Adsorción de mercurio y cadmio en carbón subbituminoso oxidado-xantado, sulfonado o activado y resina sintética comercial

The combustion of low rank coal produces environmental impacts due to its low heat of combustion and high heteroatom content which has promoted its alternative uses as an adsorbent. A subbituminous coal (CS) was oxidized with air at 150°C on a fixed bed for 4 hours and xanthated with carbon disulfid...

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Autores:
Fernández Maestre, Roberto
Colpas Castillo, Fredy
Tipo de recurso:
Article of journal
Fecha de publicación:
2015
Institución:
Universidad de Ciencias Aplicadas y Ambientales U.D.C.A
Repositorio:
Repositorio Institucional UDCA
Idioma:
spa
OAI Identifier:
oai:repository.udca.edu.co:11158/1625
Acceso en línea:
https://revistas.udca.edu.co/index.php/ruadc/article/view/473
Palabra clave:
Combustión
Calor
Combustibles
Adsorción
Carbón activado
Carbón subbituminoso
Xantación
Espectometría de absorción atómica
Rights
openAccess
License
Derechos Reservados - Universidad de Ciencias Aplicadas y Ambientales, 2015
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dc.title.spa.fl_str_mv Adsorción de mercurio y cadmio en carbón subbituminoso oxidado-xantado, sulfonado o activado y resina sintética comercial
dc.title.alternative.eng.fl_str_mv Mercury and cadmium adsorption in subbituminous xanthated, sulfonated or activated carbon and commercial synthetic resin
title Adsorción de mercurio y cadmio en carbón subbituminoso oxidado-xantado, sulfonado o activado y resina sintética comercial
spellingShingle Adsorción de mercurio y cadmio en carbón subbituminoso oxidado-xantado, sulfonado o activado y resina sintética comercial
Combustión
Calor
Combustibles
Adsorción
Carbón activado
Carbón subbituminoso
Xantación
Espectometría de absorción atómica
title_short Adsorción de mercurio y cadmio en carbón subbituminoso oxidado-xantado, sulfonado o activado y resina sintética comercial
title_full Adsorción de mercurio y cadmio en carbón subbituminoso oxidado-xantado, sulfonado o activado y resina sintética comercial
title_fullStr Adsorción de mercurio y cadmio en carbón subbituminoso oxidado-xantado, sulfonado o activado y resina sintética comercial
title_full_unstemmed Adsorción de mercurio y cadmio en carbón subbituminoso oxidado-xantado, sulfonado o activado y resina sintética comercial
title_sort Adsorción de mercurio y cadmio en carbón subbituminoso oxidado-xantado, sulfonado o activado y resina sintética comercial
dc.creator.fl_str_mv Fernández Maestre, Roberto
Colpas Castillo, Fredy
dc.contributor.author.spa.fl_str_mv Fernández Maestre, Roberto
Colpas Castillo, Fredy
dc.subject.lemb.spa.fl_str_mv Combustión
Calor
topic Combustión
Calor
Combustibles
Adsorción
Carbón activado
Carbón subbituminoso
Xantación
Espectometría de absorción atómica
dc.subject.armarc.spa.fl_str_mv Combustibles
dc.subject.proposal.spa.fl_str_mv Adsorción
Carbón activado
Carbón subbituminoso
Xantación
Espectometría de absorción atómica
description The combustion of low rank coal produces environmental impacts due to its low heat of combustion and high heteroatom content which has promoted its alternative uses as an adsorbent. A subbituminous coal (CS) was oxidized with air at 150°C on a fixed bed for 4 hours and xanthated with carbon disulfide in a basic solution, at 30°C. The resulting xanthated coal (CX) was evaluated for the adsorption of Hg2+ and Cd2+ from 0,100, 1,000, 12.48, 124.8 y 998.3mg/L aqueous solutions; metal concentrations were determined by atomic absorption spectrometry. CX was compared against CS, a sulfonated CS, activated CS (CAp), a commercial activated carbon (CAC), and a commercial synthetic resin (RC) in terms of Hg2+ and Cd2+ adsorption. RC showed the highest adsorption capacity (concentration factor 98%) followed by theCX (concentration factor 96%). The adsorption of cadmium on the sulfonated CS was 0.56meq/g, lower than that of CX, 1.85meq/g. In general, Hg2+ was less adsorbed than Cd2+; the adsorption capacities decreased in the order: RC, CX, sulfonated CS, activated CS, CS, and CAC. CX showed a better Cd2+ adsorption, 81% against 15%, than a non-oxidized 40-hours-xanthated coal, which shows that oxidation of coal increased the amount of oxygenated groups that enhanced xanthation.
publishDate 2015
dc.date.issued.spa.fl_str_mv 2015-01
dc.date.accessioned.spa.fl_str_mv 2019-06-25T19:58:16Z
dc.date.available.spa.fl_str_mv 2019-06-25T19:58:16Z
dc.type.spa.fl_str_mv Artículo de revista
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dc.identifier.uri.spa.fl_str_mv https://revistas.udca.edu.co/index.php/ruadc/article/view/473
dc.identifier.local.spa.fl_str_mv 303001
identifier_str_mv 0123-4226
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url https://revistas.udca.edu.co/index.php/ruadc/article/view/473
dc.language.iso.spa.fl_str_mv spa
language spa
dc.relation.ispartofseries.spa.fl_str_mv Revista UDCA : Actualidad & divulgación Científica (Bogotá). -- Vol. 18, No. 1 (Ene.-Jun., 2015). -- páginas 241-250
dc.relation.indexed.spa.fl_str_mv Agricultura
dc.rights.spa.fl_str_mv Derechos Reservados - Universidad de Ciencias Aplicadas y Ambientales, 2015
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dc.rights.creativecommons.spa.fl_str_mv Atribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)
rights_invalid_str_mv Derechos Reservados - Universidad de Ciencias Aplicadas y Ambientales, 2015
https://creativecommons.org/licenses/by-nc-sa/4.0/
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dc.publisher.spa.fl_str_mv Bogotá : Universidad de Ciencias Aplicadas y Ambientales, 2015
institution Universidad de Ciencias Aplicadas y Ambientales U.D.C.A
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spelling Fernández Maestre, RobertoColpas Castillo, Fredy2019-06-25T19:58:16Z2019-06-25T19:58:16Z2015-010123-4226https://revistas.udca.edu.co/index.php/ruadc/article/view/473303001The combustion of low rank coal produces environmental impacts due to its low heat of combustion and high heteroatom content which has promoted its alternative uses as an adsorbent. A subbituminous coal (CS) was oxidized with air at 150°C on a fixed bed for 4 hours and xanthated with carbon disulfide in a basic solution, at 30°C. The resulting xanthated coal (CX) was evaluated for the adsorption of Hg2+ and Cd2+ from 0,100, 1,000, 12.48, 124.8 y 998.3mg/L aqueous solutions; metal concentrations were determined by atomic absorption spectrometry. CX was compared against CS, a sulfonated CS, activated CS (CAp), a commercial activated carbon (CAC), and a commercial synthetic resin (RC) in terms of Hg2+ and Cd2+ adsorption. RC showed the highest adsorption capacity (concentration factor 98%) followed by theCX (concentration factor 96%). The adsorption of cadmium on the sulfonated CS was 0.56meq/g, lower than that of CX, 1.85meq/g. In general, Hg2+ was less adsorbed than Cd2+; the adsorption capacities decreased in the order: RC, CX, sulfonated CS, activated CS, CS, and CAC. CX showed a better Cd2+ adsorption, 81% against 15%, than a non-oxidized 40-hours-xanthated coal, which shows that oxidation of coal increased the amount of oxygenated groups that enhanced xanthation.La combustión del carbón de bajo rango produce impactos ambientales por su bajo calor de combustión y alto conte-nido de heteroátomos, lo que ha promovido sus usos alter-nativos, como adsorbente. Un carbón subbituminoso (CS), se oxidó con aire a 150°C, en un lecho fijo, durante cuatro horas y se xantó con disulfuro de carbono en solución bá-sica, a 30°C. Este carbón xantado (CX), se evaluó para la adsorción de Hg2+ y Cd2+ de soluciones acuosas de 0,100, 1,000, 12,48, 124,8 y 998,3mg/L; los metales, se determi-naron por espectrometría de absorción atómica. CX se com-paró con CS, CS sulfonado y CS activado (CAp), además de un carbón activado comercial (CAC) y una resina sintética comercial (RC), en términos de su capacidad de adsorción de metales. RC mostró la más alta capacidad de adsorción (factor de concentración 98%), seguido por CX (factor deconcentración 96%). En general, el Hg2+ se adsorbió me-nos que el Cd2+ y las capacidades de adsorción siguieron el orden, de mayor a menor: RC, CX, CAp, CS, y CAC. CX también mostró una mejor adsorción de Cd2+, 81% vs. 15%, que un carbón xantado no oxidado, lo que muestra que la oxidación previa del carbón aumentó la cantidad de grupos oxigenados que, a su vez, aumentaron la xantación.Incluye referencias bibliográficasapplication/pdfspaBogotá : Universidad de Ciencias Aplicadas y Ambientales, 2015Revista UDCA : Actualidad & divulgación Científica (Bogotá). -- Vol. 18, No. 1 (Ene.-Jun., 2015). -- páginas 241-250AgriculturaDerechos Reservados - Universidad de Ciencias Aplicadas y Ambientales, 2015https://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccessAtribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)http://purl.org/coar/access_right/c_abf2Adsorción de mercurio y cadmio en carbón subbituminoso oxidado-xantado, sulfonado o activado y resina sintética comercialMercury and cadmium adsorption in subbituminous xanthated, sulfonated or activated carbon and commercial synthetic resinArtículo de 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en las Obras Colectivas;
b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda;
c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas.Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).
4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:
a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).
b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.
c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.
d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:
i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.
ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.
e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, Acinpro), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.
5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.
6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.
7. Término.
a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.
b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.
8. Varios.
a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.
b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.
c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.
d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.



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