Influencia del pH sobre la digestión anaerobia de biorresiduos de origen municipal
Municipal bio-wastes-MBW are characterized by their high content of organic matter, humidity, nutrients, and additionally are wastes easily acids, which makes them a source of pollution when are improperly disposed. Anaerobic digestion-AD is a technological alternative for MBW pollution control as w...
- Autores:
-
Parra Orobio, Brayan Alexis
Torres Lozada, Patricia
Marmolejo Rebellón, Luis Fernando
Cárdenas Cleves, Lina Marcela
Vásquez Franco, Carlos
Torres López, Wilmar Alexander
Ordóñez Andrade, José Abdón
- Tipo de recurso:
- Article of journal
- Fecha de publicación:
- 2014
- Institución:
- Universidad de Ciencias Aplicadas y Ambientales U.D.C.A
- Repositorio:
- Repositorio Institucional UDCA
- Idioma:
- spa
- OAI Identifier:
- oai:repository.udca.edu.co:11158/2213
- Acceso en línea:
- https://revistas.udca.edu.co/index.php/ruadc/article/view/421
https://doi.org/10.31910/rudca.v17.n2.2014.421
- Palabra clave:
- Biodegradabilidad anaerobia
Capacidad buffer
Potencial bioquímico de metano
Residuos sólidos
Materia orgánica
Nutrientes
Humedad
Residuos
- Rights
- openAccess
- License
- Derechos Reservados - Universidad de Ciencias Aplicadas y Ambientales
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dc.title.spa.fl_str_mv |
Influencia del pH sobre la digestión anaerobia de biorresiduos de origen municipal |
dc.title.alternative.spa.fl_str_mv |
Influence of ph on anaerobic digestion of municipal bio-wastes |
title |
Influencia del pH sobre la digestión anaerobia de biorresiduos de origen municipal |
spellingShingle |
Influencia del pH sobre la digestión anaerobia de biorresiduos de origen municipal Biodegradabilidad anaerobia Capacidad buffer Potencial bioquímico de metano Residuos sólidos Materia orgánica Nutrientes Humedad Residuos |
title_short |
Influencia del pH sobre la digestión anaerobia de biorresiduos de origen municipal |
title_full |
Influencia del pH sobre la digestión anaerobia de biorresiduos de origen municipal |
title_fullStr |
Influencia del pH sobre la digestión anaerobia de biorresiduos de origen municipal |
title_full_unstemmed |
Influencia del pH sobre la digestión anaerobia de biorresiduos de origen municipal |
title_sort |
Influencia del pH sobre la digestión anaerobia de biorresiduos de origen municipal |
dc.creator.fl_str_mv |
Parra Orobio, Brayan Alexis Torres Lozada, Patricia Marmolejo Rebellón, Luis Fernando Cárdenas Cleves, Lina Marcela Vásquez Franco, Carlos Torres López, Wilmar Alexander Ordóñez Andrade, José Abdón |
dc.contributor.author.spa.fl_str_mv |
Parra Orobio, Brayan Alexis Torres Lozada, Patricia Marmolejo Rebellón, Luis Fernando Cárdenas Cleves, Lina Marcela Vásquez Franco, Carlos Torres López, Wilmar Alexander Ordóñez Andrade, José Abdón |
dc.subject.proposal.spa.fl_str_mv |
Biodegradabilidad anaerobia Capacidad buffer Potencial bioquímico de metano Residuos sólidos |
topic |
Biodegradabilidad anaerobia Capacidad buffer Potencial bioquímico de metano Residuos sólidos Materia orgánica Nutrientes Humedad Residuos |
dc.subject.agrovoc.spa.fl_str_mv |
Materia orgánica Nutrientes Humedad Residuos |
description |
Municipal bio-wastes-MBW are characterized by their high content of organic matter, humidity, nutrients, and additionally are wastes easily acids, which makes them a source of pollution when are improperly disposed. Anaerobic digestion-AD is a technological alternative for MBW pollution control as well as for methane production as a renewable energy source; however, parameters such as pH can affect the process. This study evaluated at laboratory scale thought Biochemical Potential Methane-BPM assays at a temperature of 30oC during 40 days, the influence of pH on the MBW-AD. The pH values tested ranged from 5.5 to 8.0 units, using as inoculum sludge coming from the sludge anaerobic digestion of a domestic wastewater treatment plant. It was noticed that the acid pH between 5.5 and 6.0 units had the lowest methane production, 70.0 and 71.0mLCH4*gVS-1 respectively; while pH values near to the neutrality achieved the best results, being the highest production of methane corresponding to a pH of 7.0 units, reaching a value of 126.0mLCH4*gVS-1. Similarly, it was found that pH values from 7.0 to 8.0 units had the best buffer capacity, ensuring stability of the anaerobic process and avoiding inhibition phenomena. To achieve this condition, it is necessary to apply pH adjust due to the acid characteristics of the MBW. |
publishDate |
2014 |
dc.date.issued.spa.fl_str_mv |
2014-07 |
dc.date.accessioned.spa.fl_str_mv |
2019-10-03T15:48:23Z |
dc.date.available.spa.fl_str_mv |
2019-10-03T15:48:23Z |
dc.type.spa.fl_str_mv |
Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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http://purl.org/coar/resource_type/c_6501 |
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info:eu-repo/semantics/article |
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0123-4226 |
dc.identifier.uri.spa.fl_str_mv |
https://revistas.udca.edu.co/index.php/ruadc/article/view/421 |
dc.identifier.doi.spa.fl_str_mv |
https://doi.org/10.31910/rudca.v17.n2.2014.421 |
dc.identifier.local.spa.fl_str_mv |
305298 |
identifier_str_mv |
0123-4226 305298 |
url |
https://revistas.udca.edu.co/index.php/ruadc/article/view/421 https://doi.org/10.31910/rudca.v17.n2.2014.421 |
dc.language.iso.spa.fl_str_mv |
spa |
language |
spa |
dc.relation.ispartofseries.spa.fl_str_mv |
Revista UDCA : Actualidad & divulgación Científica (Bogotá). -- Vol. 17 No. 2 (Jul.-Dic., 2014). -- páginas 553-562 |
dc.relation.indexed.spa.fl_str_mv |
Agricultura |
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Derechos Reservados - Universidad de Ciencias Aplicadas y Ambientales |
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http://purl.org/coar/access_right/c_abf2 |
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Atribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0) |
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Derechos Reservados - Universidad de Ciencias Aplicadas y Ambientales https://creativecommons.org/licenses/by-nc-sa/4.0/ Atribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0) http://purl.org/coar/access_right/c_abf2 |
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openAccess |
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application/pdf |
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Bogotá : Universidad de Ciencias Aplicadas y Ambientales, 2014 |
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Universidad de Ciencias Aplicadas y Ambientales U.D.C.A |
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Parra Orobio, Brayan AlexisTorres Lozada, PatriciaMarmolejo Rebellón, Luis FernandoCárdenas Cleves, Lina MarcelaVásquez Franco, CarlosTorres López, Wilmar AlexanderOrdóñez Andrade, José Abdón2019-10-03T15:48:23Z2019-10-03T15:48:23Z2014-070123-4226https://revistas.udca.edu.co/index.php/ruadc/article/view/421https://doi.org/10.31910/rudca.v17.n2.2014.421305298Municipal bio-wastes-MBW are characterized by their high content of organic matter, humidity, nutrients, and additionally are wastes easily acids, which makes them a source of pollution when are improperly disposed. Anaerobic digestion-AD is a technological alternative for MBW pollution control as well as for methane production as a renewable energy source; however, parameters such as pH can affect the process. This study evaluated at laboratory scale thought Biochemical Potential Methane-BPM assays at a temperature of 30oC during 40 days, the influence of pH on the MBW-AD. The pH values tested ranged from 5.5 to 8.0 units, using as inoculum sludge coming from the sludge anaerobic digestion of a domestic wastewater treatment plant. It was noticed that the acid pH between 5.5 and 6.0 units had the lowest methane production, 70.0 and 71.0mLCH4*gVS-1 respectively; while pH values near to the neutrality achieved the best results, being the highest production of methane corresponding to a pH of 7.0 units, reaching a value of 126.0mLCH4*gVS-1. Similarly, it was found that pH values from 7.0 to 8.0 units had the best buffer capacity, ensuring stability of the anaerobic process and avoiding inhibition phenomena. To achieve this condition, it is necessary to apply pH adjust due to the acid characteristics of the MBW.Los biorresiduos de origen municipal-BOM, se caracterizan por su alto contenido de materia orgánica, humedad y nu-trientes, además de ser residuos fácilmente acidificables, lo que los convierte en una fuente contaminante cuando se dis-ponen inadecuadamente. La digestión anaerobia-DA es una alternativa tecnológica para el control de la contaminación de los BOM y la obtención de una fuente de energía reno-vable, como el metano; sin embargo, variables, como el pH,pueden afectar el proceso. Este estudio evaluó, a escala de laboratorio, mediante ensayos de Potencial Bioquímico de Metano-PBM, a una temperatura de 30oC, durante 40 días, la influencia del pH sobre la DA de BOM. Los valores de pH del sustrato variaron entre 5,5 a 8,0 unidades, utilizando como inóculo lodo, proveniente de la biodigestión anaerobia de lodos, de una planta de tratamiento de aguas residuales domésticas. Se evidenció que los pH ácidos correspondien-tes a 5,5 y 6,0 unidades, presentaron la menor producción de metano, del orden de 70,0 y 71,0 mLCH4*gSV-1, respecti-vamente, mientras que los pH cercanos a la neutralidad, lo-graron los mejores resultados, siendo la producción a un pH de 7,0 unidades la mayor, la cual, fue 126,0mLCH4*gSV-1. Los resultados están acordes con el comportamiento de la capacidad buffer, que fue más adecuada, entre 7,0 y 8,0 unidades, garantizando estabilidad del proceso anaerobio y evitando así la ocurrencia de fenómenos de inhibición. Para lograr estos niveles de pH, se hace necesario adicionar un alcalinizante, debido a las características ácidas de los BOM.Incluye referencias bibliográficasapplication/pdfspaBogotá : Universidad de Ciencias Aplicadas y Ambientales, 2014Revista UDCA : Actualidad & divulgación Científica (Bogotá). -- Vol. 17 No. 2 (Jul.-Dic., 2014). -- páginas 553-562AgriculturaDerechos Reservados - Universidad de Ciencias Aplicadas y Ambientaleshttps://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccessAtribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)http://purl.org/coar/access_right/c_abf2Influencia del pH sobre la digestión anaerobia de biorresiduos de origen municipalInfluence of ph on anaerobic digestion of municipal bio-wastesArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionTexthttp://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85Biodegradabilidad anaerobiaCapacidad bufferPotencial bioquímico de metanoResiduos sólidosMateria orgánicaNutrientesHumedadResiduosPublicationORIGINALArtículo.pdfArtículo.pdfapplication/pdf293503https://repository.udca.edu.co/bitstreams/3a403434-ac06-484a-a89f-6b28ddf5c1fd/downloadfb2bb36d9876f2748a516018f6a6ddc5MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-814775https://repository.udca.edu.co/bitstreams/cf0de32b-3f62-4775-84ad-34dc99a80409/downloadf661acf14bedbf9f5d13897a0387e751MD52TEXTArtículo.pdf.txtArtículo.pdf.txtExtracted texttext/plain35920https://repository.udca.edu.co/bitstreams/703c8444-6dd3-4d05-b403-07103bd8b341/downloadb6920d682e7bde1b5e100372d1c37d6dMD53THUMBNAILArtículo.pdf.jpgArtículo.pdf.jpgGenerated 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en las Obras Colectivas;
b.	Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda;
c.	Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.
Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas.Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).
4. Restricciones.
La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:
a.	Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).
b.	Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.
c.	Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.
d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:
i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.
ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.
e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, Acinpro), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.
5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.
6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.
7. Término.
a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.
b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.
8. Varios.
a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.
b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.
c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.
d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.

 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