Kinetic model describing the UV/H2O2 Photodegradation of phenol From water
ABSTRACT: A kinetic model for phenol transformation through the UV/H2O2 system was developed and validated. The model includes the pollutant decomposition by direct photolysis and HO, HO2 and O2 - oxidation. HO scavenging effects of CO32-, HCO3-, SO42- and Cl- were also considered, as well as the pH...
- Autores:
-
Chica Arrieta, Edwin Lenin
Peñuela Mesa, Gustavo Antonio
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2017
- Institución:
- Universidad de Antioquia
- Repositorio:
- Repositorio UdeA
- Idioma:
- eng
- OAI Identifier:
- oai:bibliotecadigital.udea.edu.co:10495/12782
- Acceso en línea:
- http://hdl.handle.net/10495/12782
- Palabra clave:
- Nível de H2O2
Modelo cinético
Contaminación con fenol
Fotodegradación con fenol
- Rights
- openAccess
- License
- Atribución-NoComercial-SinDerivadas 2.5 Colombia
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Kinetic model describing the UV/H2O2 Photodegradation of phenol From water |
| title |
Kinetic model describing the UV/H2O2 Photodegradation of phenol From water |
| spellingShingle |
Kinetic model describing the UV/H2O2 Photodegradation of phenol From water Nível de H2O2 Modelo cinético Contaminación con fenol Fotodegradación con fenol |
| title_short |
Kinetic model describing the UV/H2O2 Photodegradation of phenol From water |
| title_full |
Kinetic model describing the UV/H2O2 Photodegradation of phenol From water |
| title_fullStr |
Kinetic model describing the UV/H2O2 Photodegradation of phenol From water |
| title_full_unstemmed |
Kinetic model describing the UV/H2O2 Photodegradation of phenol From water |
| title_sort |
Kinetic model describing the UV/H2O2 Photodegradation of phenol From water |
| dc.creator.fl_str_mv |
Chica Arrieta, Edwin Lenin Peñuela Mesa, Gustavo Antonio |
| dc.contributor.author.none.fl_str_mv |
Chica Arrieta, Edwin Lenin Peñuela Mesa, Gustavo Antonio |
| dc.subject.none.fl_str_mv |
Nível de H2O2 Modelo cinético Contaminación con fenol Fotodegradación con fenol |
| topic |
Nível de H2O2 Modelo cinético Contaminación con fenol Fotodegradación con fenol |
| description |
ABSTRACT: A kinetic model for phenol transformation through the UV/H2O2 system was developed and validated. The model includes the pollutant decomposition by direct photolysis and HO, HO2 and O2 - oxidation. HO scavenging effects of CO32-, HCO3-, SO42- and Cl- were also considered, as well as the pH changes as the process proceeds. Additionally, the detrimental action of the organic matter and reaction intermediates in shielding UV and quenching HO was incorporated. It was observed that the model can accurately predict phenol abatement using different H2O2/phenol mass ratios (495, 228 and 125), obtaining an optimal H2O2/phenol ratio of 125, leading to a phenol removal higher than 95% after 40 min of treatment, where the main oxidation species was HO. The developed model could be relevant for calculating the optimal level of H2O2 efficiently degrading the pollutant of interest, allowing saving in costs and time. |
| publishDate |
2017 |
| dc.date.issued.none.fl_str_mv |
2017 |
| dc.date.accessioned.none.fl_str_mv |
2020-01-02T13:04:33Z |
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2020-01-02T13:04:33Z |
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info:eu-repo/semantics/article |
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http://purl.org/coar/version/c_970fb48d4fbd8a86 http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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Artículo de investigación |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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Rubio, A., Chica, E. & Peñuela, G. A., (2017). Kinetic model describing the uv/h2o2 Photodegradation of phenol From water. Chemical Industry & Chemical Engineering Quarterly, 23 (4), 547−562. DOI: 10.2298/CICEQ161119008R |
| dc.identifier.issn.none.fl_str_mv |
1451-9372 |
| dc.identifier.uri.none.fl_str_mv |
http://hdl.handle.net/10495/12782 |
| dc.identifier.doi.none.fl_str_mv |
10.2298/CICEQ161119008R |
| dc.identifier.eissn.none.fl_str_mv |
2217-7434 |
| identifier_str_mv |
Rubio, A., Chica, E. & Peñuela, G. A., (2017). Kinetic model describing the uv/h2o2 Photodegradation of phenol From water. Chemical Industry & Chemical Engineering Quarterly, 23 (4), 547−562. DOI: 10.2298/CICEQ161119008R 1451-9372 10.2298/CICEQ161119008R 2217-7434 |
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http://hdl.handle.net/10495/12782 |
| dc.language.iso.spa.fl_str_mv |
eng |
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eng |
| dc.relation.ispartofjournalabbrev.spa.fl_str_mv |
Chem. Ind. Chem. Eng. Q. |
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Atribución-NoComercial-SinDerivadas 2.5 Colombia |
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info:eu-repo/semantics/openAccess |
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http://creativecommons.org/licenses/by-nc-nd/2.5/co/ |
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Atribución-NoComercial-SinDerivadas 2.5 Colombia http://creativecommons.org/licenses/by-nc-nd/2.5/co/ http://purl.org/coar/access_right/c_abf2 https://creativecommons.org/licenses/by-nc-nd/4.0/ |
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openAccess |
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15 |
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application/pdf |
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Association of the Chemical Engineers of Serbia AChE |
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Diagnóstico y Control de la Contaminación |
| dc.publisher.place.spa.fl_str_mv |
Serbia |
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Universidad de Antioquia |
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Chica Arrieta, Edwin LeninPeñuela Mesa, Gustavo Antonio2020-01-02T13:04:33Z2020-01-02T13:04:33Z2017Rubio, A., Chica, E. & Peñuela, G. A., (2017). Kinetic model describing the uv/h2o2 Photodegradation of phenol From water. Chemical Industry & Chemical Engineering Quarterly, 23 (4), 547−562. DOI: 10.2298/CICEQ161119008R1451-9372http://hdl.handle.net/10495/1278210.2298/CICEQ161119008R2217-7434ABSTRACT: A kinetic model for phenol transformation through the UV/H2O2 system was developed and validated. The model includes the pollutant decomposition by direct photolysis and HO, HO2 and O2 - oxidation. HO scavenging effects of CO32-, HCO3-, SO42- and Cl- were also considered, as well as the pH changes as the process proceeds. Additionally, the detrimental action of the organic matter and reaction intermediates in shielding UV and quenching HO was incorporated. It was observed that the model can accurately predict phenol abatement using different H2O2/phenol mass ratios (495, 228 and 125), obtaining an optimal H2O2/phenol ratio of 125, leading to a phenol removal higher than 95% after 40 min of treatment, where the main oxidation species was HO. The developed model could be relevant for calculating the optimal level of H2O2 efficiently degrading the pollutant of interest, allowing saving in costs and time.15application/pdfengAssociation of the Chemical Engineers of Serbia AChEDiagnóstico y Control de la ContaminaciónSerbiainfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARTArtículo de investigaciónhttp://purl.org/coar/version/c_970fb48d4fbd8a86http://purl.org/coar/version/c_970fb48d4fbd8a85Atribución-NoComercial-SinDerivadas 2.5 Colombiainfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/2.5/co/http://purl.org/coar/access_right/c_abf2https://creativecommons.org/licenses/by-nc-nd/4.0/Nível de H2O2Modelo cinéticoContaminación con fenolFotodegradación con fenolKinetic model describing the UV/H2O2 Photodegradation of phenol From waterChem. Ind. Chem. Eng. Q.Chemical Industry & Chemical Engineering Quarterly547562234CC-LICENSElicense_urllicense_urltext/plain; charset=utf-849http://bibliotecadigital.udea.edu.co/bitstream/10495/12782/2/license_url4afdbb8c545fd630ea7db775da747b2fMD52license_textlicense_texttext/html; charset=utf-80http://bibliotecadigital.udea.edu.co/bitstream/10495/12782/3/license_textd41d8cd98f00b204e9800998ecf8427eMD53license_rdflicense_rdfapplication/rdf+xml; charset=utf-80http://bibliotecadigital.udea.edu.co/bitstream/10495/12782/4/license_rdfd41d8cd98f00b204e9800998ecf8427eMD54LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://bibliotecadigital.udea.edu.co/bitstream/10495/12782/5/license.txt8a4605be74aa9ea9d79846c1fba20a33MD55ORIGINALRubioAinhoa_2017_Kineticmodeldescribing.pdfRubioAinhoa_2017_Kineticmodeldescribing.pdfArtículo de investigaciónapplication/pdf417059http://bibliotecadigital.udea.edu.co/bitstream/10495/12782/1/RubioAinhoa_2017_Kineticmodeldescribing.pdf8aeec245481086518744135308baa759MD5110495/12782oai:bibliotecadigital.udea.edu.co:10495/127822021-06-11 14:54:31.632Repositorio Institucional Universidad de Antioquiaandres.perez@udea.edu.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 |