Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation
ABSTRACT: Two new vanadates have been successfully synthesized by the hydrothermal and coprecipitation methods. Both vanadates were calcined at 600 °C and the resulting catalysts were tested on reaction of oxidative dehydrogenation of propane. The catalysts were characterized by x-ray diffraction, a...
- Autores:
-
Hernández Naranjo, Juan Pablo
Echavarría, Adriana
Palacio Santos, Luz Amparo
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2013
- Institución:
- Universidad de Antioquia
- Repositorio:
- Repositorio UdeA
- Idioma:
- eng
- OAI Identifier:
- oai:bibliotecadigital.udea.edu.co:10495/5441
- Acceso en línea:
- http://hdl.handle.net/10495/5441
- Palabra clave:
- Vanadio
Níquel
Deshidrogenación
- Rights
- openAccess
- License
- Atribución-NoComercial-CompartirIgual (CC BY-NC-SA)
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| dc.title.spa.fl_str_mv |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| dc.title.alternative.spa.fl_str_mv |
Síntesis de dos nuevos vanadatos de Níquel y Cobre-Níquel usados en la deshidrogenación oxidativa de propano |
| title |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| spellingShingle |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation Vanadio Níquel Deshidrogenación |
| title_short |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| title_full |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| title_fullStr |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| title_full_unstemmed |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| title_sort |
Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation |
| dc.creator.fl_str_mv |
Hernández Naranjo, Juan Pablo Echavarría, Adriana Palacio Santos, Luz Amparo |
| dc.contributor.author.none.fl_str_mv |
Hernández Naranjo, Juan Pablo Echavarría, Adriana Palacio Santos, Luz Amparo |
| dc.subject.none.fl_str_mv |
Vanadio Níquel Deshidrogenación |
| topic |
Vanadio Níquel Deshidrogenación |
| description |
ABSTRACT: Two new vanadates have been successfully synthesized by the hydrothermal and coprecipitation methods. Both vanadates were calcined at 600 °C and the resulting catalysts were tested on reaction of oxidative dehydrogenation of propane. The catalysts were characterized by x-ray diffraction, atomic absorption, thermogravimetric analysis, and differential temperature analysis. The reaction was carried out in the temperature range of 350-500 °C. A conversion of propane of 10.6 % and a selectivity towards propene of 29.9 % at 400 °C were obtained with nickel vanadate; a conversion of 1.9 % and a selectivity of 56.9 % were reached at the same temperature with the nickel copper vanadate. |
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2013 |
| dc.date.issued.none.fl_str_mv |
2013 |
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2016-11-18T20:26:23Z |
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2016-11-18T20:26:23Z |
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info:eu-repo/semantics/article |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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Artículo de investigación |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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publishedVersion |
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J. P. Hernández, A. Echavarría and L. A. Palacio, "Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation", Rev. Fac. Ing. Univ. Antioquia, no. 67, pp. 137-145, 2013. |
| dc.identifier.issn.none.fl_str_mv |
0120-6230 |
| dc.identifier.uri.none.fl_str_mv |
http://hdl.handle.net/10495/5441 |
| dc.identifier.eissn.none.fl_str_mv |
2422-2844 |
| identifier_str_mv |
J. P. Hernández, A. Echavarría and L. A. Palacio, "Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation", Rev. Fac. Ing. Univ. Antioquia, no. 67, pp. 137-145, 2013. 0120-6230 2422-2844 |
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http://hdl.handle.net/10495/5441 |
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eng |
| language |
eng |
| dc.relation.ispartofjournalabbrev.spa.fl_str_mv |
Rev. Fac. Ing. Univ. Antioquia |
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Atribución-NoComercial-CompartirIgual (CC BY-NC-SA) |
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info:eu-repo/semantics/openAccess |
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application/pdf |
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Universidad de Antioquia, Facultad de Ingeniería |
| dc.publisher.group.spa.fl_str_mv |
Catalizadores y Adsorbentes |
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Medellín, Colombia |
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Universidad de Antioquia |
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Hernández Naranjo, Juan PabloEchavarría, AdrianaPalacio Santos, Luz Amparo2016-11-18T20:26:23Z2016-11-18T20:26:23Z2013J. P. Hernández, A. Echavarría and L. A. Palacio, "Synthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenation", Rev. Fac. Ing. Univ. Antioquia, no. 67, pp. 137-145, 2013.0120-6230http://hdl.handle.net/10495/54412422-2844ABSTRACT: Two new vanadates have been successfully synthesized by the hydrothermal and coprecipitation methods. Both vanadates were calcined at 600 °C and the resulting catalysts were tested on reaction of oxidative dehydrogenation of propane. The catalysts were characterized by x-ray diffraction, atomic absorption, thermogravimetric analysis, and differential temperature analysis. The reaction was carried out in the temperature range of 350-500 °C. A conversion of propane of 10.6 % and a selectivity towards propene of 29.9 % at 400 °C were obtained with nickel vanadate; a conversion of 1.9 % and a selectivity of 56.9 % were reached at the same temperature with the nickel copper vanadate.RESUMEN: Se probaron dos nuevos vanadatos en la deshidrogenación oxidativa de propano. Los catalizadores fueron sintetizados por el método hidrotérmico y de coprecipitación, la caracterización se llevó a cabo por medio de difracción de rayos X, absorción atómica, análisis termogravimétrico y análisis térmico diferencial. La reacción se realizó en un rango de temperatura de 350-500 °C. Con el vanadato de níquel se obtuvo una conversión de propano de 10.6 % y una selectividad hacia propeno del 29.9 % a 400 °C y con el vanadato de cobre y níquel se alcanzó a la misma temperatura una conversión de 1.9 % y una selectividad del 56.9 %application/pdfengUniversidad de Antioquia, Facultad de IngenieríaCatalizadores y AdsorbentesMedellín, Colombiainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARTArtículo de investigaciónhttp://purl.org/coar/version/c_970fb48d4fbd8a85Atribución-NoComercial-CompartirIgual (CC BY-NC-SA)info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-sa/2.5/co/http://purl.org/coar/access_right/c_abf2https://creativecommons.org/licenses/by-nc-sa/4.0/VanadioNíquelDeshidrogenaciónSynthesis of two new Nickel and CopperNickel vanadates used for propane oxidative dehydrogenationSíntesis de dos nuevos vanadatos de Níquel y Cobre-Níquel usados en la deshidrogenación oxidativa de propanoRev. Fac. Ing. Univ. AntioquiaRevista Facultad de Ingeniería13714567ORIGINALHernandezJuan_2013_SynthesisNickelCoppernickel.pdfHernandezJuan_2013_SynthesisNickelCoppernickel.pdfArtículo de investigaciónapplication/pdf1126574http://bibliotecadigital.udea.edu.co/bitstream/10495/5441/1/HernandezJuan_2013_SynthesisNickelCoppernickel.pdf3ecef76f2291097d70a1e9b2490f97dcMD51CC-LICENSElicense_urllicense_urltext/plain; charset=utf-849http://bibliotecadigital.udea.edu.co/bitstream/10495/5441/2/license_url4afdbb8c545fd630ea7db775da747b2fMD52license_textlicense_texttext/html; charset=utf-80http://bibliotecadigital.udea.edu.co/bitstream/10495/5441/3/license_textd41d8cd98f00b204e9800998ecf8427eMD53license_rdflicense_rdfapplication/rdf+xml; charset=utf-80http://bibliotecadigital.udea.edu.co/bitstream/10495/5441/4/license_rdfd41d8cd98f00b204e9800998ecf8427eMD54LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://bibliotecadigital.udea.edu.co/bitstream/10495/5441/5/license.txt8a4605be74aa9ea9d79846c1fba20a33MD5510495/5441oai:bibliotecadigital.udea.edu.co:10495/54412021-05-16 11:47:08.501Repositorio Institucional Universidad de Antioquiaandres.perez@udea.edu.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 |