str_mv 2003
dc.date.accessioned.none.fl_str_mv 2022-03-30T17:01:40Z
dc.date.available.none.fl_str_mv 2022-03-30T17:01:40Z
dc.type.spa.fl_str_mv info:eu-repo/semantics/article
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dc.type.local.spa.fl_str_mv Artículo de investigación
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status_str publishedVersion
dc.identifier.citation.spa.fl_str_mv F. Bolivar, A. Morales, y C. Arroyave, «Simulación de los procesos de corrosión atmosférica durante largos períodos de tiempo de un acero autoprotector y ordinario», revmetal, vol. 39, n.º Extra, pp. 265–269, dic. 2003.
dc.identifier.issn.none.fl_str_mv 0034-8570
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/10495/27151
dc.identifier.doi.none.fl_str_mv 10.3989/revmetalm.2003.v39.iExtra.1129
dc.identifier.eissn.none.fl_str_mv 1988-4222
identifier_str_mv F. Bolivar, A. Morales, y C. Arroyave, «Simulación de los procesos de corrosión atmosférica durante largos períodos de tiempo de un acero autoprotector y ordinario», revmetal, vol. 39, n.º Extra, pp. 265–269, dic. 2003.
0034-8570
10.3989/revmetalm.2003.v39.iExtra.1129
1988-4222
url http://hdl.handle.net/10495/27151
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartofjournalabbrev.spa.fl_str_mv Rev. Metal.
dc.rights.spa.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.uri.*.fl_str_mv http://creativecommons.org/licenses/by/2.5/co/
dc.rights.accessrights.spa.fl_str_mv http://purl.org/coar/access_right/c_abf2
dc.rights.creativecommons.spa.fl_str_mv https://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/2.5/co/
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dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Consejo Superior de Investigaciones Científicas; Centro Nacional de Investigaciones Metalúrgicas
dc.publisher.group.spa.fl_str_mv Centro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT)
Grupo de Estado Sólido
dc.publisher.place.spa.fl_str_mv Madrid, España
institution Universidad de Antioquia
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spelling Bolívar Osorio, Francisco JavierMorales Aramburo, Álvaro LuisArroyave Posada, Carlos Enrique2022-03-30T17:01:40Z2022-03-30T17:01:40Z2003F. Bolivar, A. Morales, y C. Arroyave, «Simulación de los procesos de corrosión atmosférica durante largos períodos de tiempo de un acero autoprotector y ordinario», revmetal, vol. 39, n.º Extra, pp. 265–269, dic. 2003.0034-8570http://hdl.handle.net/10495/2715110.3989/revmetalm.2003.v39.iExtra.11291988-4222ABSTRACT: Information on weathering steel behaviour and its rust products characteristics after decades of atmospheric exposure are scarce. On the other side, generally accepted laboratory tests for the assessment of its corrosion resistance have not been developed yet. Consequently, simulating corrosion in the laboratory during long periods of time are attractive for the interesting and complete information obtainable from them. In the present work, AISI-SAE 1008 and ASTM'588 B steel samples have been exposed for two years to a immersion-emersion CEBELCOR type test in the laboratory, simulating a moderate urban atmosphere. Two groups of six samples each were tested. After the first year, three samples of each batch were retired for analysis and the rest was kept until they reached two years of exposure. The half cell electrode potentials were measured daily. The rust was characterized by metallographic techniques, Mossbauer spectroscopy (MS), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). Comparison was done with field exposure experiments reported in the literature, and conclusions on the behaviour of tested samples were drawn looking for differences and similarities with samples and structures under actual atmospheric conditions.RESUMEN: La información sobre el comportamiento y las características de los productos de corrosión de los aceros auto protectores, después de varias décadas de exposición a la atmósfera, es escasa. Por otra parte, aún no se han desarrollado ensayos de laboratorio de aceptación general para evaluar su resistencia a la corrosión. En consecuencia, cada día toman más importancia los ensayos de laboratorio durante largos periodos de exposición. En el presente trabajo, se sometieron muestras de acero AISI-SAE 1008 y ASTM 588-B, durante dos años, a un ensayo de laboratorio de inmersión-emersión tipo CEBELCOR. Se ensayaron dos grupos de seis muestras de cada composición de acero, en una disolución que trataba de simular una atmósfera urbana moderada. Después del primer año, se retiraron tres muestras de cada grupo y el resto se dejo en el ensayo hasta completar los dos años exposición. Diariamente, se midió el potencial de electrodo respecto al electrodo de Calomel saturado. Las herrumbres formadas se caracterizaron mediante microscopía óptica, espectroscopia Mössbauer e infrarroja con transformada de Fourier y difracción de rayos X. Se realizó una comparación de los resultados obtenidos en este experimento con los reflejados en la literatura y se formularon conclusiones respecto a las diferencias y similitudes en su comportamiento.COL0007927COL00081387application/pdfengConsejo Superior de Investigaciones Científicas; Centro Nacional de Investigaciones MetalúrgicasCentro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT)Grupo de Estado SólidoMadrid, Españainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARTArtículo de investigaciónhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/2.5/co/http://purl.org/coar/access_right/c_abf2https://creativecommons.org/licenses/by/4.0/Simulation of a long term atmospheric corrosion process on plain and weathering steelsSimulación de los procesos de corrosión atmosférica durante largos períodos de tiempo de un acero autoprotector y ordinarioCorrosión del aceroSteel - CorrosionCorrosión del hierroIron - corrosionEspectroscopia de MossbauerMossbauer spectroscopyEnsayo de materialesMaterials - TestingRev. Metal.Revista de Metalurgia26526939ExtraORIGINALBolivarFrancisco_2003_SimulationTermAtmospheric.pdfBolivarFrancisco_2003_SimulationTermAtmospheric.pdfArtículo de investigaciónapplication/pdf1857936http://bibliotecadigital.udea.edu.co/bitstream/10495/27151/1/BolivarFrancisco_2003_SimulationTermAtmospheric.pdf5eba7ae69f1fe9304c637c1a47e66977MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8927http://bibliotecadigital.udea.edu.co/bitstream/10495/27151/2/license_rdf1646d1f6b96dbbbc38035efc9239ac9cMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://bibliotecadigital.udea.edu.co/bitstream/10495/27151/3/license.txt8a4605be74aa9ea9d79846c1fba20a33MD5310495/27151oai:bibliotecadigital.udea.edu.co:10495/271512022-03-30 12:01:40.621Repositorio Institucional Universidad de Antioquiaandres.perez@udea.edu.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