Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation
ABSTRACT: Two new vanadates have been successfully synthesized by the hydrothermal and coprecipitation methods. Both vanadates were calcined at 600 °C and the resulting catalysts were tested on reaction of oxidative dehydrogenation of propane. The catalysts were characterized by x-ray diffraction, a...
- Autores:
-
Hernández Naranjo, Juan Pablo
Echavarría, Adriana
Palacio Santos, Luz Amparo
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2013
- Institución:
- Universidad de Antioquia
- Repositorio:
- Repositorio UdeA
- Idioma:
- eng
- OAI Identifier:
- oai:bibliotecadigital.udea.edu.co:10495/5441
- Acceso en línea:
- http://hdl.handle.net/10495/5441
- Palabra clave:
- Vanadio
Vanadium
Propano
Propane
Propeno
Propene; Propylene
Níquel
Nickel
Deshidrogenación oxidativa
vanadato de niquel
vanadato de cobre-niquel
Deshidrogenación
- Rights
- openAccess
- License
- http://creativecommons.org/licenses/by-nc-sa/2.5/co/
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| dc.title.spa.fl_str_mv |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| dc.title.translated.spa.fl_str_mv |
Síntesis de dos nuevos vanadatos de Níquel y Cobre-Níquel usados en la deshidrogenación oxidativa de propano |
| title |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| spellingShingle |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation Vanadio Vanadium Propano Propane Propeno Propene; Propylene Níquel Nickel Deshidrogenación oxidativa vanadato de niquel vanadato de cobre-niquel Deshidrogenación |
| title_short |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| title_full |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| title_fullStr |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| title_full_unstemmed |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| title_sort |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| dc.creator.fl_str_mv |
Hernández Naranjo, Juan Pablo Echavarría, Adriana Palacio Santos, Luz Amparo |
| dc.contributor.author.none.fl_str_mv |
Hernández Naranjo, Juan Pablo Echavarría, Adriana Palacio Santos, Luz Amparo |
| dc.contributor.researchgroup.spa.fl_str_mv |
Catalizadores y Adsorbentes |
| dc.subject.lemb.none.fl_str_mv |
Vanadio Vanadium Propano Propane Propeno Propene; Propylene Níquel Nickel |
| topic |
Vanadio Vanadium Propano Propane Propeno Propene; Propylene Níquel Nickel Deshidrogenación oxidativa vanadato de niquel vanadato de cobre-niquel Deshidrogenación |
| dc.subject.proposal.spa.fl_str_mv |
Deshidrogenación oxidativa vanadato de niquel vanadato de cobre-niquel Deshidrogenación |
| description |
ABSTRACT: Two new vanadates have been successfully synthesized by the hydrothermal and coprecipitation methods. Both vanadates were calcined at 600 °C and the resulting catalysts were tested on reaction of oxidative dehydrogenation of propane. The catalysts were characterized by x-ray diffraction, atomic absorption, thermogravimetric analysis, and differential temperature analysis. The reaction was carried out in the temperature range of 350-500 °C. A conversion of propane of 10.6 % and a selectivity towards propene of 29.9 % at 400 °C were obtained with nickel vanadate; a conversion of 1.9 % and a selectivity of 56.9 % were reached at the same temperature with the nickel copper vanadate. |
| publishDate |
2013 |
| dc.date.issued.none.fl_str_mv |
2013 |
| dc.date.accessioned.none.fl_str_mv |
2016-11-18T20:26:23Z |
| dc.date.available.none.fl_str_mv |
2016-11-18T20:26:23Z |
| dc.type.spa.fl_str_mv |
Artículo de investigación |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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https://purl.org/redcol/resource_type/ART |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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info:eu-repo/semantics/article |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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publishedVersion |
| dc.identifier.citation.spa.fl_str_mv |
J. P. Hernández, A. Echavarría and L. A. Palacio, "Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation", Rev. Fac. Ing. Univ. Antioquia, no. 67, pp. 137-145, 2013. |
| dc.identifier.issn.none.fl_str_mv |
0120-6230 |
| dc.identifier.uri.none.fl_str_mv |
http://hdl.handle.net/10495/5441 |
| dc.identifier.eissn.none.fl_str_mv |
2422-2844 |
| identifier_str_mv |
J. P. Hernández, A. Echavarría and L. A. Palacio, "Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation", Rev. Fac. Ing. Univ. Antioquia, no. 67, pp. 137-145, 2013. 0120-6230 2422-2844 |
| url |
http://hdl.handle.net/10495/5441 |
| dc.language.iso.spa.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournalabbrev.spa.fl_str_mv |
Rev. Fac. Ing. Univ. Antioquia |
| dc.relation.citationendpage.spa.fl_str_mv |
145 |
| dc.relation.citationissue.spa.fl_str_mv |
67 |
| dc.relation.citationstartpage.spa.fl_str_mv |
137 |
| dc.relation.ispartofjournal.spa.fl_str_mv |
Revista Facultad de Ingeniería |
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http://creativecommons.org/licenses/by-nc-sa/2.5/co/ |
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https://creativecommons.org/licenses/by-nc-sa/4.0/ |
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Atribución-NoComercial-CompartirIgual (CC BY-NC-SA) |
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info:eu-repo/semantics/openAccess |
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Universidad de Antioquia, Facultad de Ingeniería |
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Medellín, Colombia |
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Universidad de Antioquia |
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Hernández Naranjo, Juan PabloEchavarría, AdrianaPalacio Santos, Luz AmparoCatalizadores y Adsorbentes2016-11-18T20:26:23Z2016-11-18T20:26:23Z2013J. P. Hernández, A. Echavarría and L. A. Palacio, "Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation", Rev. Fac. Ing. Univ. Antioquia, no. 67, pp. 137-145, 2013.0120-6230http://hdl.handle.net/10495/54412422-2844ABSTRACT: Two new vanadates have been successfully synthesized by the hydrothermal and coprecipitation methods. Both vanadates were calcined at 600 °C and the resulting catalysts were tested on reaction of oxidative dehydrogenation of propane. The catalysts were characterized by x-ray diffraction, atomic absorption, thermogravimetric analysis, and differential temperature analysis. The reaction was carried out in the temperature range of 350-500 °C. A conversion of propane of 10.6 % and a selectivity towards propene of 29.9 % at 400 °C were obtained with nickel vanadate; a conversion of 1.9 % and a selectivity of 56.9 % were reached at the same temperature with the nickel copper vanadate.RESUMEN: Se probaron dos nuevos vanadatos en la deshidrogenación oxidativa de propano. Los catalizadores fueron sintetizados por el método hidrotérmico y de coprecipitación, la caracterización se llevó a cabo por medio de difracción de rayos X, absorción atómica, análisis termogravimétrico y análisis térmico diferencial. La reacción se realizó en un rango de temperatura de 350-500 °C. Con el vanadato de níquel se obtuvo una conversión de propano de 10.6 % y una selectividad hacia propeno del 29.9 % a 400 °C y con el vanadato de cobre y níquel se alcanzó a la misma temperatura una conversión de 1.9 % y una selectividad del 56.9 %COL0001923application/pdfengUniversidad de Antioquia, Facultad de IngenieríaMedellín, Colombiahttp://creativecommons.org/licenses/by-nc-sa/2.5/co/https://creativecommons.org/licenses/by-nc-sa/4.0/Atribución-NoComercial-CompartirIgual (CC BY-NC-SA)info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenationSíntesis de dos nuevos vanadatos de Níquel y Cobre-Níquel usados en la deshidrogenación oxidativa de propanoArtículo de investigaciónhttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionVanadioVanadiumPropanoPropanePropenoPropene; PropyleneNíquelNickelDeshidrogenación oxidativavanadato de niquelvanadato de cobre-niquelDeshidrogenaciónRev. Fac. Ing. Univ. 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