Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2

En este trabajo se tomó una muestra de poliestireno expandido (EPS) de una matriz de residuos sólidos, este material se utilizó como materia prima para la síntesis de poliamino estireno (PSNH2) en un proceso de dos pasos. Primero, se llevó a cabo la nitración de PS para obtener polinitro estireno (P...

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Autores:
Murcia Patiño, Andrés Felipe
Tipo de recurso:
Masters Thesis
Fecha de publicación:
2019
Institución:
Universidad Santo Tomás
Repositorio:
Universidad Santo Tomás
Idioma:
spa
OAI Identifier:
oai:repository.usta.edu.co:11634/16630
Acceso en línea:
http://hdl.handle.net/11634/16630
Palabra clave:
CO2 capture
Expanded polystyrene
Nitration
Polyamine styrene
Reduction of NO2
Urban solid waste
Poliestireno
Conversión de residuos
Nitración
Captura de CO2
Nitración
Poliestireno expandido
Poliamino estireno
Reducción de grupos NO2
Residuos sólidos urbanos
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openAccess
License
Atribución-NoComercial-SinDerivadas 2.5 Colombia
id SantoToma2_9d4c17b3a899654fcef9de0324cdd056
oai_identifier_str oai:repository.usta.edu.co:11634/16630
network_acronym_str SantoToma2
network_name_str Universidad Santo Tomás
repository_id_str
dc.title.spa.fl_str_mv Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2
title Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2
spellingShingle Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2
CO2 capture
Expanded polystyrene
Nitration
Polyamine styrene
Reduction of NO2
Urban solid waste
Poliestireno
Conversión de residuos
Nitración
Captura de CO2
Nitración
Poliestireno expandido
Poliamino estireno
Reducción de grupos NO2
Residuos sólidos urbanos
title_short Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2
title_full Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2
title_fullStr Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2
title_full_unstemmed Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2
title_sort Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2
dc.creator.fl_str_mv Murcia Patiño, Andrés Felipe
dc.contributor.advisor.spa.fl_str_mv Merchán Arenas, Diego Rolando
dc.contributor.author.spa.fl_str_mv Murcia Patiño, Andrés Felipe
dc.subject.keyword.spa.fl_str_mv CO2 capture
Expanded polystyrene
Nitration
Polyamine styrene
Reduction of NO2
Urban solid waste
topic CO2 capture
Expanded polystyrene
Nitration
Polyamine styrene
Reduction of NO2
Urban solid waste
Poliestireno
Conversión de residuos
Nitración
Captura de CO2
Nitración
Poliestireno expandido
Poliamino estireno
Reducción de grupos NO2
Residuos sólidos urbanos
dc.subject.lemb.spa.fl_str_mv Poliestireno
Conversión de residuos
Nitración
dc.subject.proposal.spa.fl_str_mv Captura de CO2
Nitración
Poliestireno expandido
Poliamino estireno
Reducción de grupos NO2
Residuos sólidos urbanos
description En este trabajo se tomó una muestra de poliestireno expandido (EPS) de una matriz de residuos sólidos, este material se utilizó como materia prima para la síntesis de poliamino estireno (PSNH2) en un proceso de dos pasos. Primero, se llevó a cabo la nitración de PS para obtener polinitro estireno (PSNO2) con un rendimiento de 10.18 % en función de grupos NO2 obtenidos. Seguidamente, el PSNO2 se redujo utilizando HCl/Sn, con un rendimiento del 50 % en función de grupos NO2 reducidos del precursor. La materia prima, el precursor y el producto final obtenido se caracterizaron mediante técnicas analíticas como IR, 1H-RMN, SEM-EDS y TGA. Con el material en nuestras manos, se evaluó su actividad de captura de CO2, obteniendo una capacidad de adsorción de 1.05 mmol g-1 de PSNH2.
publishDate 2019
dc.date.accessioned.spa.fl_str_mv 2019-05-11T01:26:28Z
dc.date.available.spa.fl_str_mv 2019-05-11T01:26:28Z
dc.date.issued.spa.fl_str_mv 2019-05-09
dc.type.local.spa.fl_str_mv Tesis de maestría
dc.type.version.none.fl_str_mv info:eu-repo/semantics/acceptedVersion
dc.type.category.spa.fl_str_mv Formación de Recurso Humano para la Ctel: Trabajo de grado de Maestría
dc.type.coar.none.fl_str_mv http://purl.org/coar/resource_type/c_bdcc
dc.type.drive.none.fl_str_mv info:eu-repo/semantics/masterThesis
format http://purl.org/coar/resource_type/c_bdcc
status_str acceptedVersion
dc.identifier.citation.spa.fl_str_mv Murcia Patiño, A. F. (2019). Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2 [Tesis de Maestría]. Universidad Santo Tomás, Bucaramanga, Colombia
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/11634/16630
dc.identifier.reponame.spa.fl_str_mv reponame:Repositorio Institucional Universidad Santo Tomás
dc.identifier.instname.spa.fl_str_mv instname:Universidad Santo Tomás
dc.identifier.repourl.spa.fl_str_mv repourl:https://repository.usta.edu.co
identifier_str_mv Murcia Patiño, A. F. (2019). Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2 [Tesis de Maestría]. Universidad Santo Tomás, Bucaramanga, Colombia
reponame:Repositorio Institucional Universidad Santo Tomás
instname:Universidad Santo Tomás
repourl:https://repository.usta.edu.co
url http://hdl.handle.net/11634/16630
dc.language.iso.spa.fl_str_mv spa
language spa
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spelling Merchán Arenas, Diego RolandoMurcia Patiño, Andrés Felipe2019-05-11T01:26:28Z2019-05-11T01:26:28Z2019-05-09Murcia Patiño, A. F. (2019). Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2 [Tesis de Maestría]. Universidad Santo Tomás, Bucaramanga, Colombiahttp://hdl.handle.net/11634/16630reponame:Repositorio Institucional Universidad Santo Tomásinstname:Universidad Santo Tomásrepourl:https://repository.usta.edu.coEn este trabajo se tomó una muestra de poliestireno expandido (EPS) de una matriz de residuos sólidos, este material se utilizó como materia prima para la síntesis de poliamino estireno (PSNH2) en un proceso de dos pasos. Primero, se llevó a cabo la nitración de PS para obtener polinitro estireno (PSNO2) con un rendimiento de 10.18 % en función de grupos NO2 obtenidos. Seguidamente, el PSNO2 se redujo utilizando HCl/Sn, con un rendimiento del 50 % en función de grupos NO2 reducidos del precursor. La materia prima, el precursor y el producto final obtenido se caracterizaron mediante técnicas analíticas como IR, 1H-RMN, SEM-EDS y TGA. Con el material en nuestras manos, se evaluó su actividad de captura de CO2, obteniendo una capacidad de adsorción de 1.05 mmol g-1 de PSNH2.A sample of expanded polystyrene (EPS) was isolated from a whole solid waste sample as raw material, for the synthesis of the polyamino styrene (PSNH2) in a two steps process. Initially, it was carried out the nitration of PS to obtain polynitro styrene (PSNO2) in a 10.18 % of yield according to the NO2 groups obtained. Afterwards, PSNO2 was reduced using HCl/Sn conditions, to obtain the PSNH2 in 50 % yield according to the reduction of NO2 groups of the precursor. Raw material, intermediary and the final product were completely characterized by chemical analytical techniques. With the new material in hands, it was used as solid support to CO2 capture, showing an adsorption capacity of 1.05 mmol g-1 of PSNH2.Magister en Ciencias y Tecnologías Ambientaleshttp://www.ustabuca.edu.co/ustabmanga/presentacionMaestríaapplication/pdfspaUniversidad Santo TomásMaestría Ciencias y Tecnologías AmbientalesFacultad de Química AmbientalAtribución-NoComercial-SinDerivadas 2.5 Colombiahttp://creativecommons.org/licenses/by-nc-nd/2.5/co/Abierto (Texto Completo)info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Síntesis de Poliamino Estireno a Partir de Residuos Sólidos de Poliestireno Expandido y su Potencial Aplicación Como Secuestrante de CO2CO2 captureExpanded polystyreneNitrationPolyamine styreneReduction of NO2Urban solid wastePoliestirenoConversión de residuosNitraciónCaptura de CO2NitraciónPoliestireno expandidoPoliamino estirenoReducción de grupos NO2Residuos sólidos urbanosTesis de maestríainfo:eu-repo/semantics/acceptedVersionFormación de Recurso Humano para la Ctel: Trabajo de grado de Maestríahttp://purl.org/coar/resource_type/c_bdccinfo:eu-repo/semantics/masterThesisCRAI-USTA BucaramangaAaron D. & Tsouris C. 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