Identificación y cuantificación de contaminantes de preocupación emergente en núcleos sedimentarios del embalse de Tominé

Given the risks associated with the presence in the environment of the pharmaceutical compounds Sulfamethoxazole (SMX), Trimethoprim (TMP) and Diclofenac (DCF), considered of emerging concern, it is necessary to monitor and regulate the use and deposition of these contaminants in different matrices,...

Full description

Autores:
Barreneche Vasquez, Johan Sebastian
Tipo de recurso:
Trabajo de grado de pregrado
Fecha de publicación:
2021
Institución:
Universidad Antonio Nariño
Repositorio:
Repositorio UAN
Idioma:
spa
OAI Identifier:
oai:repositorio.uan.edu.co:123456789/6373
Acceso en línea:
http://repositorio.uan.edu.co/handle/123456789/6373
Palabra clave:
Núcleo sedimentario
Cuantificación
Contaminantes de preocupación emergente
Drogas
Riesgo ambiental
540
Sedimentary core
Quantification
Contaminants of emerging concern
Drugs
Environmental risk
Rights
openAccess
License
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
Description
Summary:Given the risks associated with the presence in the environment of the pharmaceutical compounds Sulfamethoxazole (SMX), Trimethoprim (TMP) and Diclofenac (DCF), considered of emerging concern, it is necessary to monitor and regulate the use and deposition of these contaminants in different matrices, like sediment. For this reason, SMX, TMP and DCF were identified and quantified in a sedimentary core extracted from the Tominé reservoir (Cundinamarca-Colombia), using the ultrasound-assisted solid phase extraction technique to extract and concentrate these pollutants. Identification and quantification was carried out by high performance liquid chromatography with mass spectrometry. The three pharmaceutical compounds were detected throughout the core at concentrations between 16.05 - 4.43 ng / g, 13.39 - 10.77 ng / g and 26.40 - 17.33 ng / g for SMX, TMP and DCF respectively, which indicates the entry and accumulation of these compounds. In the sediments, being proof of the continuous use and disposal of SMX, TMP and DCF, which can enter the ecosystem by runoff and by catchment sources of the reservoir. In the same way, other parameters were established in the sedimentary core, such as organic matter and granulometry, which may be involved in the mobility of organic pollutants, their adsorption and bioavailability. Additionally, together with the analysis of the activity of 210Pb, they allowed to corroborate that the core has adequate conditions to be dated.