Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use
Trabajo de investigación
- Autores:
-
Báez-Martínez, Fredy de Jesús
- Tipo de recurso:
- Fecha de publicación:
- 2022
- Institución:
- Universidad Católica de Colombia
- Repositorio:
- RIUCaC - Repositorio U. Católica
- Idioma:
- eng
- OAI Identifier:
- oai:repository.ucatolica.edu.co:10983/27874
- Acceso en línea:
- https://hdl.handle.net/10983/27874
- Palabra clave:
- RESINAS EPÓXICAS
POLÍMEROS VEGETALES
DECORACIÓN Y ORNAMENTACIÓN
Epoxy resin
Bio-resin
Epoxidized soybean oil
Decorative encapsulation
Analytical hierarchical process
Exothermic
Bubble release
- Rights
- openAccess
- License
- Copyright-Universidad Católica de Colombia, 2022
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dc.title.eng.fl_str_mv |
Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use |
title |
Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use |
spellingShingle |
Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use RESINAS EPÓXICAS POLÍMEROS VEGETALES DECORACIÓN Y ORNAMENTACIÓN Epoxy resin Bio-resin Epoxidized soybean oil Decorative encapsulation Analytical hierarchical process Exothermic Bubble release |
title_short |
Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use |
title_full |
Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use |
title_fullStr |
Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use |
title_full_unstemmed |
Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use |
title_sort |
Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use |
dc.creator.fl_str_mv |
Báez-Martínez, Fredy de Jesús |
dc.contributor.advisor.none.fl_str_mv |
Novegil-González-Anleo, Francisco Javier |
dc.contributor.author.none.fl_str_mv |
Báez-Martínez, Fredy de Jesús |
dc.subject.armarc.none.fl_str_mv |
RESINAS EPÓXICAS POLÍMEROS VEGETALES DECORACIÓN Y ORNAMENTACIÓN |
topic |
RESINAS EPÓXICAS POLÍMEROS VEGETALES DECORACIÓN Y ORNAMENTACIÓN Epoxy resin Bio-resin Epoxidized soybean oil Decorative encapsulation Analytical hierarchical process Exothermic Bubble release |
dc.subject.proposal.none.fl_str_mv |
Epoxy resin Bio-resin Epoxidized soybean oil Decorative encapsulation Analytical hierarchical process Exothermic Bubble release |
description |
Trabajo de investigación |
publishDate |
2022 |
dc.date.accessioned.none.fl_str_mv |
2022-12-15T02:40:39Z |
dc.date.available.none.fl_str_mv |
2022-12-15T02:40:39Z |
dc.date.issued.none.fl_str_mv |
2022 |
dc.type.none.fl_str_mv |
Trabajo de grado - Maestría |
dc.type.coarversion.fl_str_mv |
http://purl.org/coar/version/c_71e4c1898caa6e32 |
dc.type.coarversion.none.fl_str_mv |
http://purl.org/coar/version/c_fa2ee174bc00049f |
dc.type.content.none.fl_str_mv |
Text |
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info:eu-repo/semantics/masterThesis |
dc.type.redcol.none.fl_str_mv |
http://purl.org/redcol/resource_type/TM |
dc.identifier.citation.none.fl_str_mv |
Báez-Martínez, F. J. (2022). Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use. Tesis de Grado. Universidad Católica de Colombia. Facultad de Ingeniería. Maestría en Ingeniería y Gestión de la Innovación. Bogotá, Colombia. |
dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/10983/27874 |
identifier_str_mv |
Báez-Martínez, F. J. (2022). Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use. Tesis de Grado. Universidad Católica de Colombia. Facultad de Ingeniería. Maestría en Ingeniería y Gestión de la Innovación. Bogotá, Colombia. |
url |
https://hdl.handle.net/10983/27874 |
dc.language.iso.none.fl_str_mv |
eng |
language |
eng |
dc.relation.references.none.fl_str_mv |
ALAM, Manawwer et al. Vegetable oil based eco-friendly coating materials: A review article. In: Arabian Journal of Chemistry, 2014, vol. 7, n. 4, p. 469–479. DOI: https://doi.org/10.1016/j.arabjc.2013.12.023 ANDRADE NAVIA, Juan Manuel, RAMÍREZ PLAZAS, Elías, and ORJUELA GARZÓN, Alejandro. Vigilancia tecnológica aplicada a la cadena productiva de cacao. En: Revista Espacios, 2018, vol. 39, n. 9, p. 33-44. ARANGO ALZATE, Bibiana, TAMAYO GIRALDO, Lida, and FADUL BARBOSA, Alejandra. Vigilancia tecnológica: metodologías y aplicaciones. In: Revista Electrónica Gestión de las Personas y Tecnología, 2012, vol. 5, n. 13, p. 1-7. ARNAUD, Parent et al. Technical field A hardener for epoxy resins and its use in casting resins to form completely transparent articles. WO 2021/058574 Al WO, 2021. BALGURI, Praveen Kumar, HARRIS SAMUEL, D. G. and UDAYABHASKARARAO, Thumu. A review on mechanical properties of epoxy nanocomposites. In: Materials Today: Proceedings, 2021, vol. 44, n. 10, p. 346–355. DOI: https://doi.org/10.1016/j.matpr.2020.09.742 BARDE, Mehul. Crosslinked Polymers from Pyrolysis of Lignocellulosic Biomass. Doctoral dissertation (Philosophy). Auburn University, 2018. 166 p. BARONCINI, Elyse A. et al. Recent advances in bio-based epoxy resins and bio-based epoxy curing agents. In: Journal of Applied Polymer Science, 2016, vol. 133, n. 45. DOI: https://doi.org/10.1002/app.44103 BERNARD, Mariana. Optimización del proceso de producción de materiales entrecruzados derivados de poliésteres insaturados a partir de aceites vegetales (soja). Doctoral dissertation. Córdoba: Universidad Nacional de Córdoba, 2020. BUITELAAR, Rudolf M. and PADILLA PÉREZ, Ramón. Maquila, economic reform and corporate strategies. In: World Development, 2000, vol. 28, n. 9, p. 1627–1642. DOI: http://dx.doi.org/10.1016/S0305-750X(00)00041-3 BURTON, Bruce, ALEXANDER, David and KLEIN, Howard. Epoxy formulations using Jeffamine® polyetheramines. Huntsman Corp. 2011, 106 p. CARBELLO, Liliana. Vuelve la moda de los muebles y objetos con resina [online]. Clarín, Buenos Aires. June 10, 2019. Available at: https://www.clarin.com/arq/vuelve moda-muebles-objetos-resina_0_NLT7SKgKA.htm CHEN, Jing and TAYLOR, Ambrose C. Epoxy modified with triblock copolymers: Morphology, mechanical properties and fracture mechanisms. Journal of Materials Science, 2012, vol. 47, n. 11, p. 4546–4560. DOI: http://dx.doi.org/10.1007/s10853- 012-6313-6 CHÉRCOLES ASENSIO, Ruth. Estudio del comportamiento físico-químico de materiales poliméricos utilizados en conservación y restauración de bienes culturales. Tesis doctoral. Madrid: Universidad Complutense de Madrid, 2016. CRAGG, Tony. Signs of Life. Malaga: Publisher Cac, 2003. DAI, Xueyan, LI, Peihong, SUI, Yanlong, y ZHANG, Chunling. Thermal and flame retardant properties of intrinsic flame-retardant epoxy resin containing biphenyl structures and phosphorus. In: European Polymer Journal, 2021, vol. 147. DOI: https://doi.org/10.1016/j.eurpolymj.2021.110319 DALALAH, Doraid, AL-OQLA, Faris, and HAYAJNEH, Mohammed. Application of the Analytic Hierarchy Process (AHP) in Multi- Criteria Analysis of the Selection of Cranes. In: Jordan Journal of Mechanical and Industrial Engineering, 2010, vol. 4, n. 5, p. 567– 578. DE FREITAS KERSTING, Daniel. Avaliação de Resinas Epóxi para Fabricação de Materiais Compósitos pelo Processo de Pultrusão Daniel. Dissertação (Mestre em Engenharia). Porto Alegre: Universidade Federal Do Rio Grande Do Sul, 2004. DELOZANNE, Justine et al. Thermal oxidation of aromatic epoxy-diamine networks. In: Polymer Degradation and Stability, 2019, vol. 166, p. 174–187. DOI: https://doi.org/10.1016/j.polymdegradstab.2019.05.030 DOWN, Jane L. The yellowing of epoxy resin adhesives: Report on natural dark aging. In: Studies in Conservation, 1984, vol. 29, n. 2, p. 63–76, 1984. DOI: https://doi.org/10.2307/1506076 EDWARDS, Maury and ZHOU, Yhan. Comparative Properties of Optically Clear Epoxy Encapsulants. In: Proceedings, 2001, vol. 4436, pp. 190–197. DOI: https://doi.org/10.1117/12.451299 ELLIS, Bryan. Chemestry and Technology Epoxy Resins. Sheffield: Edited by Bryan Ellis Department of Engineering Materials University of Sheffield, 1993. ELDRIDGE, Amanda. Short Term Characteristics and Environmental Aging of Bio-Resin GFRP Tested in Tension and for. Thesis (Master, Civil Engineering). Kingston, Ontario, Canada: Queen’s University, 2013. EZZAH, Farah et al. Physicochemical, structural and mechanical evaluation of bio based epoxidized jatropha oil blended with amine-cured epoxy resin as new hybrid matrix. In: Journal of Engineering Science and Technology, 2019, vol. 14, n. 2, p. 1071–1087. GARCÍA DÍEZ, Sergio. Los polímeros en la época de difusión de estilos artísticos. En: Arte, Individuo y Sociedad, 2009, n. 21, p. 27-35. GARRIDO, Leoncio, IBARRA, Luis, and MARCO, Carlos. Ciencia y Tecnología de los materiales poliméricos. Madrid: Instituto de la Ciencia y Tecnología de Polímeros (CSIC), 2004. HAYATY, Mehran, BEHESHTY, Mohammad Hosain and ESFANDEH, Masoud. A New Approach for Determination of Gel Time of a Glass/Epoxy Prepreg. In: Journal of Applied Polymer Science, 2010, vol. 120, n. 3, p. 1483–1489. DOI: https://doi.org/10.1002/app.33251 HERNÁNDEZ BARRAGÁN, Camilo Andrés, RAMÓN VALENCIA, Bladimir A., and VALENCIA, Fabuer Ramón. Development of New Materials Based on Bio-Epoxy Resins With Natural Fibers for Automotive. In: Revista Ambiental Agua, Aire y Suelo, 2014, vol. 5, n. 2, p. 4-13. DOI: https://doi.org/10.24054/19009178.v2.n2.2014.3228 KENIG, Samuel. Processing of Polymer Nanocomposites. Hanser Publications, 2019. KISIEL, Maciej and MOSSETY-LESZCZAK, Beata. Development in liquid crystalline epoxy resins and composites – A review. In: European Polymer Journal, 2019, vol. 124. DOI: https://doi.org/10.1016/j.eurpolymj.2020.109507 KUMAR, Sudheer et al. Recent Development of Biobased Epoxy Resins: A Review. In: Polymer-Plastics Technology and Engineering, 2018, vol. 57, n. 3, p. 133–155. DOI https://doi.org/10.1080/03602559.2016.1253742 LI, Ke et al. The change of thermal-mechanical properties and chemical structure of ambient cured DGEBA/TEPA under accelerated thermo-oxidative aging. In: Polymer Degradation and Stability, 2013, vol. 98, n. 11, p. 2340–2346. DOI: http://dx.doi.org/10.1016/j.polymdegradstab.2013.08.014 LIM, Su Hyun et al. Resin impregnation and interfacial adhesion behaviors in carbon fiber/epoxy composites: Effects of polymer slip and normalized surface free energy with respect to the sizing agents. In: Composites Part A: Applied Science and Manufacturing, 2021, vol. 146. DOI: https://doi.org/10.1016/j.compositesa.2021.106424 MAHESH, Vishwas, JOLADARASHI, Sharnappa, and KULKARNI, Satyabodh. A comprehensive review on material selection for polymer matrix composites subjected to impact load. Defence Technology, 2021, vol. 17, n. 1, pp. 257–277. DOI: https://doi.org/10.1016/j.dt.2020.04.002 MASKEPATIL, Lahu P., GANDIGUDE, Ashish U. and KALE, Sandip. Selection of material for wind turbine blade by analytic hierarchy process (AHP) method. In: Applied Mechanics and Materials, 2014, vol. 612, p. 145–150. DOI: http://dx.doi.org/10.4028/www.scientific.net/AMM.612.145 MAY, Clayton. Epoxy resins: Chemistry and technology. CRC Press, 1987. MCQUARRIE, Terry S., SUTTON, Martin y GERMANOV, Yaroslav. Pultrudable bio-based epoxy resins. CAMX 2020, 2021. MONTESERÍN VILELA, Cristina. Estrategias para la Mejora de las Prestaciones de Materiales Compuestos. Doctoral Thesis. Universidad del País Vasco, 2017. MORAN, Christopher S. Design and Characterization of Bio-Based Polymer Blends and Composites. Doctoral dissertation. Golden: Colorado School, 2017. MORANCHO LLENA, José María. Estudio del curado de materiales compuestos por un sistema epoxi y partículas elastoméricas. Tesis. Barcelona: Universitat Politècnica de Catalunya, 1996. 140 p. MORSCH, Suzanne et al. Examining the early stages of thermal oxidative degradation in epoxy-amine resins. In: Polymer Degradation and Stability, 2020, vol. 176. DOI: https://doi.org/10.1016/j.polymdegradstab.2020.109147 MUÑOZ DOMÍNGUEZ, Eva. Fabricación y caracterización de green composites con bioresina y tejido de fibra natural de lino mediante moldeo por transferencia de resina. Tesis (Doctorado en Ingeniería Industrial). Universitat Politècnica de València, Valencia, 2012. 367 p. NATIONAL RESEARCH COUNCIL et al. Polymer Science and Engineering: The Shifting. Washington, D.C.: National Academies Press, 1994. NEGOITA, Cătălin, CRISTACHE, Nicoleta and BODOR, Marius. The epoxy resin - History and perspectives. In: Materiale Plastice, 2016, vol. 53, n. 3, p. 564–571. NIKAFSHAR, Saeid et al. The effects of UV light on the chemical and mechanical properties of a transparent epoxy-diamine system in the presence of an organic UV absorber. In: Materials (Basel), 2017, vol. 10, n. 2, p. 1–18. DOI: https://doi.org/10.3390/ma10020180 OKOKPUJIE, Imhade et al. Implementation of multi-criteria decision method for selection of suitable material for development of horizontal wind turbine blade for sustainable energy generation. In: Heliyon, 2020, vol. 6, n. 1. DOI: https://doi.org/10.1016/j.heliyon.2019.e03142 OLIVEIRA, Alexsandro. Efeito da utilização de aditivos desaerantes nas características da resina epóxi e de compósitos com fibras de vidro. Dissertação (Mestre em Engenharia). Porto Alegre: Universidade Federal Do Rio Grande Do Sul Escola de Engenharia, 2012. ORTIZ, Pablo, WIEKAMP, Martijn, VENDAMME, Richard and EEVERS, Walter. Bio-based epoxy resins from biorefinery by-products. En: BioResources, 2019, vol. 14, n. 2, p. 3200–3209. OSORIO GÓMEZ, Juan Carlos and OREJUELA CABRERA, Juan Pablo. El proceso de análisis jerárquico y la toma de decisiones multicriterio. In: Scientia et Technica, 2008, vol. 2, n. 39, p. 247–252. DOI: https://doi.org/10.22517/23447214.3217 PALET CASAS, Antoni. Identificación Química de Pigmentos Artísticos, 1st ed. Barcelona: Universidad de Barcelona, 1997. PETRIE, Edward. Epoxy Adhesive Formulations. New York: McGraw-Hill, 2006. PÉREZ TREJO, Leonor, MÉNDEZ SÁNCHEZ, Arturo, and PANIAGUA MERCADO, Ana María. Determinación de la viscosidad de fluidos newtonianos y no newtonianos (una revisión del viscosímetro de Couette). In: Latin-American Journal of Physics Education, 2010, vol. 4, n. 1, p. 237-245. POYNTON, Gary.Multi ‐ component Epoxy Resin Formulation for High Temperature Applications. Thesis (Doctor of Philosophy). School of Materials, 2014. QUISPE LOYOLA, César Raúl. Aplicación del proceso analítico jerárquico (AHP) en la selección de un marco de referencia para gestionar los proyectos de una empresa consultora. Thesis. Lima: Universidad Nacional Mayor de San Marcos, 2017. RAD, Elaheh Rohani et al. Bio-epoxy resins with inherent flame retardancy. In: Progress in Organic Coatings, 2019, vol. 135, p. 608–612. DOI: https://doi.org/10.1016/j.porgcoat.2019.05.046 RAD, Elaheh Rohani et al. Bio-epoxy resins with inherent flame retardancy. In: Progress in Organic Coatings, 2019, vol. 135, p. 608–612. DOI: https://doi.org/10.1016/j.porgcoat.2019.05.046 RESINAS CASTRO. GAMA WWA Sistemas de resina epoxi transparente de colada. España: Resoltech. 2017, 8 p. RIMDUSIT, Sarawut and ISHIDA, Hatsuo. Development of new class of electronic packaging materials based on ternary systems of benzoxazine, epoxy, and phenolic resins. In: Polymer, 2000, vol. 41, n. 22, p. 7941–7949. DOI: http://dx.doi.org/10.1016/S0032-3861(00)00164-6 ROJAS MORALES, Mallerly and TORRES GÓMEZ, David Alexander. Evaluación para la obtención de resina epóxica a partir de aceite de ricino a nivel laboratorio. Tesis (Ingeniería Química). Fundación Universidad de América, Bogotá, 2016. 78 p. RUAN, Kunpeng et al. Liquid crystal epoxy resins with high intrinsic thermal conductivities and their composites: A mini-review. In: Materials Today Physics, 2021, vol. 20. DOI: https://doi.org/10.1016/j.mtphys.2021.100456 SAATY, Thomas L. The Analytical Hierarchy Process. New York: McGraw-Hill, 1980. SAHOO, Sushanta K. and MOHANTY, Smita y NAYAK, Sanjay K. Synthesis and characterization of bio-based epoxy blends from renewable resource based epoxidized soybean oil as reactive diluent. In: Chinese Journal of Polymer Sciences, 2015, vol. 33, n. 1, pp. 137–152. DOI: http://dx.doi.org/10.1007/s10118-015-1568-4 SAMPER, María Dolores et al.. Properties of biobased epoxy resins from epoxidized linseed oil (ELO) crosslinked with a mixture of cyclic anhydride and maleinized linseed oil. In: Express Polymer Letters, 2019, vol. 13, n. 5, p. 407–418. DOI: http://doi.org/10.3144/expresspolymlett.2019.34 SANDINO VARGAS, Enrique. A strategy to meet: UK is trying to innovate in terms of competitiveness, 1998-2005. En: Revista Científica General José María Córdova, 2014, vol. 12, n. 13, p. 205–258. SANTANDREU, Martha et al. Amperometric immunosensors based on rigid conducting immunocomposites. In: Analyticalo Chemistry, 1997, vol. 69, n. 12, p. 2080–2085. DOI: https://doi.org/10.1021/ac961222b SAWHNEY, Anil and MUND, André. Adaptive Probabilistic Neural Network-based Crane Type Selection System. In: Journal of Construction Engineering and Management, 2002, vol. 128, n. 3, p. 265–273. DOI: https://doi.org/10.1061/(ASCE)0733- 9364(2002)128:3(265 SHAHARI, Shazzuan et al. Recent developments in fire retardant glass fibre reinforced epoxy composite and geopolymer as a potential fire-retardant material: A review. In: Construction and Building Materials, 2021, vol. 277. DOI: https://doi.org/10.1016/j.conbuildmat.2021.122246 SHIH, Meng-Jung, LIU, Duen-Ruen, and HSU, Ming-Li. Discovering competitive intelligence by mining changes in patent trends. In: Expert Systems with Applications, 2010, vol. 37, n. 4, p. 2882–2890. DOI: http://dx.doi.org/10.1016/j.eswa.2009.09.001 SUNG, Jonggeun. Soybean Oil Based Resin for Transparent Flexible Coating Applications. Thesis (Master of Science). Manhattan: Kansas State University, 2014. TENG, Na et al. Hyperbranched flame retardant to simultaneously improve the fire safety, toughness and glass transition temperature of epoxy resin. In: European Polymer Journal, 2021, vol. 157. DOI: https://doi.org/10.1016/j.eurpolymj.2021.110638 UCLES, Ena. Criterio de selección de materiales. 2015. Available at: https://es.slideshare.net/EnaUcles1/criterio-de-seleccion-de-los-materiales WANG, Rongpeng and SCHUMAN, Thomas. Vegetable oil-derived epoxy monomers and polymer blends: A comparative study with review. In: Express Polymer Letters, 2012, vol. 7, n. 3, p. 272–292, 2012. DOI: http://dx.doi.org/10.3144/expresspolymlett.2013.25 WEI, Xiong y YALUN, Wang. Epoxy resin lamps base design based on users emotional needs, vol. 774. Springer International Publishing, 2019. WOOL, Richard and SUN, X. Susan. Bio-based polymers and composites, 1st ed. Amsterdam, Boston: Elsevier Academic Press, 2005. YANG, Guozhen et al. Biorenewable Epoxy Resins Derived from Plant-Based Phenolic Acids. In: ACS Sustainable Chemistry, 2016, vol. 4, n. 12, p. 6524–6533. DOI: https://doi.org/10.1021/acssuschemeng.6b01343 YATAGANBABA, Alptug and KURTBAŞ, İrfan. A scientific approach with bibliometric analysis related to brick and tile drying: A review. In: Renewable and Sustainable Energy Reviews, 2016, vol. 59, p. 206–224. DOI: https://doi.org/10.1016/j.rser.2015.12.357 YUE, Liang. Biobased Epoxy Composites Sustainable Alternative for Advanced Materials. Doctoral Dissertation. Case Western Reserve University, 2018. 162 p. ZANGENEH, Ali, JADID, Shahram and RAHIMI-KIAN, Ashkan. A hierarchical decision making model for the prioritization of distributed generation technologies: A case study for Iran. In: Energy Policy, 2009, vol. 37, n. 12, p. 5752–5763. DOI: https://doi.org/10.1016/j.enpol.2009.08.045 ZEGARRA BASURCO, Mirtha Rocío. Preparación De Compuestos Epóxicos. Thesis. Lima: Universidad Nacional de Ingeniería, 2006. |
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Novegil-González-Anleo, Francisco Javierb5f5ab45-e17f-4756-9067-33d065725ce8Báez-Martínez, Fredy de Jesúsc132fba3-64d5-42ca-bc68-e18a354851b7-12022-12-15T02:40:39Z2022-12-15T02:40:39Z2022Trabajo de investigaciónThis project studies the formulation of an epoxy system for use in artistic encapsulation applications, with eye-catching and customized finishes. The motivation stems from the need to solve some of the problems of epoxy systems, such as their high reactivity and exothermicity, which limit the mixing quantities and, consequently, the ability to obtain adequate thicknesses per applied layer. (Tomado de la fuente).Este proyecto de grado estudia la formulación de un sistema epóxico para su uso en aplicaciones de encapsulados artísticos y para atender la creciente demanda de materiales versátiles, fáciles de aplicar, con acabados llamativos y personalizados. La motivación de este trabajo nace de la necesidad de dar solución a algunos de los problemas de los sistemas epóxicos, como su alta reactividad y exotermia, que limitan las cantidades de mezcla y, consecuentemente, la capacidad de obtener espesores adecuados por capa aplicada. (Tomado de la fuente).MaestríaMagíster en Ingeniería y Gestión de la InnovaciónINTRODUCTION 1 PROBLEM STATEMENT 2 OBJECTIVES 3 CONCEPTUAL FRAMEWORK 4 THEORETICAL FRAMEWORK 5 STATE OF THE ART 6 MATERIALS AND METHODOLOGY 7 PROJECT DEVELOPMENT 8 RESULTS 9 VALIDATION (PILOT TESTING) 10 DESCRIPTION OF THE PROJECT 11 CONCLUSIONS AND FUTURE WORKS BIBLIOGRAPHY ANNEXES150 páginasapplication/pdfBáez-Martínez, F. J. (2022). Development of an epoxy-bio-epoxy system and its use in the construction of encapsulated elements for decorative use. Tesis de Grado. Universidad Católica de Colombia. Facultad de Ingeniería. Maestría en Ingeniería y Gestión de la Innovación. Bogotá, Colombia.https://hdl.handle.net/10983/27874engUniversidad Católica de ColombiaFacultad de IngenieríasBogotáMaestría en Ingeniería y Gestión de la InnovaciónALAM, Manawwer et al. Vegetable oil based eco-friendly coating materials: A review article. In: Arabian Journal of Chemistry, 2014, vol. 7, n. 4, p. 469–479. DOI: https://doi.org/10.1016/j.arabjc.2013.12.023ANDRADE NAVIA, Juan Manuel, RAMÍREZ PLAZAS, Elías, and ORJUELA GARZÓN, Alejandro. Vigilancia tecnológica aplicada a la cadena productiva de cacao. En: Revista Espacios, 2018, vol. 39, n. 9, p. 33-44.ARANGO ALZATE, Bibiana, TAMAYO GIRALDO, Lida, and FADUL BARBOSA, Alejandra. Vigilancia tecnológica: metodologías y aplicaciones. In: Revista Electrónica Gestión de las Personas y Tecnología, 2012, vol. 5, n. 13, p. 1-7.ARNAUD, Parent et al. Technical field A hardener for epoxy resins and its use in casting resins to form completely transparent articles. WO 2021/058574 Al WO, 2021.BALGURI, Praveen Kumar, HARRIS SAMUEL, D. G. and UDAYABHASKARARAO, Thumu. A review on mechanical properties of epoxy nanocomposites. In: Materials Today: Proceedings, 2021, vol. 44, n. 10, p. 346–355. DOI: https://doi.org/10.1016/j.matpr.2020.09.742BARDE, Mehul. Crosslinked Polymers from Pyrolysis of Lignocellulosic Biomass. Doctoral dissertation (Philosophy). Auburn University, 2018. 166 p.BARONCINI, Elyse A. et al. Recent advances in bio-based epoxy resins and bio-based epoxy curing agents. In: Journal of Applied Polymer Science, 2016, vol. 133, n. 45. DOI: https://doi.org/10.1002/app.44103BERNARD, Mariana. Optimización del proceso de producción de materiales entrecruzados derivados de poliésteres insaturados a partir de aceites vegetales (soja). Doctoral dissertation. Córdoba: Universidad Nacional de Córdoba, 2020.BUITELAAR, Rudolf M. and PADILLA PÉREZ, Ramón. Maquila, economic reform and corporate strategies. In: World Development, 2000, vol. 28, n. 9, p. 1627–1642. 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Thermal and flame retardant properties of intrinsic flame-retardant epoxy resin containing biphenyl structures and phosphorus. In: European Polymer Journal, 2021, vol. 147. DOI: https://doi.org/10.1016/j.eurpolymj.2021.110319DALALAH, Doraid, AL-OQLA, Faris, and HAYAJNEH, Mohammed. Application of the Analytic Hierarchy Process (AHP) in Multi- Criteria Analysis of the Selection of Cranes. In: Jordan Journal of Mechanical and Industrial Engineering, 2010, vol. 4, n. 5, p. 567– 578.DE FREITAS KERSTING, Daniel. Avaliação de Resinas Epóxi para Fabricação de Materiais Compósitos pelo Processo de Pultrusão Daniel. Dissertação (Mestre em Engenharia). Porto Alegre: Universidade Federal Do Rio Grande Do Sul, 2004.DELOZANNE, Justine et al. Thermal oxidation of aromatic epoxy-diamine networks. In: Polymer Degradation and Stability, 2019, vol. 166, p. 174–187. DOI: https://doi.org/10.1016/j.polymdegradstab.2019.05.030DOWN, Jane L. 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Los polímeros en la época de difusión de estilos artísticos. En: Arte, Individuo y Sociedad, 2009, n. 21, p. 27-35.GARRIDO, Leoncio, IBARRA, Luis, and MARCO, Carlos. Ciencia y Tecnología de los materiales poliméricos. Madrid: Instituto de la Ciencia y Tecnología de Polímeros (CSIC), 2004.HAYATY, Mehran, BEHESHTY, Mohammad Hosain and ESFANDEH, Masoud. A New Approach for Determination of Gel Time of a Glass/Epoxy Prepreg. In: Journal of Applied Polymer Science, 2010, vol. 120, n. 3, p. 1483–1489. DOI: https://doi.org/10.1002/app.33251HERNÁNDEZ BARRAGÁN, Camilo Andrés, RAMÓN VALENCIA, Bladimir A., and VALENCIA, Fabuer Ramón. Development of New Materials Based on Bio-Epoxy Resins With Natural Fibers for Automotive. In: Revista Ambiental Agua, Aire y Suelo, 2014, vol. 5, n. 2, p. 4-13. DOI: https://doi.org/10.24054/19009178.v2.n2.2014.3228KENIG, Samuel. Processing of Polymer Nanocomposites. Hanser Publications, 2019.KISIEL, Maciej and MOSSETY-LESZCZAK, Beata. Development in liquid crystalline epoxy resins and composites – A review. In: European Polymer Journal, 2019, vol. 124. DOI: https://doi.org/10.1016/j.eurpolymj.2020.109507KUMAR, Sudheer et al. Recent Development of Biobased Epoxy Resins: A Review. In: Polymer-Plastics Technology and Engineering, 2018, vol. 57, n. 3, p. 133–155. DOI https://doi.org/10.1080/03602559.2016.1253742LI, Ke et al. The change of thermal-mechanical properties and chemical structure of ambient cured DGEBA/TEPA under accelerated thermo-oxidative aging. In: Polymer Degradation and Stability, 2013, vol. 98, n. 11, p. 2340–2346. DOI: http://dx.doi.org/10.1016/j.polymdegradstab.2013.08.014LIM, Su Hyun et al. Resin impregnation and interfacial adhesion behaviors in carbon fiber/epoxy composites: Effects of polymer slip and normalized surface free energy with respect to the sizing agents. In: Composites Part A: Applied Science and Manufacturing, 2021, vol. 146. DOI: https://doi.org/10.1016/j.compositesa.2021.106424MAHESH, Vishwas, JOLADARASHI, Sharnappa, and KULKARNI, Satyabodh. A comprehensive review on material selection for polymer matrix composites subjected to impact load. Defence Technology, 2021, vol. 17, n. 1, pp. 257–277. DOI: https://doi.org/10.1016/j.dt.2020.04.002MASKEPATIL, Lahu P., GANDIGUDE, Ashish U. and KALE, Sandip. Selection of material for wind turbine blade by analytic hierarchy process (AHP) method. In: Applied Mechanics and Materials, 2014, vol. 612, p. 145–150. DOI: http://dx.doi.org/10.4028/www.scientific.net/AMM.612.145MAY, Clayton. Epoxy resins: Chemistry and technology. CRC Press, 1987.MCQUARRIE, Terry S., SUTTON, Martin y GERMANOV, Yaroslav. Pultrudable bio-based epoxy resins. CAMX 2020, 2021.MONTESERÍN VILELA, Cristina. Estrategias para la Mejora de las Prestaciones de Materiales Compuestos. Doctoral Thesis. Universidad del País Vasco, 2017.MORAN, Christopher S. Design and Characterization of Bio-Based Polymer Blends and Composites. Doctoral dissertation. Golden: Colorado School, 2017.MORANCHO LLENA, José María. Estudio del curado de materiales compuestos por un sistema epoxi y partículas elastoméricas. Tesis. Barcelona: Universitat Politècnica de Catalunya, 1996. 140 p.MORSCH, Suzanne et al. Examining the early stages of thermal oxidative degradation in epoxy-amine resins. In: Polymer Degradation and Stability, 2020, vol. 176. DOI: https://doi.org/10.1016/j.polymdegradstab.2020.109147MUÑOZ DOMÍNGUEZ, Eva. Fabricación y caracterización de green composites con bioresina y tejido de fibra natural de lino mediante moldeo por transferencia de resina. Tesis (Doctorado en Ingeniería Industrial). Universitat Politècnica de València, Valencia, 2012. 367 p.NATIONAL RESEARCH COUNCIL et al. Polymer Science and Engineering: The Shifting. Washington, D.C.: National Academies Press, 1994.NEGOITA, Cătălin, CRISTACHE, Nicoleta and BODOR, Marius. The epoxy resin - History and perspectives. In: Materiale Plastice, 2016, vol. 53, n. 3, p. 564–571.NIKAFSHAR, Saeid et al. The effects of UV light on the chemical and mechanical properties of a transparent epoxy-diamine system in the presence of an organic UV absorber. In: Materials (Basel), 2017, vol. 10, n. 2, p. 1–18. DOI: https://doi.org/10.3390/ma10020180OKOKPUJIE, Imhade et al. Implementation of multi-criteria decision method for selection of suitable material for development of horizontal wind turbine blade for sustainable energy generation. In: Heliyon, 2020, vol. 6, n. 1. DOI: https://doi.org/10.1016/j.heliyon.2019.e03142OLIVEIRA, Alexsandro. Efeito da utilização de aditivos desaerantes nas características da resina epóxi e de compósitos com fibras de vidro. Dissertação (Mestre em Engenharia). Porto Alegre: Universidade Federal Do Rio Grande Do Sul Escola de Engenharia, 2012.ORTIZ, Pablo, WIEKAMP, Martijn, VENDAMME, Richard and EEVERS, Walter. Bio-based epoxy resins from biorefinery by-products. En: BioResources, 2019, vol. 14, n. 2, p. 3200–3209.OSORIO GÓMEZ, Juan Carlos and OREJUELA CABRERA, Juan Pablo. El proceso de análisis jerárquico y la toma de decisiones multicriterio. In: Scientia et Technica, 2008, vol. 2, n. 39, p. 247–252. DOI: https://doi.org/10.22517/23447214.3217PALET CASAS, Antoni. Identificación Química de Pigmentos Artísticos, 1st ed. Barcelona: Universidad de Barcelona, 1997.PETRIE, Edward. Epoxy Adhesive Formulations. New York: McGraw-Hill, 2006.PÉREZ TREJO, Leonor, MÉNDEZ SÁNCHEZ, Arturo, and PANIAGUA MERCADO, Ana María. Determinación de la viscosidad de fluidos newtonianos y no newtonianos (una revisión del viscosímetro de Couette). In: Latin-American Journal of Physics Education, 2010, vol. 4, n. 1, p. 237-245.POYNTON, Gary.Multi ‐ component Epoxy Resin Formulation for High Temperature Applications. Thesis (Doctor of Philosophy). School of Materials, 2014.QUISPE LOYOLA, César Raúl. Aplicación del proceso analítico jerárquico (AHP) en la selección de un marco de referencia para gestionar los proyectos de una empresa consultora. Thesis. Lima: Universidad Nacional Mayor de San Marcos, 2017.RAD, Elaheh Rohani et al. Bio-epoxy resins with inherent flame retardancy. In: Progress in Organic Coatings, 2019, vol. 135, p. 608–612. DOI: https://doi.org/10.1016/j.porgcoat.2019.05.046RAD, Elaheh Rohani et al. Bio-epoxy resins with inherent flame retardancy. In: Progress in Organic Coatings, 2019, vol. 135, p. 608–612. DOI: https://doi.org/10.1016/j.porgcoat.2019.05.046RESINAS CASTRO. GAMA WWA Sistemas de resina epoxi transparente de colada. España: Resoltech. 2017, 8 p.RIMDUSIT, Sarawut and ISHIDA, Hatsuo. Development of new class of electronic packaging materials based on ternary systems of benzoxazine, epoxy, and phenolic resins. In: Polymer, 2000, vol. 41, n. 22, p. 7941–7949. 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