Determinación del estado de transición en la reacción de oxidación del n-heptano con el catalizador(MnAco (C16H14N2O2) mediante la exploración de la superficie de energía potencial 1
55 páginas : gráficas
- Autores:
-
Rivera Devia, Ingrid Catalina
- Tipo de recurso:
- Trabajo de grado de pregrado
- Fecha de publicación:
- 2018
- Institución:
- Universidad de Ciencias Aplicadas y Ambientales U.D.C.A
- Repositorio:
- Repositorio Institucional UDCA
- Idioma:
- spa
- OAI Identifier:
- oai:repository.udca.edu.co:11158/982
- Acceso en línea:
- https://repository.udca.edu.co/handle/11158/982
- Palabra clave:
- Oxidación -- Investigaciones
Alcanos -- Investigaciones
Química
Reacción de oxidación
n-heptano
Catalizadores
- Rights
- openAccess
- License
- Derechos Reservados - Universidad de Ciencias Aplicadas y Ambientales
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Determinación del estado de transición en la reacción de oxidación del n-heptano con el catalizador(MnAco (C16H14N2O2) mediante la exploración de la superficie de energía potencial 1 |
| title |
Determinación del estado de transición en la reacción de oxidación del n-heptano con el catalizador(MnAco (C16H14N2O2) mediante la exploración de la superficie de energía potencial 1 |
| spellingShingle |
Determinación del estado de transición en la reacción de oxidación del n-heptano con el catalizador(MnAco (C16H14N2O2) mediante la exploración de la superficie de energía potencial 1 Oxidación -- Investigaciones Alcanos -- Investigaciones Química Reacción de oxidación n-heptano Catalizadores |
| title_short |
Determinación del estado de transición en la reacción de oxidación del n-heptano con el catalizador(MnAco (C16H14N2O2) mediante la exploración de la superficie de energía potencial 1 |
| title_full |
Determinación del estado de transición en la reacción de oxidación del n-heptano con el catalizador(MnAco (C16H14N2O2) mediante la exploración de la superficie de energía potencial 1 |
| title_fullStr |
Determinación del estado de transición en la reacción de oxidación del n-heptano con el catalizador(MnAco (C16H14N2O2) mediante la exploración de la superficie de energía potencial 1 |
| title_full_unstemmed |
Determinación del estado de transición en la reacción de oxidación del n-heptano con el catalizador(MnAco (C16H14N2O2) mediante la exploración de la superficie de energía potencial 1 |
| title_sort |
Determinación del estado de transición en la reacción de oxidación del n-heptano con el catalizador(MnAco (C16H14N2O2) mediante la exploración de la superficie de energía potencial 1 |
| dc.creator.fl_str_mv |
Rivera Devia, Ingrid Catalina |
| dc.contributor.advisor.spa.fl_str_mv |
Ortiz Verano, Ismael, dir. |
| dc.contributor.author.spa.fl_str_mv |
Rivera Devia, Ingrid Catalina |
| dc.subject.lemb.spa.fl_str_mv |
Oxidación -- Investigaciones Alcanos -- Investigaciones Química |
| topic |
Oxidación -- Investigaciones Alcanos -- Investigaciones Química Reacción de oxidación n-heptano Catalizadores |
| dc.subject.proposal.spa.fl_str_mv |
Reacción de oxidación n-heptano Catalizadores |
| description |
55 páginas : gráficas |
| publishDate |
2018 |
| dc.date.accessioned.spa.fl_str_mv |
2018-09-05T19:14:55Z |
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2018-09-05T19:14:55Z |
| dc.date.issued.spa.fl_str_mv |
2018 |
| dc.type.spa.fl_str_mv |
Trabajo de grado - Pregrado |
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C. J. Viasus, R. A. Riveros, J. A. Alzate, and A. E. Burgos. Oxidaci´on de n-heptano mediada por el compuesto de coordinaci´on [Mn(C16H14N2O2 )AcO]. Revista UDCA Actualidad & Divulgaci´on Cient´ıfica, 14(2):141–149, 2011. J. B. L´opez de Mesa, G. Quintero, A. L. Guevara Vizca´ıno, D. C. Jaimes C´aceres, S.M. Guti´errez Ria˜no, and J. Miranda Garc´ıa. Bioremediaci´on de suelos contaminados con hidrocarburos derivados del petr´oleo. Nova, 4(5), 2006. P. Bifani. Medio ambiente y desarrollo sostenible. Number 18. IEPALA Editorial, 1999. A. Avellaneda. Petr´oleo e impacto ambiental en Colombia. Revista de la Universidad Nacional (1944-1992), 6(24):21–28, 1990. A. K. Suresh, M. M. Sharma, and T. Sridhar. Engineering aspects of industrial liquidphase air oxidation of hydrocarbons. Industrial & engineering chemistry research, 39(11):3958–3997, 2000 L.G. Wade Jr. Qu´ımica Org´anica. 5 edition, 2004. C. Jia, T. Kitamura, and Y. Fujiwara. Catalytic functionalization of arenes and alkanes via C–H bond activation. Accounts of Chemical Research, 34(8):633–639, 2001. A. L. Garc´ıa Cabeza. Desarrollo de nuevos m´etodos de funcionalizaci´on de enlaces CH catalizados por cobre orientados a la s´ıntesis de mol´eculas con actividad biol´ogica. PhD thesis, Universidad de C´adiz, 2016. G. Dyker. Handbook of CH transformations. Wiley-VCH, Weinheim, 2005. L. J. Watt. The production of acetylene from methane by partial oxidation. PhD thesis, University of British Columbia, 1951. R. H. Crabtree. Alkane C−H activation and functionalization with homogeneous transition metal catalysts: A century of progress — A new millennium in prospect. Journal of the Chemical Society, Dalton Transactions, (17):2437–2450, 2001. S. Romero Vargas. Estudios de transferencia electr´onica en compuestos an´alogos del azul de prusia. PhD thesis, Instituto Polit´ecnico Nacional, M´exido, 2016. F. Basolo, R. H. Busch, and R. Johnson. Qu´ımica de los compuestos de coordinaci´on: La qu´ımica de los complejos met´alicos. Revert´e, 1980. G. Rodgers. Introducci´on a la qu´ımica de coordinaci´on del estado s´olido. McGRAW HILL Interamericana, 1995. M. Beller and C. Bolm. Transition Metals for Organic Synthesis: Building Blocks and Fine Chemicals. Wiley, 2004 R.R. Contreras, J. Avenda˜no, F. B. Rullo, A. Guti´errez, E. Lacruz, E. Cardozo, and L. C. Misal. S´ıntesis y caracterizaci´on espectrosc´opica de complejos de paladio(II) con tioaminas heteroc´ıclicas tipo N,N’-alquil-bis (2-amino-1-ciclopentencarboditioato de metilo) (alquilo= etilo, L1. propilo, L2. butilo L3). Ciencia e Ingenier´ıa, 33(2):61–68, 2012 E.M. Cernia and M. Graziani. Polymer-supported coordination compounds as catalysts for organic reactions. Journal of Applied Polymer Science, 18(9):2725–2746, 1974 R. H. Crabtree. The organometallic chemistry of the transition metals. John Wiley & Sons, 2009. G. Kumar and S. K. Das. Coordination frameworks containing compounds as catalysts. Inorganic Chemistry Frontiers, 4(2):202–233, 2017. C. Redshaw. Use of metal catalysts bearing schiff base macrocycles for the ring opening polymerization (ROP) of cyclic esters. Catalysts, 7(5):165, 2017. A. P. Smith and C. L. Fraser. Bipyridine ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry {II}, pages 1 – 23. Pergamon, Oxford, 2003 C. R. Luman and F. N. Castellano. Phenanthroline ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 25 – 39. Pergamon, Oxford, 2003 R.P. Thummel. Terpyridine, oligopyridine, and polypyridine ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 41 – 53. Pergamon, Oxford, 2003. M.A. Ciriano and L.A. Oro. Pyridopyridine ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 55 – 61. Pergamon, Oxford, 2003. Z. Xu and L.K. Thompson. Heterocyclic and open-chain 1,2-diazine ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 63 – 95. Pergamon, Oxford, 2003. C. Pettinari, F. Marchetti, and A. Drozdov. /beta-diketones and related ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 97 – 115. Pergamon, Oxford, 2003. M. Haga. Benzimidazole ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 125 – 134. Pergamon, Oxford, 2003. K.M. Smith. Porphyrins. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 493 – 506. Pergamon, Oxford, 2003. R. Hern´andez-Molina and A. Mederos. Acyclic and macrocyclic schiff base ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 411 – 446. Pergamon, Oxford, 2003. K. Matsumoto, B. Saito, and T. Katsuki. Asymmetric catalysis of metal complexes with non-planar ONNO ligands: salen, salalen and salan. Chemical Communications, (35):3619–3627, 2007. P. G. Cozzi. Metal–salen Schiff base complexes in catalysis: practical aspects. Chemical Society Reviews, 33(7):410–421, 2004. S. Kumar, D. N. Dhar, and P.N. Saxena. Applications of metal complexes of Schiff bases-A review. Journal of Scientific & Industrial Research, 68:181–187, 2009. V. K. Gaikwad and U. M. Yadav. Metal complexes of Schiff bases. Scholary Research Journal for Interdisciplinary Studies, 2016. C. Burgos, E. Ana, L. Tamayo, and R. Torrellas-Hidalgo. Synthesis, characterization and antimicrobial activity of a Pd(II) complex with a 1, 3-diphenylpyrazole-4- carboxaldehyde thiosemicarbazone ligand. Revista UDCA Actualidad & Divulgaci´on Cient´ıfica, 17(2):477–486, 2014 R. T. Morrison and R. N. Boyd. Qu´ımica org´anica. Pearson Educaci´on, 1998 E. Parra Iglesias. Petr´oleo y gas natural: industria, mercados y precios, 2003. H. J. Sch¨afer. Activation and functionalization of alkanes. Angewandte Chemie, 102(7):849–850, 1990. F. G. Doro, J. R. L. Smith, A. G. Ferreira, and M. D. Assis. Oxidation of alkanes and alkenes by iodosylbenzene and hydrogen peroxide catalysed by halogenated manganese porphyrins in homogeneous solution and covalently bound to silica. Journal of Molecular Catalysis A: Chemical, 164(1-2):97–108, 2000. M. Costas. Selective C−H oxidation catalyzed by metalloporphyrins. Coordination Chemistry Reviews, 255(23):2912–2932, 2011. I. N. Levine. Qu´ımica cu´antica. Pearson Educaci´on, 2001 R. A. Friesner. Ab initio quantum chemistry: methodology and applications. Proceedings of the National Academy of Sciences of the United States of America, 102(19):6648–6653, 2005. M. Orio, D. A. Pantazis, and F. Neese. Density functional theory. Photosynthesis research, 102(2-3):443–453, 2009. G. Cuevas and F. Cort´es. Introducci´on a la qu´ımica computacional. Fondo de Cultura Econ´omica,, 2003. A. D. McNaught. Compendium of chemical terminology, volume 1669. Blackwell Science Oxford, 1997. E. G. Lewars. Computational chemistry: introduction to the theory and applications of molecular and quantum mechanics. Springer, 2016. Gold Book. Compendium of chemical terminology. International Union of Pure and Applied Chemistry, page 528, 2014. V. Moliner Ib´a˜nez. Mecanismos Moleculares de Reacciones Enzim´aticas y Estructuras de Transici´on: Estudios te´oricos. PhD thesis, Universitat Jaume I, 1993. J De Paula. Atkins Qu´ımica F´ısica. Ed. M´edica Panamericana, 2007. M. D. Hanwell, D. E. Curtis, D. C. Lonie, T. Vandermeersch, E. Zurek, and G. R. Hutchison. Avogadro: an advanced semantic chemical editor, visualization, and analysis platform. Journal of cheminformatics, 4(1):17, 2012. M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, and G. A. Petersson. Gaussian software, version 09 revision d01, 2009. Gaussian, Inc., Wallingford CT, 2016 F. Neese. The ORCA program system. Wiley Interdisciplinary Reviews: Computational Molecular Science, 2(1):73–78, 2012. M. P. Andersson and P. Uvdal. New scale factors for harmonic vibrational frequencies using the B3LYP density functional method with the triple-ζ basis set 6-311+G(d, p). The Journal of Physical Chemistry A, 109(12):2937–2941, 2005. A. Garc´ıa, K. Arafet, Y. Hern´andez, and Y. Tamayo. Estudio por la teor´ıa de funcionales de la densidad (DFT) de los complejo d´ebiles de transferencia de carga. Revista Cubana de Qu´ımica, 19(2):34–41, 2007. M. J. Frisch, J. A. Pople, and J. S. Binkley. Self-consistent molecular orbital methods 25. Supplementary functions for gaussian basis sets. The Journal of Chemical Physics, 80(7):3265–3269, 1984. |
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Ortiz Verano, Ismael, dir.Rivera Devia, Ingrid Catalina2018-09-05T19:14:55Z2018-09-05T19:14:55Z2018https://repository.udca.edu.co/handle/11158/982QI002 R38d 201855 páginas : gráficasLa funcionalización mediante la oxidación selectiva de los enlaces C-H es un reto para la química moderna. Debido a la naturaleza inerte de dicho enlace, se requiere del uso de agentes oxidantes fuertes conllevando a retos de reactividad y quimioselectividad. Los químicos tratan de imitar oxidaciones selectivas que se logran por procesos biosintéticos enzimáticos, con el uso de catalizadores de compuestos de coordinación. Mediante el uso de herramientas computacionales se determinó parte del mecanismo de adición oxidativa (con y sin solvente) que se podría presentar en la reacción de oxidación de n-heptano, catalizada con el compuesto de coordinación [MnAcO(C16H14N2O2)]. La reacción fue reportada en el estudio (experimental) publicado por Viasus y colaboradores.Incluye bibliografíaPregradoQuímico(a)application/pdfspaDerechos Reservados - Universidad de Ciencias Aplicadas y Ambientaleshttps://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccessAtribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)http://purl.org/coar/access_right/c_abf2Determinación del estado de transición en la reacción de oxidación del n-heptano con el catalizador(MnAco (C16H14N2O2) mediante la exploración de la superficie de energía potencial 1Trabajo de grado - Pregradohttp://purl.org/coar/resource_type/c_7a1finfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/publishedVersionTexthttp://purl.org/redcol/resource_type/TPhttp://purl.org/coar/version/c_970fb48d4fbd8a85Oxidación -- InvestigacionesAlcanos -- InvestigacionesQuímicaReacción de oxidaciónn-heptanoCatalizadoresC. J. Viasus, R. A. Riveros, J. A. Alzate, and A. E. Burgos. Oxidaci´on de n-heptano mediada por el compuesto de coordinaci´on [Mn(C16H14N2O2 )AcO]. Revista UDCA Actualidad & Divulgaci´on Cient´ıfica, 14(2):141–149, 2011.J. B. L´opez de Mesa, G. Quintero, A. L. Guevara Vizca´ıno, D. C. Jaimes C´aceres, S.M. Guti´errez Ria˜no, and J. Miranda Garc´ıa. Bioremediaci´on de suelos contaminados con hidrocarburos derivados del petr´oleo. Nova, 4(5), 2006.P. Bifani. Medio ambiente y desarrollo sostenible. Number 18. IEPALA Editorial, 1999.A. Avellaneda. Petr´oleo e impacto ambiental en Colombia. Revista de la Universidad Nacional (1944-1992), 6(24):21–28, 1990.A. K. Suresh, M. M. Sharma, and T. Sridhar. Engineering aspects of industrial liquidphase air oxidation of hydrocarbons. Industrial & engineering chemistry research, 39(11):3958–3997, 2000L.G. Wade Jr. Qu´ımica Org´anica. 5 edition, 2004.C. Jia, T. Kitamura, and Y. Fujiwara. Catalytic functionalization of arenes and alkanes via C–H bond activation. Accounts of Chemical Research, 34(8):633–639, 2001.A. L. Garc´ıa Cabeza. Desarrollo de nuevos m´etodos de funcionalizaci´on de enlaces CH catalizados por cobre orientados a la s´ıntesis de mol´eculas con actividad biol´ogica. PhD thesis, Universidad de C´adiz, 2016.G. Dyker. Handbook of CH transformations. Wiley-VCH, Weinheim, 2005.L. J. Watt. The production of acetylene from methane by partial oxidation. PhD thesis, University of British Columbia, 1951.R. H. Crabtree. Alkane C−H activation and functionalization with homogeneous transition metal catalysts: A century of progress — A new millennium in prospect. Journal of the Chemical Society, Dalton Transactions, (17):2437–2450, 2001.S. Romero Vargas. Estudios de transferencia electr´onica en compuestos an´alogos del azul de prusia. PhD thesis, Instituto Polit´ecnico Nacional, M´exido, 2016.F. Basolo, R. H. Busch, and R. Johnson. Qu´ımica de los compuestos de coordinaci´on: La qu´ımica de los complejos met´alicos. Revert´e, 1980.G. Rodgers. Introducci´on a la qu´ımica de coordinaci´on del estado s´olido. McGRAW HILL Interamericana, 1995.M. Beller and C. Bolm. Transition Metals for Organic Synthesis: Building Blocks and Fine Chemicals. Wiley, 2004R.R. Contreras, J. Avenda˜no, F. B. Rullo, A. Guti´errez, E. Lacruz, E. Cardozo, and L. C. Misal. S´ıntesis y caracterizaci´on espectrosc´opica de complejos de paladio(II) con tioaminas heteroc´ıclicas tipo N,N’-alquil-bis (2-amino-1-ciclopentencarboditioato de metilo) (alquilo= etilo, L1. propilo, L2. butilo L3). Ciencia e Ingenier´ıa, 33(2):61–68, 2012E.M. Cernia and M. Graziani. Polymer-supported coordination compounds as catalysts for organic reactions. Journal of Applied Polymer Science, 18(9):2725–2746, 1974R. H. Crabtree. The organometallic chemistry of the transition metals. John Wiley & Sons, 2009.G. Kumar and S. K. Das. Coordination frameworks containing compounds as catalysts. Inorganic Chemistry Frontiers, 4(2):202–233, 2017.C. Redshaw. Use of metal catalysts bearing schiff base macrocycles for the ring opening polymerization (ROP) of cyclic esters. Catalysts, 7(5):165, 2017.A. P. Smith and C. L. Fraser. Bipyridine ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry {II}, pages 1 – 23. Pergamon, Oxford, 2003C. R. Luman and F. N. Castellano. Phenanthroline ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 25 – 39. Pergamon, Oxford, 2003R.P. Thummel. Terpyridine, oligopyridine, and polypyridine ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 41 – 53. Pergamon, Oxford, 2003.M.A. Ciriano and L.A. Oro. Pyridopyridine ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 55 – 61. Pergamon, Oxford, 2003.Z. Xu and L.K. Thompson. Heterocyclic and open-chain 1,2-diazine ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 63 – 95. Pergamon, Oxford, 2003.C. Pettinari, F. Marchetti, and A. Drozdov. /beta-diketones and related ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 97 – 115. Pergamon, Oxford, 2003.M. Haga. Benzimidazole ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 125 – 134. Pergamon, Oxford, 2003.K.M. Smith. Porphyrins. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 493 – 506. Pergamon, Oxford, 2003.R. Hern´andez-Molina and A. Mederos. Acyclic and macrocyclic schiff base ligands. In Jon A. McCleverty and Thomas J. Meyer, editors, Comprehensive Coordination Chemistry II, pages 411 – 446. Pergamon, Oxford, 2003.K. Matsumoto, B. Saito, and T. Katsuki. Asymmetric catalysis of metal complexes with non-planar ONNO ligands: salen, salalen and salan. Chemical Communications, (35):3619–3627, 2007.P. G. Cozzi. Metal–salen Schiff base complexes in catalysis: practical aspects. Chemical Society Reviews, 33(7):410–421, 2004.S. Kumar, D. N. Dhar, and P.N. Saxena. Applications of metal complexes of Schiff bases-A review. Journal of Scientific & Industrial Research, 68:181–187, 2009.V. K. Gaikwad and U. M. Yadav. Metal complexes of Schiff bases. Scholary Research Journal for Interdisciplinary Studies, 2016.C. Burgos, E. Ana, L. Tamayo, and R. Torrellas-Hidalgo. Synthesis, characterization and antimicrobial activity of a Pd(II) complex with a 1, 3-diphenylpyrazole-4- carboxaldehyde thiosemicarbazone ligand. Revista UDCA Actualidad & Divulgaci´on Cient´ıfica, 17(2):477–486, 2014R. T. Morrison and R. N. Boyd. Qu´ımica org´anica. Pearson Educaci´on, 1998E. Parra Iglesias. Petr´oleo y gas natural: industria, mercados y precios, 2003.H. J. Sch¨afer. Activation and functionalization of alkanes. Angewandte Chemie, 102(7):849–850, 1990.F. G. 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The Journal of Chemical Physics, 80(7):3265–3269, 1984.Facultad de CienciasQuímicaPublicationORIGINALTesis Catalina Rivera - 2018.pdfTesis Catalina Rivera - 2018.pdfapplication/pdf4103864https://repository.udca.edu.co/bitstreams/6244dbf1-387f-4890-a1c9-3142167fdafc/download01e0e155dca381fcd7369cb114915c2fMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-814775https://repository.udca.edu.co/bitstreams/fda6b2d6-c045-4b00-abfe-2bc1af823973/downloadf661acf14bedbf9f5d13897a0387e751MD52TEXTTesis Catalina Rivera - 2018.pdf.txtTesis Catalina Rivera - 2018.pdf.txtExtracted texttext/plain71404https://repository.udca.edu.co/bitstreams/c4b75d5e-2a67-4fec-bfd5-79692176ddb3/download423d0ed170850eba770d137cf443f788MD53THUMBNAILTesis Catalina Rivera - 2018.pdf.jpgTesis Catalina Rivera - 2018.pdf.jpgGenerated 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en las Obras Colectivas;
b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda;
c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas.Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).
4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:
a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).
b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.
c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.
d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:
i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.
ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.
e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, Acinpro), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.
5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.
6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.
7. Término.
a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.
b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.
8. Varios.
a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.
b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.
c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.
d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.

 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